Molecular Beam Measurement of the Hyperfine Structure of 85Rb19F

Radio‐frequency transitions between the hfs levels of the J=1 rotational state in 85Rb19F have been observed using a molecular beam electric resonance spectrometer. From these spectra we have obtained values for the constant eq1Q1, which characterizes the interaction between the electric quadrupole moment of the Rb nucleus with the molecular electric‐field gradient; for the constants c1 and c2 which characterize the magnetic interaction between the Rb and F nuclei, respectively, and the rotational angular momentum J of the molecule; and for the constants c3 and c4 which describe the magnetic coupling of the two nuclear spins. Measurements have been made on the first‐five vibrational states. The results for v=0 areeq1Q1=(−70.342±0.001)MHz,c1=(+0.52±0.02)kHz,c2=(+10.615±0.06)kHz,c3=(+0.80±0.06)kHz,c4=(+0.15±0.05)kHz.Values of these constants for v=1, 2, 3, and 4 are given with somewhat less precision.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/69352/2/JCPSA6-45-10-3731-1.pd

Triple Resonance Method for Molecular hfs Spectroscopy: Measurements on 133Cs19F

Three sequential oscillatory fields are employed in a molecular beam electric resonance spectrometer in order to observe molecular hfs transitions which do not obey the criteria for observability in the usual beam apparatus. The triple resonance method has been used to examine the hfs of CsF under conditions of very weak external fields. The method shows considerable promise for the detailed study of molecular hfs when more than one nucleus has a quadrupole moment, and for the observation of transitions at audio frequencies between closely spaced molecular energy levels.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/70906/2/JCPSA6-47-10-3904-1.pd

Hyperfine Structure of Thallium Bromide

The hyperfine structure of the J  =  2J=2 and J  =  3J=3 rotational states of TlBr has been measured with a molecular‐beam electric resonance spectrometer. Hyperfine transition frequencies were measured under conditions of very weak electric and magnetic fields. The linewidth was 500 Hz. The hyperfine interaction constants have been determined for 205Tl79Br, 203Tl79Br, 205Tl81Br, and 203Tl81Br in the first five vibrational states for J  =  2J=2. In addition, the interaction constants for J  =  3,υ  =  0J=3,υ=0 were determined for Tl79Br and Tl81Br, but it was not possible to resolve the effect of the two thallium isotopes in the J  =  3J=3 state. The spectra measured are well described by a hyperfine Hamiltonian containing the bromine quadrupole interaction, the spin–rotation interactions of both the thallium and the bromine nuclei, and both the scalar and tensor parts of the spin–spin interaction between the nuclei. The dependence of the magnetic hfs constants on vibrational state and on isotopic composition shows good agreement with theory. The magnetic octupole interaction of the bromine nucleus in TlBr is negligibly small, and we find no evidence for nuclear polarization or pseudoquadrupole effects.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/70429/2/JCPSA6-53-4-1525-1.pd

Identifying Prominent Life Events on Twitter

Social media is a common place for people to post and share digital reflections of their life events, including major events such as getting married, having children, graduating, etc. Although the creation of such posts is straightforward, the identification of events on online media remains a challenge. Much research in recent years focused on extracting major events from Twitter, such as earthquakes, storms, and floods. This paper however, targets the automatic detection of personal life events, focusing on five events that psychologists found to be the most prominent in people lives. We define a variety of features (user, content, semantic and interaction) to capture the characteristics of those life events and present the results of several classification methods to automatically identify these events in Twitter. Our proposed classification methods obtain results between 0.84 and 0.92 F1-measure for the different types of life events. A novel contribution of this work also lies in a new corpus of tweets, which has been annotated by using crowdsourcing and that constitutes, to the best of our knowledge, the first publicly available dataset for the automatic identification of personal life events from Twitter

Identifying Important Life Events from Twitter Using Semantic and Syntactic Patterns

Identifying global events from social media has been the focus of much research in recent years. However, the identification of personal life events poses new requirements and challenges that have received relatively little research attention. In this paper we explore a new approach for life event identification, where we expand social media posts into both semantic, and syntactic networks of content. Frequent graph patterns are mined from these networks and used as features to enrich life-event classifiers. Results show that our approach significantly outperforms the best performing baseline in accuracy (by 4.48% points) and F-measure (by 4.54% points) when used to identify five major life events identified from the psychology literature: Getting Married, Having Children, Death of a Parent, Starting School, and Falling in Love. In addition, our results show that, while semantic graphs are effective at discriminating the theme of the post (e.g. the topic of marriage), syntactic graphs help identify whether the post describes a personal event (e.g. someone getting married)

Automatic Identification of Personal Life Events in Twitter

New social media has led to an explosion in personal digital data that encompasses both those expressions of self chosen by the individual as well as reflections of self provided by other, third parties. The resulting Digital Personhood (DP) data is complex and for many users it is too easy to become lost in the mire of digital data. This paper studies the automatic detection of personal life events in Twitter. Six relevant life events are considered from psychological research including: beginning school; first full time job; falling in love; marriage; having children and parent's death. We define a variety of features (user, content, semantic and interaction) to capture the characteristics of those life events and present the results of several classification methods to automatically identify these events in Twitter

Hyperfine Structure of Thallium Chloride

The radio‐frequency spectra of TlCl at very weak electric and magnetic fields have been measured with a molecular beam electric resonance spectrometer. From these spectra the hyperfine interaction constants for the four isotopic species of the molecule were calculated. The constants for 205Tl35Cl in the J  =  2,υ  =  0J=2,υ=0 state are: eqQ  =  − 15793.32(50)kHz,cCl  =  1.38(10)kHz,cTl  =  76.35(10)kHz,c3  =  − 0.13(10)kHz,c4  =  − 1.54(10)kHz.eqQ=−15793.32(50)kHz,cCl=1.38(10)kHz,cTl=76.35(10)kHz,c3=−0.13(10)kHz,c4=−1.54(10)kHz. A test was made for the polarization of the chlorine nucleus in the electric field of the molecule by comparing the ratio of the quadrupole interaction constants for 205Tl35Cl and 205Tl37Cl to the ratio of the quadrupole interaction constants for the free chlorine atoms. The agreement of the two ratios is within their uncertainties, thus providing no evidence for a polarization effect. In addition, the dependence of the spin–rotation and spin–spin interaction constants on isotope was found to show good agreement with theory.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/69724/2/JCPSA6-50-5-2086-1.pd

Extremophiles in an Antarctic Marine Ecosystem

Recent attempts to explore marine microbial diversity and the global marine microbiome have indicated a large proportion of previously unknown diversity. However, sequencing alone does not tell the whole story, as it relies heavily upon information that is already contained within sequence databases. In addition, microorganisms have been shown to present small-to-large scale biogeographical patterns worldwide, potentially making regional combinations of selection pressures unique. Here, we focus on the extremophile community in the boundary region located between the Polar Front and the Southern Antarctic Circumpolar Current in the Southern Ocean, to explore the potential of metagenomic approaches as a tool for bioprospecting in the search for novel functional activity based on targeted sampling efforts. We assessed the microbial composition and diversity from a region north of the current limit for winter sea ice, north of the Southern Antarctic Circumpolar Front (SACCF) but south of the Polar Front. Although, most of the more frequently encountered sequences were derived from common marine microorganisms, within these dominant groups, we found a proportion of genes related to secondary metabolism of potential interest in bioprospecting. Extremophiles were rare by comparison but belonged to a range of genera. Hence, they represented interesting targets from which to identify rare or novel functions. Ultimately, future shifts in environmental conditions favoring more cosmopolitan groups could have an unpredictable effect on microbial diversity and function in the Southern Ocean, perhaps excluding the rarer extremophiles

Radio source calibration for the VSA and other CMB instruments at around 30 GHz

Accurate calibration of data is essential for the current generation of CMB experiments. Using data from the Very Small Array (VSA), we describe procedures which will lead to an accuracy of 1 percent or better for experiments such as the VSA and CBI. Particular attention is paid to the stability of the receiver systems, the quality of the site and frequent observations of reference sources. At 30 GHz the careful correction for atmospheric emission and absorption is shown to be essential for achieving 1 percent precision. The sources for which a 1 percent relative flux density calibration was achieved included Cas A, Cyg A, Tau A and NGC7027 and the planets Venus, Jupiter and Saturn. A flux density, or brightness temperature in the case of the planets, was derived at 33 GHz relative to Jupiter which was adopted as the fundamental calibrator. A spectral index at ~30 GHz is given for each. Cas A,Tau A, NGC7027 and Venus were examined for variability. Cas A was found to be decreasing at $0.394 \pm 0.019$ percent per year over the period March 2001 to August 2004. In the same period Tau A was decreasing at $0.22\pm 0.07$ percent per year. A survey of the published data showed that the planetary nebula NGC7027 decreased at $0.16\pm 0.04$ percent per year over the period 1967 to 2003. Venus showed an insignificant ($1.5 \pm 1.3$ percent) variation with Venusian illumination. The integrated polarization of Tau A at 33 GHz was found to be $7.8\pm 0.6$ percent at pa $= 148^\circ \pm 3^\circ$.}Comment: 13 pages, 15 figures, submitted to MNRA

Ozone depletion, greenhouse gases, and climate change

This symposium was organized to study the unusual convergence of a number of observations, both short and long term that defy an integrated explanation. Of particular importance are surface temperature observations and observations of upper atmospheric temperatures, which have declined significantly in parts of the stratosphere. There has also been a dramatic decline in ozone concentration over Antarctica that was not predicted. Significant changes in precipitation that seem to be latitude dependent have occurred. There has been a threefold increase in methane in the last 100 years; this is a problem because a source does not appear to exist for methane of the right isotopic composition to explain the increase. These and other meteorological global climate changes are examined in detail