Rotational modulation and single g-mode pulsation in the B9pSi star HD 174356?

Chemically peculiar (CP) stars of the upper main sequence are characterized by specific anomalies in the photospheric abundances of some chemical elements. The group of CP2 stars, which encompasses classical Ap and Bp stars, exhibits strictly periodic light, spectral, and spectropolarimetric variations that can be adequately explained by the model of a rigidly rotating star with persistent surface structures and a stable global magnetic field. Using observations from the Kepler K2 mission, we find that the B9pSi star HD 174356 displays a light curve variable in both amplitude and shape, which is not expected in a CP2 star. Employing archival and new photometric and spectroscopic observations, we carry out a detailed abundance analysis of HD 174356 and discuss its photometric and astrophysical properties in detail. We employ phenomenological modelling to decompose the light curve and the observed radial velocity variability. Our abundance analysis confirms that HD 174356 is a silicon-type CP2 star. No magnetic field stronger than 110 G was found. The star's light curve can be interpreted as the sum of two independent strictly periodic signals with and. The periods have remained stable over 17 yr of observations. In all spectra, HD 174356 appears to be single-lined. From the simulation of the variability characteristics and investigation of stars in the close angular vicinity, we put forth the hypothesis that the peculiar light variability of HD 174356 arises in a single star and is caused by rotational modulation due to surface abundance patches (P1) and g-mode pulsation (P2).Fil: Mikulaek, Z. Masaryk University; República ChecaFil: Paunzen, E.. Masaryk University; República ChecaFil: Hümmerich, S.. Masaryk University; República ChecaFil: Niemczura, E.. University of Wrocław; PoloniaFil: Walczak, P.. University of Wrocław; PoloniaFil: Fraga, L.. Masaryk University; República ChecaFil: Bernhard, K.. American Association of Variable Star Observers ; Estados UnidosFil: Janik, J.. Masaryk University; República ChecaFil: Hubrig, S.. Leibniz-Institut für Astrophysik Potsdam; AlemaniaFil: Järvinen, S.. Masaryk University; República ChecaFil: Jagelka, M.. Leibniz Institute For Astrophysics Potsdam; AlemaniaFil: Pintado, Olga Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto Superior de Correlación Geológica. Universidad Nacional de Tucumán. Facultad de Ciencias Naturales e Instituto Miguel Lillo. Departamento de Geología. Cátedra Geología Estructural. Instituto Superior de Correlación Geológica; Argentina. Universidad San Pablo Tucumán; ArgentinaFil: Krticka, J.. Masaryk University; República ChecaFil: Prisegen, M.. Masaryk University; República ChecaFil: Skarka, M.. Masaryk University; República ChecaFil: Zejda, M.. Masaryk University; República ChecaFil: Ilyin, I.. Leibniz-Institut für Astrophysik Potsdam; AlemaniaFil: Pribulla, T.. Masaryk University; República ChecaFil: Kaminski, K.. Adam Mickiewicz University; PoloniaFil: Kaminska, M. K.. Adam Mickiewicz University; PoloniaFil: Tokarek, J.. Adam Mickiewicz University; PoloniaFil: Zielinski, P.. Astronomical Observatory University of Warsaw; Poloni

Angiographic and clinical outcome of SARS-CoV-2 positive patients with ST-segment elevation myocardial infarction undergoing primary angioplasty: A collaborative, individual patient data meta-analysis of six registry-based studies

The characteristics and outcome of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2)-positive patients with ST-Elevation Myocardial Infarction (STEMI) undergoing primary percutaneous coronary intervention (PPCI) are still poorly known

Principal component analysis of summertime ground site measurements in the Athabasca oil sands with a focus on analytically unresolved intermediate-volatility organic compounds

In this paper, measurements of air pollutants made at a ground site near Fort McKay in the Athabasca oil sands region as part of a multi-platform campaign in the summer of 2013 are presented. The observations included measurements of selected volatile organic compounds (VOCs) by a gas chromatograph–ion trap mass spectrometer (GC-ITMS). This instrument observed a large, analytically unresolved hydrocarbon peak (with a retention index between 1100 and 1700) associated with intermediate-volatility organic compounds (IVOCs). However, the activities or processes that contribute to the release of these IVOCs in the oil sands region remain unclear. Principal component analysis (PCA) with varimax rotation was applied to elucidate major source types impacting the sampling site in the summer of 2013. The analysis included 28 variables, including concentrations of total odd nitrogen (NOy), carbon dioxide (CO2), methane (CH4), ammonia (NH3), carbon monoxide (CO), sulfur dioxide (SO2), total reduced-sulfur compounds (TRSs), speciated monoterpenes (including α- and β-pinene and limonene), particle volume calculated from measured size distributions of particles less than 10 and 1&thinsp;µm in diameter (PM10−1 and PM1), particle-surface-bound polycyclic aromatic hydrocarbons (pPAHs), and aerosol mass spectrometer composition measurements, including refractory black carbon (rBC) and organic aerosol components. The PCA was complemented by bivariate polar plots showing the joint wind speed and direction dependence of air pollutant concentrations to illustrate the spatial distribution of sources in the area. Using the 95&thinsp;% cumulative percentage of variance criterion, 10 components were identified and categorized by source type. These included emissions by wet tailing ponds, vegetation, open pit mining operations, upgrader facilities, and surface dust. Three components correlated with IVOCs, with the largest associated with surface mining and likely caused by the unearthing and processing of raw bitumen.</p

Efficient photochemical generation of peroxycarboxylic nitric anhydrides with ultraviolet light-emitting diodes

Photochemical sources of peroxycarboxylic nitric anhydrides (PANs) are utilized in many atmospheric measurement techniques for calibration or to deliver an internal standard. Conventionally, such sources rely on phosphor-coated low-pressure mercury (Hg) lamps to generate the UV light necessary to photo-dissociate a dialkyl ketone (usually acetone) in the presence of a calibrated amount of nitric oxide (NO) and oxygen (O2). In this manuscript, a photochemical PAN source in which the Hg lamp has been replaced by arrays of ultraviolet light-emitting diodes (UV-LEDs) is described. The output of the UV-LED source was analyzed by gas chromatography (PAN-GC) and thermal dissociation cavity ring-down spectroscopy (TD-CRDS). Using acetone, diethyl ketone (DIEK), diisopropyl ketone (DIPK), or di-n-propyl ketone (DNPK), respectively, the source produces peroxyacetic (PAN), peroxypropionic (PPN), peroxyisobutanoic (PiBN), or peroxy-n-butanoic nitric anhydride (PnBN) from NO in high yield (> 90 %). Box model simulations with a subset of the Master Chemical Mechanism (MCM) were carried out to rationalize product yields and to identify side products. The present work demonstrates that UV-LED arrays are a viable alternative to current Hg lamp setups

Efficient photochemical generation of peroxycarboxylic nitric anhydrides with ultraviolet light-emitting diodes

Photochemical sources of peroxycarboxylic nitric anhydrides (PANs) are utilized in many atmospheric measurement techniques for calibration or to deliver an internal standard. Conventionally, such sources rely on phosphor-coated low-pressure mercury (Hg) lamps to generate the UV light necessary to photo-dissociate a dialkyl ketone (usually acetone) in the presence of a calibrated amount of nitric oxide (NO) and oxygen (O₂). In this manuscript, a photochemical PAN source in which the Hg lamp has been replaced by arrays of ultraviolet light-emitting diodes (UV-LEDs) is described. The output of the UV-LED source was analyzed by gas chromatography (PAN-GC) and thermal dissociation cavity ring-down spectroscopy (TD-CRDS). Using acetone, diethyl ketone (DIEK), diisopropyl ketone (DIPK), or di-n-propyl ketone (DNPK), respectively, the source produces peroxyacetic (PAN), peroxypropionic (PPN), peroxyisobutanoic (PiBN), or peroxy-n-butanoic nitric anhydride (PnBN) from NO in high yield (> 90 %). Box model simulations with a subset of the Master Chemical Mechanism (MCM) were carried out to rationalize product yields and to identify side products. The present work demonstrates that UV-LED arrays are a viable alternative to current Hg lamp setups

A large contribution of anthropogenic organo-nitrates to secondary organic aerosol in the Alberta oil sands

10.5194/acp-19-12209-2019Atmospheric Chemistry and Physics191912209-1221