71 research outputs found
Plastisol Foaming Process. Decomposition of the Foaming Agent, Polymer Behavior in the Corresponding Temperature Range and Resulting Foam Properties
The decomposition of azodicarbonamide, used as foaming agent in PVC - plasticizer (1/1) plastisols was studied by DSC. Nineteen different plasticizers, all belonging to the ester family, two being polymeric (polyadipates), were compared. The temperature of maximum decomposition rate (in anisothermal regime at 5 K min-1 scanning rate), ranges between 434 and 452 K. The heat of decomposition ranges between 8.7 and 12.5 J g -1. Some trends of variation of these parameters appear significant and are discussed in terms of solvent (matrix) and viscosity effects on the decomposition reactions. The shear modulus at 1 Hz frequency was determined at the temperature of maximum rate of foaming agent decomposition, and differs significantly from a sample to another. The foam density was determined at ambient temperature and the volume fraction of bubbles was used as criterion to judge the efficiency of the foaming process. The results reveal the existence of an optimal shear modulus of the order of 2 kPa that corresponds roughly to plasticizer molar masses of the order of 450 ± 50 g mol-1. Heavier plasticizers, especially polymeric ones are too difficult to deform. Lighter plasticizers such as diethyl phthalate (DEP) deform too easily and presumably facilitate bubble collapse
Mean-field transport theory for the two-flavour NJL model
By making decomposition of the Wigner function simultaneously in both the
spinor and the isospin spaces we derive a set of kinetic equations for the
quark distribution functions and the spin densities. A detailed analysis of the
consequences imposed by the chiral invariance on the form of the transport
equations is presented.Comment: Revtex, 25 pages, no figure
Immunizations Against Respiratory Infections in Children in Primary Health Care in Poland: Coverage and Delays
Exosomal miR-126 blocks the development of non-small cell lung cancer through the inhibition of ITGA6
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