Validation of Argon from Underground Sources for Use in the DarkSide-50 Detector

Liquid argon is an attractive target for dark matter searches due to its low cost and exemplary event discrimination. However, atmospherically derived argon contains the beta-emitter 39Ar which confounds the growth of dual-phase time projection chamber (TPC) style detectors to the ton-scale. The DarkSide Collaboration seeks to bypass this limitation by extracting argon from deep underground, from a location known to contain significantly less 39Ar than atmospherically derived argon. This thesis will summarize the e orts taken to produce the first batch of underground argon, focusing on the first operation of the underground argon in a dual-phase TPC to validate the purity of the product, performed at Fermilab using the SCENE cryostat

Proposed Keystone XL Pipeline: Legal Issues

[Excerpt] In 2008, TransCanada Corp. applied for a presidential permit from the State Department to construct and operate an oil pipeline across the U.S.-Canada border in a project known as Keystone XL. The Keystone XL pipeline would transport oil produced from oil sands in Alberta,Canada, to Gulf Coast refineries. The permit application was subjected to review by the State Department pursuant to executive branch authority over cross-border pipeline facilities as articulated in Executive Order 13337. After several phases of review, on November 10, 2011, the State Department announced that it would seek additional information about alternative pipeline routes before it could move forward with a national interest determination. In response, several pieces of legislation were introduced, including Title V of the Temporary Payroll Tax Cut Continuation Act of 2011. Title V dictated that President must grant the Keystone XL pipeline permit within 60 days of the law’s enactment, unless the President determined that the pipeline is not in the national interest. If the President did not make a national interest determination and took no action to grant the permit, then the law provided that the permit “shall be in effect by operation of law.” The Temporary Payroll Tax Cut Continuation Act of 2011 (P.L. 112-78), including Title V addressing the Keystone XL permit, was enacted on December 23, 2011. Pursuant to the requirements of Title V, on January 18, 2012, the State Department recommended that “the presidential permit for the proposed Keystone XL pipeline be denied and, that at this time, the TransCanada Keystone XL Pipeline be determined not to serve the national interest. ”The same day, the President stated his determination that the Keystone XL pipeline project“ would not serve the national interest. ”New legislative activity with respect to the permitting of border-crossing facilities, a subject previously handled exclusively by the executive branch, has triggered inquiries as to whether this raises constitutional issues related to the jurisdiction of the two branches over such facilities. Additionally, as states have begun to contemplate taking action with respect to the pipeline siting, some have questioned whether state siting of a pipeline is preempted by federal law. Others argue that states dictating the route of the pipeline violates the dormant Commerce Clause of the Constitution which, among other things, prohibits one state from acting to protect its own interests to the detriment of other states. This report reviews those legal issues. First, it suggests that legislation related to cross-border facility permitting is unlikely to raise significant constitutional questions, despite the fact that such permits have traditionally been handled by the executive branch alone pursuant to its constitutional “foreign affairs” authority. Next, it observes generally that state oversight of pipeline siting decisions does not appear to violate existing federal law or the Constitution. Finally, the report suggests that State Department’s implementation of the existing authority to issue presidential permits appears to allow for judicial review of its National Environmental Policy Act determinations

An analytic solution to the Busemann-Petty problem on sections of convex bodies

We derive a formula connecting the derivatives of parallel section functions of an origin-symmetric star body in R^n with the Fourier transform of powers of the radial function of the body. A parallel section function (or (n-1)-dimensional X-ray) gives the ((n-1)-dimensional) volumes of all hyperplane sections of the body orthogonal to a given direction. This formula provides a new characterization of intersection bodies in R^n and leads to a unified analytic solution to the Busemann-Petty problem: Suppose that K and L are two origin-symmetric convex bodies in R^n such that the ((n-1)-dimensional) volume of each central hyperplane section of K is smaller than the volume of the corresponding section of L; is the (n-dimensional) volume of K smaller than the volume of L? In conjunction with earlier established connections between the Busemann-Petty problem, intersection bodies, and positive definite distributions, our formula shows that the answer to the problem depends on the behavior of the (n-2)-nd derivative of the parallel section functions. The affirmative answer to the Busemann-Petty problem for n\le 4 and the negative answer for n\ge 5 now follow from the fact that convexity controls the second derivatives, but does not control the derivatives of higher orders.Comment: 13 pages, published versio

New Records of Michigan Cicadidae (Homoptera), With Notes on the Use of Songs to Monitor Range Changes

We present records of Diceroprocta vitripennis, Tibicen chloromera, and Tibicen pruinosa (new state record) in Michigan. Monitoring geographic range changes and population size differences by song suggests several population situations for cicadas: (1) sizable populations in most areas of apparently good habitat; (2) widely separated single individuals or small populations on the edges of populated regions, representing range extensions that may be of limited duration; (3) one or a few individuals present only once, probably transferred in soil on roots, and ultimately unsuccessful. Species- specific calling songs allow sensitive measurement of species\u27 range changes

Self-assembly of polyphosphazene immunoadjuvant with poly(ethylene oxide) enables advanced nanoscale delivery modalities and regulated pH-dependent cellular membrane activity

AbstractWater-soluble polyphosphazene polyacids, such as poly[di(carboxylatophenoxy)phosphazene] (PCPP), have been of significant interest due to their unique immunoadjuvant and vaccine delivery properties. We report that PCPP can spontaneously self-assemble into intermolecular complexes with common formulation excipients − polyethers in aqueous solutions at neutral pH through the establishment of hydrogen bonds. The resulting advanced PCPP delivery modalities can range from macromolecular assemblies at the nanoscale level to physically cross-linked hydrogels and the physical state can be modulated through varying polymer ratios and molecular weight of polyether. It has been demonstrated that such macromolecular complexes maintain protein-binding ability − a key characteristics of the delivery system. Importantly, the non-covalent modification of PCPP immunoadjuvant with polyethers introduces pH dependent membrane disruptive activity, which is not characteristic for PCPP itself, and is typically correlated to the ability of macromolecular carrier to facilitate endosomal escape. This can potentially affect the mechanism of immunoadjuvant action displayed by PCPP, afford means for its fine-tuning, as well as provide important insights for understanding the relationship between fundamental physico-chemical characteristics of polyphosphazene immunoadjuvants and their activity in vivo

A Two-Coordinate Nickel Imido Complex That Effects C−H Amination

An exceptionally low coordinate nickel imido complex, (IPr*)Ni═N(dmp) (2) (dmp = 2,6-dimesitylphenyl), has been prepared by the elimination of N_2 from a bulky aryl azide in its reaction with (IPr*)Ni(η^6-C_7H_8) (1). The solid-state structure of 2 features two-coordinate nickel with a linear C−Ni−N core and a short Ni−N distance, both indicative of multiple-bond character. Computational studies using density functional theory showed a Ni═N bond dominated by Ni(dπ)−N(pπ) interactions, resulting in two nearly degenerate singly occupied molecular orbitals (SOMOs) that are Ni−N π* in character. Reaction of 2 with CO resulted in nitrene-group transfer to form (dmp)NCO and (IPr*)Ni(CO)_3 (3). Net C−H insertion was observed in the reaction of 2 with ethene, forming the vinylamine (dmp)NH(CH═CH_2) (5) via an azanickelacyclobutane intermediate, (IPr*)Ni{N,C:κ^2-N(dmp)CH_2CH_2} (4)