First principles study of adsorbed Cu_n (n=1-4) microclusters on MgO(100): structural and electronic properties

We present a density functional study of the structural and electronic properties of small Cu_n (n=1,4) aggregates on defect-free MgO(100). The calculations employ a slab geometry with periodic boundary conditions, supercells with up to 76 atoms, and include full relaxation of the surface layer and of all adsorbed atoms. The preferred adsorption site for a single Cu adatom is on top of an oxygen atom. The adsorption energy and Cu-O distance are E_S-A = 0.99 eV and d_S-A = 2.04 Angstroems using the Perdew-Wang gradient corrected exchange correlation functional. The saddle point for surface diffusion is at the "hollow" site, with a diffusion barrier of around 0.45 eV. For the adsorbed copper dimer, two geometries, one parallel and one perpendicular to the surface, are very close in energy. For the adsorbed Cu_3, a linear configuration is preferred to the triangular geometry. As for the tetramer, the most stable adsorbed geometry for Cu_4 is a rhombus. The adsorption energy per Cu atom decreases with increasing the size of the cluster, while the Cu-Cu cohesive energy increases, rapidly becoming more important than the adsorption energy.Comment: Major revision, Latex(2e) document, 23 pages, 11 figures, accepted for publication in J. of Chem. Phys., paper available at http://irrmawww.epfl.ch/vm/vm_wor

The old anticentre open cluster Berkeley 32: membership and fundamental parameters

We have obtained medium-low resolution spectroscopy and BVI CCD imaging of Berkeley 32, an old open cluster which lies in the anticentre direction. From the radial velocities of 48 stars in the cluster direction we found that 31 of them, in crucial evolutionary phases, are probable cluster members, with an average radial velocity of +106.7 (sigma = 8.5) km/s. From isochrone fitting to the colour magnitude diagrams of Berkeley 32 we have obtained an age of 6.3 Gyr, (m-M)0 = 12.48 and E(B-V) = 0.10. The best fit is obtained with Z=0.008. A consistent distance, (m-M)0 ~= 12.6 +/- 0.1, has been derived from the mean magnitude of red clump stars with confirmed membership; we may assume (m-M)0 ~= 12.55 +/- 0.1. The colour magnitude diagram of the nearby field observed to check for field stars contamination looks intriguingly similar to that of the Canis Major overdensity.Comment: MNRAS, in press. Degraded resolution for Fig.

Radial velocities and membership of stars in the old, distant open cluster Berkeley 29

Multi slit spectroscopy at the Telescopio Nazionale Galileo was employed to measure radial velocities for 20 stars in the direction of the old open cluster Berkeley 29, the farthest known in our Galaxy. Membership information was derived for stars along all the red giant branch, in particular near its tip, and on the red clump. The sample of bona-fide cluster members was used to revise the cluster distance to about 15 kpc, on the basis of an empirical comparison with the red clump in open clusters with known distances. A metallicity [Fe/H] = -0.74 +/- 0.18 was also estimated using the colours of spectroscopically confirmed red giant stars.Comment: 7 pages, 5 figures (fig. 1 at low-res, but JPEG version included too), accepted for publication in A&

Photometric and spectroscopic study of the intermediate-age open cluster NGC 2355

In this paper we analyse the evolutionary status and properties of the old open cluster NGC 2355, located in the Galactic anticentre direction, as a part of the long term programme BOCCE. NGC 2355 was observed with LBC@LBT using the Bessel $B$, $V$, and $I_c$ filters. The cluster parameters have been obtained using the synthetic colour-magnitude diagram (CMD) method, as done in other papers of this series. Additional spectroscopic observations with FIES@NOT of three giant stars were used to determine the chemical properties of the cluster. Our analysis shows that NGC 2355 has metallicity slightly less than solar, with [Fe/H]$=-0.06$ dex, age between 0.8 and 1 Gyr, reddening $E(B-V)$ in the range 0.14 and 0.19 mag, and distance modulus $(m-M)_0$ of about 11 mag. We also investigated the abundances of O, Na, Al, $\alpha$, iron-peak, and neutron capture elements, showing that NGC 2355 falls within the abundance distribution of similar clusters (same age and metallicity). The Galactocentric distance of NGC~2355 places it at the border between two regimes of metallicity distribution; this makes it an important cluster for the study of the chemical properties and evolution of the disc.Comment: 20 pages, 11 figures, Accepted on MNRA

Functional compartmentalization of Rad9 and Hus1 reveals diverse assembly of the 9-1-1 complex components during the DNA damage response in Leishmania

The Rad9-Rad1-Hus1 (9-1-1) complex is a key component in the coordination of DNA damage sensing, cell cycle progression and DNA repair pathways in eukaryotic cells. This PCNA-related trimer is loaded onto RPA-coated single stranded DNA and interacts with ATR kinase to mediate effective checkpoint signaling to halt the cell cycle and to promote DNA repair. Beyond these core activities, mounting evidence suggests that a broader range of functions can be provided by 9-1-1 structural diversification. The protozoan parasite Leishmania is an early-branching eukaryote with a remarkably plastic genome, which hints at peculiar genome maintenance mechanisms. Here, we investigated the existence of homologs of the 9-1-1 complex subunits in L. major and found that LmRad9 and LmRad1 associate with chromatin in response to replication stress and form a complex in vivo with LmHus1. Similar to LmHus1, LmRad9 participates in telomere homeostasis and in the response to both replication stress and double strand breaks. However, LmRad9 and LmHus1-deficient cells present markedly opposite phenotypes, which suggest their functional compartmentalization. We show that some of the cellular pool of LmRad9 forms an alternative complex and that some of LmHus1 exists as a monomer. We propose that the diverse assembly of the Leishmania 9-1-1 subunits mediates functional compartmentalization, which has a direct impact on the response to genotoxic stress

Stacked analysis of earthquake sequences: statistical space-time definition of clustering and Omori law behavior

The definition of the aftershocks sequence is still a debated topic. We here propose a study of the spatial and temporal variation of the earthquakes clustering and rate decay. We used five different seismic catalogues, characterized by specific spatial and magnitude ranges. They are respectively: world one, for a global analysis, Greek, Japanese, Californian and Italian regional catalogues in order to investigate different seismo-tectonic settings. A stacking procedure has been applied to characterize a typical sequence behavior and allowing the evaluation of changes over time intervals

Earthquake sound perception

Sound is an effect produced by almost all earthquakes. Using a web-based questionnaire on earthquake effects that included questions relating to seismic sound, we collected 77,000 responses for recent shallow Italian earthquakes. An analysis of audibility attenuation indicated that the decrease of the percentage of respondents hearing the sound was proportional to the logarithm of the epicentral distance and linearly dependent on earthquake magnitude, in accordance with the behavior of ground displacement. Even if this result was based on Italian data, qualitative agreement with the results of theoretical displacement, and of a similar study based on French seismicity suggests wider validity. We also found that, given earthquake magnitude, audibility increased together with the observed macroseismic intensity, leading to the possibility of accounting for sound audibility in intensity assessment. Magnitude influenced this behavior, making small events easier to recognize, as suggested by their frequency content

How Observer Conditions Impact Earthquake Perception

Intensity scales define the criteria used to determine different levels of shaking in relation to environmental effects. Objective evaluations of low intensity degrees based on transient effects may be difficult. In particular, estimations for the number of people feeling an earthquake are critical, and are qualitatively described by words such as “few”, “many”, and “most” for determining various intensity levels. In general, such qualitative amounts are converted into specific percentages for each macroseismic scale. Additionally, estimations of macroseismic intensity are influenced by variables that are mentioned in macroseismic scale degree descriptions. For example, the Mercalli-Cancani-Sieberg (MCS; Sieberg, 1930) and the Modified Mercalli Intensity (MMI) scales (Wood and Neumann, 1931) describe the intensity II as “Felt only by a few people, extremely susceptible, in perfectly quiet situations, almost always on the upper floors of buildings”. Another example is the European Macroseismic Scale (EMS) (Grunthal, 1998) that describes the intensity V as “felt indoors by most, outdoors by few. Many sleeping people awake”. In this work, we focus on two variables referred to as people’s physical “situation” (what were you doing?), here categorized as “sleeping”, “at rest”, or “in motion”; and the observer’s “location”, here categorized as “higher floors”, “lower floors”, and “outdoors”. Both variables have a partial influence on intensity assessments because they condition vibration perception. However, it is important to study, using an experimental method, the weights of these variables in the quantification of felt effects. Musson (2005a) also recognized the influence of such conditions on the number of people feeling an earthquake, stating that the proportion of people in different conditions “are generally difficult to quantify in any case”. Today, we have a large amount of data available through the macroseismic web site “haisentitoilterremoto” associated with specific observer conditions. Using this data, a study of these effects is possible. For this analysis, we placed attention on transitory effects that, in the past, could not be easily studied due to the intrinsic difficulty in collecting this type of data. The aim of this work was to specifically analyze and quantify how the observer’s “situation” and “location” influence earthquake perception suggesting a new scale description that can be easily used for low intensity estimation

Luther-Emery Phase and Atomic-Density Waves in a Trapped Fermion Gas

The Luther-Emery liquid is a state of matter that is predicted to occur in one-dimensional systems of interacting fermions and is characterized by a gapless charge spectrum and a gapped spin spectrum. In this Letter we discuss a realization of the Luther-Emery phase in a trapped cold-atom gas. We study by means of the density-matrix renormalization-group technique a two-component atomic Fermi gas with attractive interactions subject to parabolic trapping inside an optical lattice. We demonstrate how this system exhibits compound phases characterized by the coexistence of spin pairing and atomic-density waves. A smooth crossover occurs with increasing magnitude of the atom-atom attraction to a state in which tightly bound spin-singlet dimers occupy the center of the trap. The existence of atomic-density waves could be detected in the elastic contribution to the light-scattering diffraction pattern.Comment: 10 pages, 3 figures, 1 Table, submitted to Phys. Rev. on July 25th 200

Double layer in ionic liquids: Overscreening vs. crowding

We develop a simple Landau-Ginzburg-type continuum theory of solvent-free ionic liquids and use it to predict the structure of the electrical double layer. The model captures overscreening from short-range correlations, dominant at small voltages, and steric constraints of finite ion sizes, which prevail at large voltages. Increasing the voltage gradually suppresses overscreening in favor of the crowding of counterions in a condensed inner layer near the electrode. The predicted ion profiles and capacitance-voltage relations are consistent with recent computer simulations and experiments on room-temperature ionic liquids, using a correlation length of order the ion size.Comment: 4 pages + supplementary informatio