Early Jurassic dolerites of the Karoo Large Igneous Province ( KLIP): an analysis of their age and emplacement history from sea level to the Drakensberg Mountains in the Eastern Cape , South Africa Submitted

South Africa hosts one of the largest Large Igneous Provinces (LIPs that is likely linked to the early separation of East and West Gondwana. However, despite many studies, the relationship between dolerites and volcanic basalts of this LIP (also known as the Karoo Large Igneous Province or KLIP) remains unsolved, because of poorly linked age dates (timing), geochemistry and emplacement mechanisms. This problem is in part because different unreliable dating techniques with large margin of errors have been applied This study aims to address these issues by performing new geo chemical and high resolution geochronological analyses on a number of dolerites (sills and dykes), volcanic s also referred to in the literature as the Drakensberg flood basalts) and samples from drill cores and field outcrops. This project is focused on dolerites in the Eastern Cape Province and provides results from field mapping of dolerites (sills and dykes) from the sea level to an elevation of circa 1350 metres above sea level (MASL) and their link to the volcanic in the Eastern Cape Province. The dolerite dykes observed trends from metres to hundreds of kilometres and cut across volcanic, which have similar geochemistry. The intrusive dolerites collected from the field and from d rill core samples were likely emplaced by magma infiltration through pre-existing sub vertical brittle fractures and fissures and then emplaced horizontally as sills circa 183 Ma Detailed fracture mapping across host rock to the dolerite was carried out to test if they acted as possible pathways for magmatic emplacements. The dolerite dykes and fractures mapped in the host sedimentary rocks have a dominant NW direction, especially towards volcanic basalts. The project provides tests based on the geochemical relationships of the dolerites and basalts from sixty-six (66) cores and field outcrop samples. The results confirm that the chemical analyses from the volcanic basalts an d dolerites are closely related and reveal that most samples are Ocean Island Basalt OIB), but some also reveal subduction related processes. This is consistent with models that suggest subduction along south west Gondwana may have influenced plumemagmatism derived from the lower mantle that initiated break up of this supercontinent e.g de Wit and Stern 1981 Storey et al , 1992 ; Torsvik et al., 2006 and Burke et al., 2008

Cretaceous dyke swarms and brittle deformation structures in the upper continental crust flanking the Atlantic and Indian margins of Southern Africa, and their relationship to Gondwana break-up

Permanent brittle deformation of rocks of the upper crust is often manifested in the growth of fractures, or sliding along fractures, which may subsequently be intruded by magma and other fluids. The brittle deformation structures described here include faults, joints and dykes. Brittle deformation structures along passive continental margins result from continental fragmentation and related uplift, as is seen around the southern African margins in response to Gondwana break-up. In many cases the fragmentation is accompanied by significant magmatic events, for example the Cretaceous mafic dyke swarms that form major components of the South Atlantic Large Igneous Province (LIP) and originated during the break-up of West Gondwana (Africa and South America). The magmatic events accompanying the break-up of Gondwana resulted in crustal extension and the formation of joint systems and dyke swarms that exhibit distinct geometric features that appear to display fractal patterns. This work analyses the relationship between the Henties Bay-Outjo Dyke Swarm (HOD) on the west coast of Namibia, and the Ponta Grossa Dyke Swarm (PG) on the coast of Brazil, both of which formed ca. ~130 Ma, to test for their co-linearity and fractal geometry before and during West Gondwana break-up. This was achieved by reconstructing Gondwana‘s plates that contained the PG and HOD swarms, using ArcGIS and Gplates software. The dyke analyses was complemented with a comparative study of joints of the Table Mountain Group quartzites (TMG, ca. 400 Ma) in the Western Cape Province and Golden Valley Sill (GVS, ca. 180 Ma) in the Eastern Cape Province, to compare their fractal patterns and possible relationship. Mapping of joints was carried out in the field with the use of a compass and GPS. The HOD trend is positioned largely NNE > NE, but a NW dyke trend is also common. The dominant joints in the TMG trend NNW > WSW and the GVS joints trend WNW > NNE and others. The GVS and HOD orientations appear strongly correlated, while TMG shows no simple orientation correlation with GVS and HOD. The lack of correlation is attributed to the TMG‘s formation in different host-rocks with variable anisotropy and/or the presence of different mechanical processes acting at a different time in geological history. All mapped dykes and joints were analysed to test for fractal geometry. The fractal dimension results of about 18605 HOD dykes from microscopic to mega scale (0.1 mm – 100 km) shows fractal patterns that range between Df = 1.1 to 1.9; and the fractal dimension of about 1716 joints in the TMG and about 1026 joints in the GVS at all scales range between ca. Df = 1.6 to 1.9. The similarity of the fractal patterns indicates that joints and dykes may have formed in response to similar tectonic stress events; and similar orientations may indicate that joints pre-dated the dyke intrusions. However, the data also indicate that dykes are not always related to pre-existing joints

CO2 storage potential of basaltic rocks, Mpumalanga: Implications for the Just Transition

South Africa is the largest CO2 emitter on the African continent. These emissions stem from a heavy reliance on coal as the primary energy fuel and contributor toward socio-economic development. The South African government has targeted reducing CO2 emissions by more than half in the next 10 years. To meet climate change mitigation scenarios, while alleviating continued emissions, South Africa will look to technologies such as carbon capture, utilisation and storage. Initial assessments of South Africa’s potential for CO2 storage have focused on deep saline aquifers within volcano-sedimentary sequences along the near and offshore regions. Sustaining the Just Transition will, however, require additional storage capacity. In this study, we make an initial assessment of possible CO2 storage in basaltic sequences of the Ventersdorp Supergroup. Geological and mineralogical information was ascertained from borehole data. The geological information suggests that the subsurface extent of the Ventersdorp Supergroup is at least 80 000 km2 larger than previously mapped, extending beneath major point-source CO2 emitters and active coalfields. Furthermore, petrographic analyses suggest pore space of up to ca 15% with minimal alteration, and preservation of mafic silicate minerals that would enable reactive carbonation of injected CO2. Notable metasomatic and hydrothermal alteration is confined to significant contact horizons, such as the lowermost Ventersdorp Contact Reef. These results suggest that basaltic sequences may exponentially increase South Africa’s CO2 sequestration storage capacity and may have a significant impact on the country’s Just Transition. Significance:This study shows that basaltic sequences may support the permanent storage of anthropogenic CO2 in South Africa, in particular, proximal to significant point-source CO2 emitters. South Africa has voluminous and widespread basaltic sequences, which, in combination, increase South Africa’s geological CO2 storage potential by several orders of magnitude. These storage reservoirs can have a direct impact in South Africa by enabling a sustainable Just Transition toward a low-carbon economy while meeting intended climate change mitigation scenarios

CO2 storage potential of basaltic rocks, Mpumalanga: Implications for the Just Transition

South Africa is the largest CO2 emitter on the African continent. These emissions stem from a heavy reliance on coal as the primary energy fuel and contributor toward socio-economic development. The South African government has targeted reducing CO2 emissions by more than half in the next 10 years. To meet climate change mitigation scenarios, while alleviating continued emissions, South Africa will look to technologies such as carbon capture, utilisation and storage. Initial assessments of South Africa’s potential for CO2 storage have focused on deep saline aquifers within volcano-sedimentary sequences along the near and offshore regions. Sustaining the Just Transition will, however, require additional storage capacity. In this study, we make an initial assessment of possible CO2 storage in basaltic sequences of the Ventersdorp Supergroup. Geological and mineralogical information was ascertained from borehole data. The geological information suggests that the subsurface extent of the Ventersdorp Supergroup is at least 80 000 km2 larger than previously mapped, extending beneath major point-source CO2 emitters and active coalfields. Furthermore, petrographic analyses suggest pore space of up to ca 15% with minimal alteration, and preservation of mafic silicate minerals that would enable reactive carbonation of injected CO2. Notable metasomatic and hydrothermal alteration is confined to significant contact horizons, such as the lowermost Ventersdorp Contact Reef. These results suggest that basaltic sequences may exponentially increase South Africa’s CO2 sequestration storage capacity and may have a significant impact on the country’s Just Transition. Significance: This study shows that basaltic sequences may support the permanent storage of anthropogenic CO2 in South Africa, in particular, proximal to significant point-source CO2 emitters. South Africa has voluminous and widespread basaltic sequences, which, in combination, increase South Africa’s geological CO2 storage potential by several orders of magnitude. These storage reservoirs can have a direct impact in South Africa by enabling a sustainable Just Transition toward a low-carbon economy while meeting intended climate change mitigation scenarios

Earth Stewardship Science—Transdisciplinary Contributions to Quantifying Natural and Cultural Heritage of Southernmost Africa

Evaluating anthropogenic changes to natural systems demand greater quantification through innovative transdisciplinary research focused on adaptation and mitigation across a wide range of thematic sciences. Southernmost Africa is a unique field laboratory to conduct such research linked to earth stewardship, with ‘earth’ as in our Commons. One main focus of the AEON’s Earth Stewardship Science Research Institute (ESSRI) is to quantify the region’s natural and cultural heritage at various scales across land and its flanking oceans, as well as its time-scales ranging from the early Phanerozoic (some 540 million years) to the evolution of the Anthropocene (changes) following the emergence of the first human-culture on the planet some 200 thousand years ago. Here we illustrate the value of this linked research through a number of examples, including: (i) geological field mapping with the aid of drone, satellite and geophysical methods, and geochemical fingerprinting; (ii) regional ground and surface water interaction studies; (iii) monitoring soil erosion, mine tailing dam stability and farming practices linked to food security and development; (iv) ecosystem services through specific biodiversity changes based on spatial logging of marine (oysters and whales) and terrestrial (termites, frogs and monkeys) animals. We find that the history of this margin is highly episodic and complex by, for example, the successful application of ambient noise and groundwater monitoring to assess human-impacted ecosystems. This is also being explored with local Khoisan representatives and rural communities through Citizen Science. Our goal is to publicly share and disseminate the scientific and cultural data, through initiatives like the Africa Alive Corridor 10: ‘Homo Sapiens’ that embraces storytelling along the entire southern coast. It is envisioned that this approach will begin to develop the requisite integrated technological and societal practices that can contribute toward the needs of an ever-evolving and changing global ‘village’