Chiral Metal Surfaces and Nanoparticles

The surface of metals can exhibit intrinsic chiral structure. Furthermore, chirality can be bestowed onto achiral metal surfaces by adsorption of chiral molecules. Such chiral metal surfaces are promising as heterogeneous enantioselective catalysts and may furthermore be used for the separation and detection of enantiomers. Similarly, metal nanoparticles can be chiral, which is reflected by their optical activity in metal-based electronic transitions. The transfer of chirality from adsorbate to the metal surface depends on the structure of the former, which is however difficult to elucidate. It is shown that vibrational circular dichroism can be used to determine the structure of a chiral adsorbed molecule and the way it interacts with the metal

Control of the plasmonic resonance of a graphene coated plasmonic nanoparticle array combined with a nematic liquid crystal

We report on the fabrication and characterization of a switchable plasmonic device based on a conductive graphene oxide (cGO) coated plasmonic nanoparticle (NP) array, layered with nematic liquid crystal (NLC) as an active medium. A monolayer of NPs has been immobilized on a glass substrate through electrostatic interaction, and then grown in place using nanochemistry. This monolayer is then coated with a thin (less then 100nm) cGO film which acts simultaneously as both an electro-conductive and active medium. The combination of the conductive NP array with a separate top cover substrate having both cGO and a standard LC alignment layer is used for aligning a NLC film in a hybrid configuration. The system is analysed in terms of morphological and electro-optical properties. The spectral response of the sample characterized after each element is added (air, cGO, NLC) reveals a red-shift of the localized plasmonic resonance (LPR) frequency of approximately 62nm with respect to the NP array surrounded by air. The application of an external voltage (8Vpp) is suitable to modulate (blue shift) the LPR frequency by approximately 22nm

Linking Forest Fire Regimes and Climate—A Historical Analysis in a Dry Inner Alpine Valley

Forest fire regimes are likely to experience considerable changes in the European Alps due to climatic changes. However, little is known about the recent regional fire history and the impact of local climate on the fire regime during the 20th century. We therefore reconstructed the fire history in a dry continental valley of the Swiss Alps (Valais) over the past 100years based on documentary evidence, and investigated the relationship between the reconstructed fire regime and the local climatic variability. We compared the impact of temperature, precipitation, drought and dry foehn winds on fire frequency, extent of burnt area, and fire seasonality on various spatial and temporal scales. In the subalpine zone, the fire regime appears to have been mainly driven by temperature and precipitation, whereas these variables seem to have played only a secondary role in the colline-montane zones. Here, foehn winds and, probably, non-climatic factors seem to have been more important. Temperature and precipitation played a major role in shaping fire frequency and burnt area in the first half of the 20th century, but lost their importance during the second half. Our case study illustrates the occurrence of different fire regime patterns and their driving forces on small spatial scales (a few hundred square kilometers). We conclude that the strong rise in temperature over the past century has not profoundly changed the fire regime in Valais, but in the second half of the 20th century temperature was no longer a strong determinant for forest fires as compared to human activities or biomass availability in forest

Hotspots and richness pattern of grasshopper species in cultural landscapes

The success of the hotspot approach for biodiversity conservation depends on the spatial scale and the indicator species used. In this study, we investigated grasshopper species richness in Switzerland at a 1ha resolution including a total of 111 species. We compared the representativeness of common and of endangered grasshopper species for the overall grasshopper species richness and we assessed the efficiency of the hotspot approach for grasshopper conservation. The pattern of overall grasshopper species richness was well represented by both the number of common and the number of endangered grasshopper species. For evaluating the efficiency of different hotspot approaches for conservation, we compared hotspots of common species, hotspots of endangered species (rarity hotspots), and hotspots of all grasshopper species (richness hotspots). Among these hotspot types, richness hotspots not only featured most common grasshopper species, but they even contained more endangered species than the rarity hotspots. The combination of rarity hotspots and hotspots of common species featured more species than the other combinations of hotspot types. However, the gain of combining two hotspot types compared to the single-hotspot approach was low (max. 3 species). About 24% of the species were not contained in any of the hotspots. These grasshopper species require species-specific action plans. As rarity hotspots were located in areas that are rather strongly affected by landscape change, species richness in rarity hotspots may decrease in the future. We conclude that, for grasshoppers, the hotspot approach on the 1ha scale can be an effective way to conserve a high proportion of species richnes