High-temperature molten salt thermal energy storage systems

The results of comparative screening studies of candidate molten carbonate salts as phase change materials (PCM) for advanced solar thermal energy storage applications at 540 to 870 C (1004 to 1600 F) and steam Rankine electric generation at 400 to 540 C (752 to 1004 F) are presented. Alkali carbonates are attractive as latent heat storage materials because of their relatively high storage capacity and thermal conductivity, low corrosivity, moderate cost, and safe and simple handling requirements. Salts were tested in 0.1 kWhr lab scale modules and evaluated on the basis of discharge heat flux, solidification temperature range, thermal cycling stability, and compatibility with containment materials. The feasibility of using a distributed network of high conductivity material to increase the heat flux through the layer of solidified salt was evaluated. The thermal performance of an 8 kWhr thermal energy storage (TES) module containing LiKCO3 remained very stable throughout 5650 hours and 130 charge/discharge cycles at 480 to 535 C (896 to 995 F). A TES utilization concept of an electrical generation peaking subsystem composed of a multistage condensing steam turbine and a TES subsystem with a separate power conversion loop was defined. Conceptual designs for a 100 MW sub e TES peaking system providing steam at 316 C, 427 C, and 454 C (600 F, 800 F, and 850 F) at 3.79 million Pa (550 psia) were developed and evaluated. Areas requiring further investigation have also been identified

Evidence of Freezing Pressure in Sea Ice Discrete Brine Inclusions and Its Impact on Aqueous-Gaseous Equilibrium

Sea ice in part controls surface water properties and the ocean-atmosphere exchange of greenhouse gases at high latitudes. In sea ice, gas exists dissolved in brine and as air bubbles contained in liquid brine inclusions or as bubbles trapped directly within the ice matrix. Current research on gas dynamics within the ocean-sea ice-atmosphere interface has been based on the premise that brine with dissolved air becomes supersaturated with respect to the atmosphere during ice growth. Based on Henry's law, gas bubbles within brine should grow when brine reaches saturation during cooling, given that the total partial pressure of atmospheric gases is above the implicit pressure in brine of 1 atm. Using high-resolution light microscopy time series imagery of gas bubble evolution inside discrete brine pockets, we observed bubbles shrinking during cooling events in response to the development of freezing pressure above 3 atm. During warming of discrete brine pockets, existing bubbles expand and new bubbles nucleate in response to depressurization. Pressure variation within these inclusions has direct impacts on aqueous-gaseous equilibrium, indicating that Henry's law at a constant pressure of 1 atm is inadequate to assess the partitioning between dissolved and gaseous fractions of gas in sea ice. This new evidence of pressure build-up in discrete brine inclusions controlling the solubility of gas and nucleation of bubbles in these inclusions has the potential to affect the transport pathways of air bubbles and dissolved gases within sea ice-ocean-atmosphere interface and modifies brine biochemical properties

Quantifying Tri-partite Entanglement with Entropic Correlations

We show how to quantify tri-partite entanglement using entropies derived from experimental correlations. We use a multi-partite generalization of the entanglement of formation that is greater than zero if and only if the state is genuinely multi-partite entangled. We develop an entropic witness for tripartite entanglement, and show that the degree of violation of this witness places a lower limit on the tripartite entanglement of formation. We test our results in the three-qubit regime using the GHZ-Werner state and the W-Werner state, and in the high-dimensional pure-state regime using the triple-Gaussian wavefunction describing the spatial and energy-time entanglement in photon triplets generated in third-order spontaneous parametric down-conversion. In addition, we discuss the challenges in quantifying the entanglement for progressively larger numbers of parties, and give both entropic and target-state-based witnesses of multi-partite entanglement that circumvent this issue.Comment: 14 pages, 6 figures (removed inequality (formerly appendix B4) due to typo

CO2 and CH4 in sea ice from a subarctic fjord under influence of riverine input

We present the CH4 concentration [CH4], the partial pressure of CO2 (pCO2) and the total gas content in bulk sea ice from subarctic, land-fast sea ice in the Kapisillit fjord, Greenland. Fjord systems are characterized by freshwater runoff and riverine input and based on dδ18O data, we show that > 30% of the surface water originated from periodic river input during ice growth. This resulted in fresher sea-ice layers with higher gas content than is typical from marine sea ice. The bulk ice [CH4] ranged from 1.8 to 12.1 nmol Lg-1, which corresponds to a partial pressure ranging from 3 to 28 ppmv. This is markedly higher than the average atmospheric methane content of 1.9 ppmv. Evidently most of the trapped methane within the ice was contained inside bubbles, and only a minor portion was dissolved in the brines. The bulk ice pCO2 ranged from 60 to 330 ppmv indicating that sea ice at temperatures above -4 °C is undersaturated compared to the atmosphere (390 ppmv). This study adds to the few existing studies of CH4 and CO2 in sea ice, and we conclude that subarctic seawater can be a sink for atmospheric CO2, while being a net source of CH4

Truly unentangled photon pairs without spectral filtering

We demonstrate that an integrated silicon microring resonator is capable of efficiently producing photon pairs that are completely unentangled; such pairs are a key component of heralded single photon sources. A dual-channel interferometric coupling scheme can be used to independently tune the quality factors associated with the pump and signal and idler modes, yielding a biphoton wavefunction with Schmidt number arbitrarily close to unity. This will permit the generation of heralded single photon states with unit purity.Comment: 5 pages, 3 figure

Quantifying Entanglement in a 68-billion Dimensional Quantum State Space

Entanglement is the powerful and enigmatic resource central to quantum information processing, which promises capabilities in computing, simulation, secure communication, and metrology beyond what is possible for classical devices. Exactly quantifying the entanglement of an unknown system requires completely determining its quantum state, a task which demands an intractable number of measurements even for modestly-sized systems. Here we demonstrate a method for rigorously quantifying high-dimensional entanglement from extremely limited data. We improve an entropic, quantitative entanglement witness to operate directly on compressed experimental data acquired via an adaptive, multilevel sampling procedure. Only 6,456 measurements are needed to certify an entanglement-of-formation of 7.11 ± .04 ebits shared by two spatially-entangled photons. With a Hilbert space exceeding 68 billion dimensions, we need 20-million-times fewer measurements than the uncompressed approach and 1018-times fewer measurements than tomography. Our technique offers a universal method for quantifying entanglement in any large quantum system shared by two parties