Drying shrinkage of hydrothermally cured cements with reactive magnesia and clay brick waste

In recent years, worldwide research and development in the cement industry has gathered momentum with an aim to explore innovative and sustainable methods to deliver environmentally responsible Portland Cement (PC) based construction products. This study investigated physical and mechanical properties of autoclaved cement-quartz sand blends with the addition of clay-brick waste (CB waste) and reactive magnesia (MgO) with the aim to lower CO2 emissions through the reduction of PC consumption. Mechanical properties and drying shrinkage showed improvements with the incorporation of CB waste due to increased amounts and crystallinity of Al-tobermorite. The addition of reactive MgO to PC in hydrothermal conditions was observed to have a negative effect on the compressive strength. XRD data indicated that MgO did not take part in the reaction during the hydration of the cement and may even retard tobermorite formation. However, the expansive nature from the hydration of MgO to brucite may have compensated for drying shrinkage

Emerging treatments for neuromyelitis optica spectrum disorder

Neuromyelitis optica spectrum disorder (NMO-SD) has a worldwide prevalence of 0.5–10 persons per 100,000 population. It is characterised by inflammatory events centred on the optic nerve and spinal cord, often with poor recovery and subsequent residual disability. More than two-thirds of patients with NMO-SD have serum antibodies to the water channel protein aquaporin-4 (AQP4-immunoglobulin G [IgG]), which is implicated in the pathophysiology of NMO-SD. Others are seronegative or have serum antibodies to myelin oligodendrocyte glycoprotein. Diagnostic criteria depend on AQP4-IgG antibody status: those with seropositivity can have involvement of almost any CNS region, whereas those who are seronegative must have experienced at least one of either an optic neuritis, longitudinally extensive transverse myelitis, or area postrema syndrome with associated MRI lesions. Treatment of NMO-SD to date has largely been based on observational studies, case reports and retrospective analyses, and has included empiric use of off-label treatments such as rituximab, azathioprine and mycophenolate mofetil. However, with the recent completion of phase 3 clinical trials, an improved evidence base for current treatments and novel treatment options for NMO-SD are now emerging. Three clinical trials evaluate the monoclonal antibodies rituximab, satralizumab and eculizumab, versus placebo in the treatment of NMO-SD, and are discussed below

Implementation of ILLIAC 4 algorithms for multispectral image interpretation

Research has focused on the design and partial implementation of a comprehensive ILLIAC software system for computer-assisted interpretation of multispectral earth resources data such as that now collected by the Earth Resources Technology Satellite. Research suggests generally that the ILLIAC 4 should be as much as two orders of magnitude more cost effective than serial processing computers for digital interpretation of ERTS imagery via multivariate statistical classification techniques. The potential of the ARPA Network as a mechanism for interfacing geographically-dispersed users to an ILLIAC 4 image processing facility is discussed

ESEM-EDS investigation of the weathering of a heritage sydney sandstone

The degradation of Sydney sandstone used to build the heritage St Mary's Cathedral in Sydney, Australia, has been investigated using environmental scanning electron microscopy combined with energy dispersive X-ray spectroscopy. This technique provided the structural details of the cementing clay and an elemental characterization the sandstone. The observed differences in the elemental composition of the unweathered and weathered sandstones were associated with changes to the clay microstructure upon weathering. The results support the substitution theory that Fe3+ replaces Al3+ in the kaolinite clay component upon weathering. An examination of the impurities present prior to a nonstructural iron removal treatment revealed the presence of minerals that may provide a source of the elements responsible for the substitution process. © 2011 Microscopy Society Of America

Evaluation of a hybrid system of admixture and fibre for development of shrinkage resistant cement-based material

Shrinkage is a crucial feature in concrete and mortar members as it results in volume change that can lead to cracking and consequently to serviceability problems. Different additives and methods have been proposed to compensate for this problem mainly through the use of shrinkage reducing admixtures, fibres and expansive agents. In this paper, several combination systems of polyethylene micro-fibre along with an inorganic expansive agent have been studied for their influence on drying shrinkage. This special type of fibre, reported to act as shrinkage reducer, had been used in different concentrations in mortars and had been shown to have advantages and disadvantages. On the other hand, expansive agent, ammonium polyphosphate, had been shown to reduce drying shrinkage and modify most of mechanical properties. Free shrinkage strains as well as some physical properties of new mixes which contain polyphosphate and polyethylene micro-fibre are reported in this study. Several combinations were used and have been shown to have promising results in drying shrinkage, physical and mechanical properties

Jet rotation investigated in the near-ultraviolet with HST/STIS

We present results of the second phase of our near-ultraviolet investigation into protostellar jet rotation using HST/STIS. We obtain long-slit spectra at the base of five T Tauri jets to determine if there is a difference in radial velocity between the jet borders which may be interpreted as a rotation signature. These observations are extremely challenging and push the limits of current instrumentation, but have the potential to provide long-awaited observational support for the magneto-centrifugal mechanism of jet launching in which jets remove angular momentum from protostellar systems. We successfully detect all five jet targets (from RW Aur, HN Tau, DP Tau and CW Tau) in several near-ultraviolet emission lines, including the strong Mg II doublet. However, only RW Aur's bipolar jet presents sufficient signal-to-noise for analysis. The approaching jet lobe shows a difference of 10 km/s in a direction which agrees with the disk rotation sense, but is opposite to previously published optical measurements for the receding jet. The near-ultraviolet difference is not found six months later, nor is it found in the fainter receding jet. Overall, in the case of RW Aur, differences are not consistent with a simple jet rotation interpretation. Indeed, given the renowned complexity and variability of this system, it now seems likely that any rotation signature is confused by other influences, with the inevitable conclusion that RW Aur is not suited to a jet rotation study.Comment: 13 pages, 21 figures, Accepted by The Astrophysical Journa

Pitchstone Fines: A New Inorganic Binder For Portland Cement-Based Construction Products

The findings of this investigation into the performance pitchstone fines (PF) sourced from a naturally occurring pitchstone deposit in Queensland Australia as a potential pozzolanic supplementary cementitious material (SCM) are reported. 50 mm mortar cubes were prepared by replacement of 20% of the Portland cement (PC) with PF and PF blended with silica fume (SF) in a 1:1 ratio. Mortar cubes were also prepared with a 20% PC substitution level using fly ash (FA) and FA blended with SF also in a 1:1 ratio for comparison as the SCM. Control mortar cubes without PC substitution were also prepared. The compressive strength results for PF blended mortars were comparable to FA mortars, were within 75% of the control mortar at 7 and 28 days and approached the strength of the control mortar at 91 days curing. PF and FA blends containing SF produced compressive strength which surpassed the control mortar. Drying shrinkage measurements are also reported for up to 28 days storage in air. The PF mortar was found to have comparable shrinkage to the control mortar; the shrinkage of the FA mortar was found to be significantly greater. The differences were attributed to the particle shape, angularity and size resulting in greater capillary forces in the FA mortars resulting in greater shrinkage

Development of shrinkage resistant cement-based materials using fibers

Copyright © 2011 by Research Publishing Services. Drying shrinkage is themajor contributor to volume changes in normal strength concrete. Several classes of shrinkage compensating admixtures are known to the concrete industry. This study deals with the literature review and categorization of different classes of shrinkage reducing fibers, especially polyethylene fibers, with the objective of introducing new types of shrinkage reducing fiber. In this investigation a special type of hydrophobic polyethylene minifibers has been used in different dosages in mortar samples. The experimental results on drying shrinkage aswellasonseveralotherpropertiesarereported.Thehydrophobicminifibersshowedremarkable improvement in shrinkage reduction even at very lowconcentrations (0.1%of cementweight)