Microbial respiration and natural attenuation of benzene contaminated soils investigated by cavity enhanced Raman multi-gas spectroscopy

Soil and groundwater contamination with benzene can cause serious environmental damage. However, many soil microorganisms are capable to adapt and are known to strongly control the fate of organic contamination. Innovative cavity enhanced Raman multi-gas spectroscopy (CERS) was applied to investigate the short-term response of the soil micro-flora to sudden surface contamination with benzene regarding the temporal variations of gas products and their exchange rates with the adjacent atmosphere. 13C-labeled benzene was spiked on a silty-loamy soil column in order to track and separate the changes in heterotrophic soil respiration – involving 12CO2 and O2 – from the natural attenuation process of benzene degradation to ultimately form 13CO2. The respiratory quotient (RQ) decreased from a value 0.98 to 0.46 directly after the spiking and increased again within 33 hours to a value of 0.72. This coincided with the maximum 13CO2 concentration rate (0.63 μmol m−2 s−1), indicating the highest benzene degradation at 33 hours after the spiking event. The diffusion of benzene in the headspace and the biodegradation into 13CO2 were simultaneously monitored and 12 days after the benzene spiking no measurable degradation was detected anymore. The RQ finally returned to a value of 0.96 demonstrating the reestablished aerobic respiration

Performance Optimal and Robust Design of an Idle-Speed Controller Considering Physical Uncertainties

Modern passenger vehicles are equipped with a great number of control functions targeting versatile performance aspects like safe drive-ability, comfortable or sporty ride concerning assistance systems or a proper adjustment of engine control functions in order to prevent noise vibration and harshness issues. In this paper a methodology for a performance optimal and robust controller design is presented. This methodology is applied on a given idle-speed controller implementation using a detailed nonlinear drive train model in closed loop considering physical parameter uncertainties. The results are discussed with exemplary selected performance measures

Model Selection ensuring Practical Identifiability for Models of Electric Drives with Coupled Mechanics

Physically motivated models of electric drive trains with coupled mechanics are ubiquitous in industry for control design, simulation, feed-forward, model-based fault diagnosis etc. Often, however, the effort of model building prohibits these model-based methods. In this paper an automated model selection strategy is proposed for dynamic simulation models that not only optimizes the accuracy of the fit but also ensures practical identifiability of model parameters during structural optimization. Practical identifiability is crucial for physically motivated, interpretable models as opposed to pure prediction and inference applications. Our approach extends structural optimization considering practical identifiability to nonlinear models. In spite of the nonlinearity, local and linear criteria are evaluated, the integrity of which is investigated exemplarily. The methods are validated experimentally on a stacker crane

From Criticizing Progress to Psychoanalyzing Critical Theory. An Interview with Amy Allen

The importance of psychoanalysis for Critical Theory is unabated, but controversial. Regressive reactions to the crises of capitalism are currently reviving the debate about its relevance for the Frankfurt School. The interview with Amy Allen follows the focus of her book Critique on the Couch (2020) through questions about the significance of psychoanalysis for Critical Theory as well as the implications of her arguments for a theory of the subject and a critique of eurocentric concepts of progress

All-in-one: a versatile gas sensor based on fiber enhanced Raman spectroscopy for monitoring postharvest fruit conservation and ripening

In today's fruit conservation rooms the ripening of harvested fruit is delayed by precise management of the interior oxygen (O2) and carbon dioxide (CO2) levels. Ethylene (C2H4), a natural plant hormone, is commonly used to trigger fruit ripening shortly before entering the market. Monitoring of these critical process gases, also of the increasingly favored cooling agent ammonia (NH3), is a crucial task in modern postharvest fruit management. The goal of this work was to develop and characterize a gas sensor setup based on fiber enhanced Raman spectroscopy for fast (time resolution of a few minutes) and non-destructive process gas monitoring throughout the complete postharvest production chain encompassing storage and transport in fruit conservation chambers as well as commercial fruit ripening in industrial ripening rooms. Exploiting a micro-structured hollow-core photonic crystal fiber for analyte gas confinement and sensitivity enhancement, the sensor features simultaneous quantification of O2, CO2, NH3 and C2H4 without cross-sensitivity in just one single measurement. Laboratory measurements of typical fruit conservation gas mixtures showed that the sensor is capable of quantifying O2 and CO2 concentration levels with accuracy of 3% or less with respect to reference concentrations. The sensor detected ammonia concentrations, relevant for chemical alarm purposes. Due to the high spectral resolution of the gas sensor, ethylene could be quantified simultaneously with O2 and CO2 in a multi-component mixture. These results indicate that fiber enhanced Raman sensors have a potential to become universally usable on-site gas sensors for controlled atmosphere applications in postharvest fruit management

From Criticizing Progress to Psychoanalyzing Critical Theory. An Interview with Amy Allen

The importance of psychoanalysis for Critical Theory is unabated, but controversial. Regressive reactions to the crises of capitalism are currently reviving the debate about its relevance for the Frankfurt School. The interview with Amy Allen follows the focus of her book Critique on the Couch (2020) through questions about the significance of psychoanalysis for Critical Theory as well as the implications of her arguments for a theory of the subject and a critique of eurocentric concepts of progress

Direct raman spectroscopic measurements of biological nitrogen fixation under natural conditions: An analytical approach for studying nitrogenase activity

Biological N2 fixation is a major input of bioavailable nitrogen, which represents the most frequent factor limiting the agricultural production throughout the world. Especially, the symbiotic association between legumes and Rhizobium bacteria can provide substantial amounts of nitrogen (N) and reduce the need for industrial fertilizers. Despite its importance in the global N cycle, rates of biological nitrogen fixation have proven difficult to quantify. In this work, we propose and demonstrate a simple analytical approach to measure biological N2 fixation rates directly without a proxy or isotopic labeling. We determined a mean N2 fixation rate of 78 ± 5 μmol N2 (g dry weight nodule)-1 h-1 of a Medicago sativa-Rhizobium consortium by continuously analyzing the amount of atmospheric N2 in static environmental chambers with Raman gas spectroscopy. By simultaneously analyzing the CO2 uptake and photosynthetic plant activity, we think that a minimum CO2 mixing ratio might be needed for natural N2 fixation and only used the time interval above this minimum CO2 mixing ratio for N2 fixation rate calculations. The proposed approach relies only on noninvasive measurements of the gas phase and, given its simplicity, indicates the potential to estimate biological nitrogen fixation of legume symbioses not only in laboratory experiments. The same methods can presumably also be used to detect N2 fluxes by denitrification from ecosystems to the atmosphere. (Figure Presented)

Label-free CARS microscopy through a multimode fibre endoscope

Multimode fibres have recently been employed as high-resolution ultra-thin endoscopes, capable of imaging biological structures deep inside tissue in vivo. Here, we extend this technique to label-free non-linear microscopy with chemical contrast using coherent anti-Stokes Raman scattering (CARS) through a multimode fibre endoscope, which opens up new avenues for instant and in-situ diagnosis of potentially malignant tissue. We use a commercial 125 µm diameter, 0.29 NA GRIN fibre, and wavefront shaping on an SLM is used to create foci that are scanned behind the fibre facet across the sample. The chemical selectivity is demonstrated by imaging 2 µm polystyrene and 2.5 µm PMMA beads with per pixel integration time as low as 1 ms for epi-detection.Multimode fibres have recently been employed as high-resolution ultra-thin endoscopes, capable of imaging biological structures deep inside tissue in vivo. Here, we extend this technique to label-free non-linear microscopy with chemical contrast using coherent anti-Stokes Raman scattering (CARS) through a multimode fibre endoscope, which opens up new avenues for instant and in-situ diagnosis of potentially malignant tissue. We use a commercial 125 µm diameter, 0.29 NA GRIN fibre, and wavefront shaping on an SLM is used to create foci that are scanned behind the fibre facet across the sample. The chemical selectivity is demonstrated by imaging 2 µm polystyrene and 2.5 µm PMMA beads with per pixel integration time as low as 1 ms for epi-detection

The world’s growing municipal solid waste: trends and impacts

Global municipal waste production causes multiple environmental impacts, including greenhouse gas emissions, ocean plastic accumulation, and nitrogen pollution. However, estimates of both past and future development of waste and pollution are scarce. We apply compositional Bayesian regression to produce the first estimates of past and future (1965–2100) waste generation disaggregated by composition and treatment, along with resultant environmental impacts, for every country. We find that total wastes grow at declining speed with economic development, and that global waste generation has increased from 635 Mt in 1965 to 1999 Mt in 2015 and reaches 3539 Mt by 2050 (median values, middle-of-the-road scenario). From 2015 to 2050, the global share of organic waste declines from 47% to 39%, while all other waste type shares increase, especially paper. The share of waste treated in dumps declines from 28% to 18%, and more sustainable recycling, composting, and energy recovery treatments increase. Despite these increases, we estimate environmental loads to continue increasing in the future, although yearly plastic waste input into the oceans has reached a peak. Waste production does not appear to follow the environmental Kuznets curve, and current projections do not meet UN SDGs for waste reduction. Our study shows that a continuation of current trends and improvements is insufficient to reduce pressures on natural systems and achieve a circular economy. Relative to 2015, the amount of recycled waste would need to increase from 363 Mt to 740 Mt by 2030 to begin reducing unsustainable waste generation, compared to 519 Mt currently projected