781 research outputs found
Quantum Electrical Dipole in Triangular Systems: a Model for Spontaneous Polarity in Metal Clusters
Triangular symmetric molecules with mirror symmetry perpendicular to the
3-fold axis are forbidden to have a fixed electrical dipole moment. However, if
the ground state is orbitally degenerate and lacks inversion symmetry, then a
``quantum'' dipole moment does exist. The system of 3 electrons in D_3h
symmetry is our example. This system is realized in triatomic molecules like
Na_3. Unlike the fixed dipole of a molecule like water, the quantum moment does
not point in a fixed direction, but lies in the plane of the molecule and takes
quantized values +/- mu_0 along any direction of measurement in the plane. An
electric field F in the plane leads to a linear Stark splitting +/- mu_0 F}. We
introduce a toy model to study the effect of Jahn-Teller distortions on the
quantum dipole moment. We find that the quantum dipole property survives when
the dynamic Jahn-Teller effect is included, if the distortion of the molecule
is small. Linear Stark splittings are suppressed in low fields by molecular
rotation, just as the linear Stark shift of water is suppressed, but will be
revealed in moderately large applied fields and low temperatures. Coulomb
correlations also give a partial suppression.Comment: 10 pages with 7 figures included; thoroughly revised with a new
coauthor; final minor change
Constraining the variation of fundamental constants using 18cm OH lines
We describe a new technique to estimate variations in the fundamental
constants using 18cm OH absorption lines. This has the advantage that all lines
arise in the same species, allowing a clean comparison between the measured
redshifts. In conjunction with one additional transition (for example, an
HCO line), it is possible to simultaneously measure changes in ,
and . At present, only the 1665 MHz and 1667 MHz lines
have been detected at cosmological distances; we use these line redshifts in
conjunction with those of HI 21cm and mm-wave molecular absorption in a
gravitational lens at to constrain changes in the above three
parameters over the redshift range . While the constraints
are relatively weak ( 1 part in ), this is the first
simultaneous constraint on the variation of all three parameters. We also
demonstrate that either one (or more) of , and must vary with
cosmological time or there must be systematic velocity offsets between the OH,
HCO and HI absorbing clouds.Comment: 5 pages, no figures. Accepted for publication in Phys. Rev. Let
Spatial heterodyne interferometry of VY Canis Major's, alpha Orionis, alpha Scorpii, and R leonis at 11 microns
Using the technique of heterodyne interferometry, measurements were made of the spatial distribution of 11 micron radiation from four late type stars. The circumstellar shells surrounding VY Canis Majoris, alpha Orionis, and alpha Scorpii were resolved, whereas that of R Leonis was only partially resolved at a fringe spacing of 0.4 sec
The 158 micron (CII) mapping of galaxies: Probing the atomic medium
Using the MPE/UCB Far-infrared Imaging Fabry-Perot Interferometer (FIFI) on the Kuiper Airborne Observatory (KAO), we have made large scale maps of (CII) in the spiral galaxies NGC 6946, NGC 891, M83 and the peculiar elliptical Cen A, thus allowing for the first time, detailed studies of the spatial distribution of the FIR line emission in external galaxies. We find that the (CII) emission comes from a mixture of components of interstellar gas. The brightest emission is associated with the nuclear regions, a second component traces the spiral arms as seen in the nearly face on spiral galaxies NGC 6946 and M83 and the largest star forming/H2 regions contained within them, and another extended component of low brightness can be detected in all of the galaxies far from the nucleus, beyond the extent of CO emission
High spectral and spatial resolution observations of the 12.28 micron emission from H2 in the Orion molecular cloud
The pure rotational S(2) line of molecular hydrogen at 12.28 microns was looked for in 44 positions in the Orion moleular cloud with 6 in. beams and 35 km/s spectral resolution; it was detected in 27 positions. Emission was observed over a velocity range of + or - 100 km/s. The lines are approximately symmetric, and have full widths at half maximum ranging from 100 km/s down to the resolution limit. The distribution of intensities and line shapes is largely consistent with that seen in the 2 micron hydrogen transitions. However, unexpectedly complex line profiles and point-to-point variations in linear shapes appear, particularly in the region near IRc9
Conjugate 18cm OH Satellite Lines at a Cosmological Distance
We have detected the two 18cm OH satellite lines from the
source PKS1413+135, the 1720 MHz line in emission and the 1612 MHz line in
absorption. The 1720 MHz luminosity is , more than
an order of magnitude larger than that of any other known 1720 MHz maser. The
profiles of the two satellite lines are conjugate, implying that they arise in
the same gas. This allows us to test for any changes in the values of
fundamental constants, without being affected by systematic uncertainties
arising from relative motions between the gas clouds in which the different
lines arise. Our data constrain changes in ,
where ; we find ,
consistent with no changes in , and .Comment: 5 pages, 1 figure. Minor changes to match published versio
Water vapor at a translational temperature of one kelvin
We report the creation of a confined slow beam of heavy-water (D2O) molecules
with a translational temperature around 1 kelvin. This is achieved by filtering
slow D2O from a thermal ensemble with inhomogeneous static electric fields
exploiting the quadratic Stark shift of D2O. All previous demonstrations of
electric field manipulation of cold dipolar molecules rely on a predominantly
linear Stark shift. Further, on the basis of elementary molecular properties
and our filtering technique we argue that our D2O beam contains molecules in
only a few ro-vibrational states.Comment: 4 pages, 4 figures, 1 tabl
Adiabatic orientation of rotating dipole molecules in an external field
The induced polarization of a beam of polar clusters or molecules passing
through an electric or magnetic field region differs from the textbook
Langevin-Debye susceptibility. This distinction, which is important for the
interpretation of deflection and focusing experiments, arises because instead
of acquiring thermal equilibrium in the field region, the beam ensemble
typically enters the field adiabatically, i.e., with a previously fixed
distribution of rotational states. We discuss the orientation of rigid
symmetric-top systems with a body-fixed electric or magnetic dipole moment. The
analytical expression for their "adiabatic-entry" orientation is elucidated and
compared with exact numerical results for a range of parameters. The
differences between the polarization of thermodynamic and "adiabatic-entry"
ensembles, of prolate and oblate tops, and of symmetric-top and linear rotators
are illustrated and identified.Comment: 18 pages, 4 figure
State-to-State Differential and Relative Integral Cross Sections for Rotationally Inelastic Scattering of H2O by Hydrogen
State-to-state differential cross sections (DCSs) for rotationally inelastic
scattering of H2O by H2 have been measured at 71.2 meV (574 cm-1) and 44.8 meV
(361 cm-1) collision energy using crossed molecular beams combined with
velocity map imaging. A molecular beam containing variable compositions of the
(J = 0, 1, 2) rotational states of hydrogen collides with a molecular beam of
argon seeded with water vapor that is cooled by supersonic expansion to its
lowest para or ortho rotational levels (JKaKc= 000 and 101, respectively).
Angular speed distributions of fully specified rotationally excited final
states are obtained using velocity map imaging. Relative integral cross
sections are obtained by integrating the DCSs taken with the same experimental
conditions. Experimental state-specific DCSs are compared with predictions from
fully quantum scattering calculations on the most complete H2O-H2 potential
energy surface. Comparison of relative total cross sections and state-specific
DCSs show excellent agreement with theory in almost all detailsComment: 46 page
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