Combustion in microgravity: The French contribution

AbstractMicrogravity (drop towers, parabolic flights, sounding rockets and space stations) are particularly relevant to combustion problems given that they show high-density gradients and in many cases weak forced convection. For some configurations where buoyancy forces result in complex flow fields, microgravity leads to ideal conditions that correspond closely to canonical problems, e.g., combustion of a spherical droplet in a far-field still atmosphere, Emmons' problem for flame spreading over a solid flat plate, deflagration waves, etc. A comprehensive chronological review on the many combustion studies in microgravity was written first by Law and Faeth (1994) and then by F.A. Williams (1995). Later on, new recommendations for research directions have been delivered. In France, research has been managed and supported by CNES and CNRS since the creation of the microgravity research group in 1992. At this time, microgravity research and future activities contemplated the following:–Droplets: the “D2 law” has been well verified and high-pressure behavior of droplet combustion has been assessed. The studies must be extended in two main directions: vaporization in mixtures near the critical line and collective effects in dense sprays.–Flame spread: experiments observed blue flames governed by diffusion that are in accordance with Emmons' theory. Convection-dominated flames showed significant departures from the theory. Some theoretical assumptions appeared controversial and it was noted that radiation effects must be considered, especially when regarding the role of soot production in quenching.–Heterogeneous flames: two studies are in progress, one in Poitiers and the other in Marseilles, about flame/suspension interactions.–Premixed and triple flames: the knowledge still needs to be complemented. Triple flames must continue to be studied and understanding of “flame balls” still needs to be addressed

Elucidating the characteristic energy balance evolution in applied smouldering systems

Applied smouldering systems are emerging to solve a range of environmental challenges, such as remediation, sludge treatment, off-grid sanitation, and resource recovery. In many cases, these systems use smouldering to drive an efficient waste-to-energy process. While engineers and researchers are making strides in developing these systems, the characteristic energy balance trends have not yet been well-defined. This study addresses this topic and presents a detailed framework to uncover the characteristic energy balance evolution in applied smouldering systems. This work provides new experimental results; a new, validated analytical description of the cooling zone temperature profile at steady-state conditions; insight into the characteristic temperature changes over time; a re-analysis of published data; and a robust framework to contextualize the global energy balance results from applied smouldering systems. Altogether, this study is aimed to support researchers and engineers to better understand smouldering system performance to further the development of environmentally beneficial applications

Clean power generation from the intractable natural coalfield fires: turn harm into benefit

The coal fires, a global catastrophe for hundreds of years, have been proved extremely difficult to control, and hit almost every coal-bearing area globally. Meanwhile, underground coal fires contain tremendous reservoir of geothermal energy. Approximately one billion tons of coal burns underground annually in the world, which could generate ~1000GW per annum. A game-changing approach, environmentally sound thermal energy extraction from the intractable natural coalfield fires, is being developed by utilizing the waste energy and reducing the temperature of coalfield fires at the same time. Based on the Seebeck effect of thermoelectric materials, the temperature difference between the heat medium and cooling medium was employed to directly convert thermal energy into clean electrical energy. By the time of December 2016, the power generation from a single borehole at Daquan Lake fire district in Xinjiang has been exceeded 174.6W. The field trial demonstrates that it is possible to exploit and utilize the waste heat resources in the treated coal fire areas. It promises a significant impact on the structure of global energy generation and can also promote progress in thermoelectric conversion materials, geothermal exploration, underground coal fires control and other energy related areas

Applied smouldering for co-waste management: Benefits and trade-offs

Smouldering combustion is emerging as a valuable application for many environmentally beneficial purposes, including waste-to-energy. While many applied smouldering systems rely on small fractions of fuel mixed within inert porous media (IPM) like coarse grain silica sand, there is also an opportunity to pursue co-waste management with much higher fuel loadings. This study explores these co-waste systems by blending non-smoulderable wastes (e.g., sewage sludge) with smoulderable wastes (e.g., construction waste woodchips) to form porous solid fuels (PSFs). Key differences between these IPM and PSF systems were identified by contrasting the temperature profiles in space and time, specific mass loss rates, and emissions profiles across experiments in multiple reactors (with 0.054, 0.080, and 0.300 m radii). For example, the PSF systems exhibited higher throughputs, a more straightforward path towards continuous operation, improved scalability, and higher production of potentially useful by-products (e.g., CH4, H2) than the IPM systems. However, the PSF systems were more sensitive to extinction and exhibited lower fuel moisture content limitations than the IPM systems. Altogether, this study illuminates the benefits and trade-offs of co-waste smouldering

A Thin Skin Calorimeter (TSC) for Quantifying Irradiation During Large-scale Fire Testing

This paper details a novel method for quantifying irradiation (incident radiant heat flux) at the exposed surface of solid elements during large-scale fire testing. Within the scope of the work presented herein, a type of Thin Skin Calorimeter (TSC) was developed intending for a practical, low cost device enabling the cost-effective mass production required for characterising the thermal boundary conditions during multiple large-scale fire tests. The technical description of the TSC design and a formulation of the proposed calibration technique are presented. This methodology allows for the quantification of irradiation by means of an a posteriori analysis based on a temperature measurement from the TSC, a temperature measurement of the gas-phase in the vicinity of the TSC and a correction factor defined during a pre-test calibration process. The proposed calibration methodology is designed to account for uncertainties inherent to the simplicity of the irradiation measurement technique, therefore not requiring precise information regarding material thermal and optical properties. This methodology is designed and presented so as to enable adaption of the technique to meet the specific requirements of other experimental setups. This is conveyed by means of an example detailing the design and calibration of a device designed for a series of large-scale experiments as part of the ‘Real Fires for the Safe Design of Tall Buildings’ project

Experimental Characterisation of the Fire Behaviour of Thermal Insulation Materials for a Performance-Based Design Methodology

A novel performance-based methodology for the quantitative fire safe design of building assemblies including insulation materials has recently been proposed. This approach is based on the definition of suitable thermal barriers in order to control the fire hazards imposed by the insulation. Under this framework, the concept of “critical temperature” has been used to define an initiating failure criterion for the insulation, so as to ensure there will be no significant contribution to the fire nor generation of hazardous gas effluents. This paper proposes a methodology to evaluate this “critical temperature” using as examples some of the most common insulation materials used for buildings in the EU market, i.e. rigid polyisocyanurate foam, rigid phenolic foam, rigid expanded polystyrene foam and low density flexible stone wool. A characterisation of these materials, based on a series of ad-hoc Cone Calorimeter and thermo-gravimetric experiments, serves to establish the rationale behind the quantification of the critical temperature. The temperature of the main peak of pyrolysis, obtained from differential thermo-gravimetric analysis under a nitrogen atmosphere at low heating rates, is proposed as the “critical temperature” for materials that do not significantly shrink and melt, i.e. charring insulation materials. For materials with shrinking and melting behaviour it is suggested that the melting point could be used as “critical temperature”. Conservative values of “critical temperature” proposed are 300°C for polyisocyanurate, 425°C for phenolic foam and 240°C for expanded polystyrene. The concept of a “critical temperature” for the low density stone wool is examined in the same manner and found to be non-applicable due to the inability to promote a flammable mixture. Additionally, thermal inertia values required for the performance-based methodology are obtained for PIR and PF using a novel approach, providing thermal inertia values within the range 4.5 to 6.5\ua0×\ua010\ua0W\ua0s\ua0K\ua0m