18 research outputs found

    Investigations of Different Ion Intercalations on the Performance of FBG Hydrogen Sensors Based on Pt/MoO3

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    α-MoO3 has been used as a hydrogen sensing material due to its excellent properties and unique crystalline layer structure. However, the low repeatability of α-MoO3 based hydrogen sensor restricts its practical application. In this paper, the effect of intercalated ion species and the amount in α-MoO3 is experimentally investigated and discussed. It is concluded that the repeatability of the sensor depends on the radius of intercalated ions and amount of ionic bonds. The optimal ion species is Na+ and the optimal amount of precursor is 1 mmol

    A Porphyrin--Fullerene Dyad with a Supramolecular Double-Cable Structure as a Novel Electron Acceptor for Bulk Heterojunction Polymer Solar Cells

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    With a supramolecular “double-cable” structure in the solid state, a light harvesting porphyrin-fullerene dyad is demonstrated to be a promising candidate for new electron acceptors in high-performance bulk heterojunction (BHJ) polymer solar cells (PSCs). It has long-lived mobile carriers, a high short circuit current, and a large open circuit voltage

    PCBM Disperse-Red Ester with Strong Visible-Light Absorption: Implication of Molecular Design and Morphological Control for Organic Solar Cells

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    A new dyad of fullerene/disperse-red, denoted as PCBDR, strongly absorbs visible light in the range of 400–600 nm. PCBDR showed advantages over PCBM in several aspects such as enhanced visible-light absorption, improved solubility, and the possibility to facilitate cascaded electron transfer. P3HT:PCBDR bulk heterojunction (BHJ) solar cells, nevertheless, so far have not outperformed P3HT:PCBM BHJ solar cells under similar conditions. Among factors that affect the efficiency of P3HT:PCBDR BHJ solar cells, the suppression of the interchain interaction of P3HT in the P3HT:PCBDR blend played a major role, presumably due to better interfacial miscibility between P3HT and PCBDR than that in blends of P3HT:PCBM. In contrast, benzoporphyrin (BP), due to its unique crystallinity, morphology, and nonsolubility, afforded a better control of the morphology and the interface of the p/n junctions. As a consequence, the performance of solar cells with BP/PCBDR as the active layer was comparable to that of BP/PCBM solar cells. These results suggest that a synergistic approach of synthetic design and morphological control in devices is critical to develop new electron acceptors for highly efficient organic/polymer solar cells
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