Building for the Long Term

Endowed professorships support the work of select faculty -- and help to attract talented new professors

Tuning the excited state of photoactive building blocks for metal-templated self-assembly.

The reaction of 2,2':4,4'':4',4'''-quaterpyridyl (qtpy), with d(6) ruthenium(II) (Ru(II) ), and rhenium(I) (Re(I) ) metal centers has been investigated. The pendant pyridyl groups on the products have also been methylated to produce a second series of complexes containing coordinated Meqtpy(2+). The absorption spectra of the complexes are dominated by intraligand and charge-transfer bands. The ruthenium(II) complexes display broad unstructured luminescence consistent with emission from a Ru(d)→diimine(π*) manifold in acetonitrile solutions. In aqueous solutions, their emissions are weaker and the lifetimes are shorter. This effect is particularly acute for complexes incorporating coordinated dipyridylpyrazine, dppz, ligands. Although the emission of the ruthenium(II) complexes containing Meqtpy(2+) is generally shorter than their qtpy analogs, it is notable that solvent-dependent effects are much less intense. The rhenium(I) complexes also display broad unstructured luminescence but, compared with the ruthenium(II) systems, they have a relatively short lifetime in acetonitrile. Electrochemical studies reveal that all of the Ru(II) complexes display chemically reversible metal-based oxidations. Re(I) complexes only display irreversible metal-based oxidations. In most cases, the reduction processes were not fully chemically reversible. The electrochemical and optical studies reveal that the nature of the lowest excited state of these complexes--particularly, the systems incorporating dppz--is highly dependent on the nature of the coordinated ligands. Calculations indicate that, although the excited state of most of the complexes is centered on the qtpy or Meqtpy(2+) ligands, the excited state of the complexes containing dppz ligands is switched away from the dppz by qtpy methylation. A crystallographic study on one of the dicationic ruthenium(II) structures reveals that it forms an inclusion complex with benzene

From Visualization to Visually Enabled Reasoning

Interactive Visualization has been used to study scientific phenomena, analyze data, visualize information, and to explore large amounts of multi-variate data. It enables the human mind to gain novel insights by empowering the human visual system, encompassing the brain and the eyes, to discover properties that were previously unknown. While it is believed that the process of creating interactive visualizations is reasonably well understood, the process of stimulating and enabling human reasoning with the aid of interactive visualization tools is still a highly unexplored field. We hypothesize that visualizations make an impact if they successfully influence a thought process or a decision. Interacting with visualizations is part of this process. We present exemplary cases where visualization was successful in enabling human reasoning, and instances where the interaction with data helped in understanding the data and making a better informed decision. We suggest metrics that help in understanding the evolution of a decision making process. Such a metric would measure the efficiency of the reasoning process, rather than the performance of the visualization system or the user. We claim that the methodology of interactive visualization, which has been studied to a great extent, is now sufficiently mature, and we would like to provide some guidance regarding the evaluation of knowledge gain through visually enabled reasoning. It is our ambition to encourage the reader to take on the next step and move from information visualization to visually enabled reasoning

Finite Temperature Lattice QCD with Clover Fermions

We report on our simulation of finite temperature lattice QCD with two flavors of ${\cal O}(a)$ Symanzik-improved fermions and ${\cal O}(a^2)$ Symanzik-improved glue. Our thermodynamic simulations were performed on an $8^3 \times 4$ lattice, and we have performed complementary zero temperature simulations on an $8^3 \times 16$ lattice. We compare our results to those from simulations with two flavors of Wilson fermions and discuss the improvement resulting from use of the improved action.Comment: 3 pages, 4 figures, Talk presented at Lattice 9

Exotic hybrid mesons with light quarks

Hybrid mesons, made from a quark, an antiquark and gluons, can have quantum numbers inaccessible to conventional quark-antiquark states. Confirmation of such states would give information on the role of "dynamical" color in low energy QCD. We present preliminary results for hybrid meson masses using light Wilson valence quarks.Comment: 4 pages, 4 figures, Talk presented at LATTICE96(spectrum

A qualitative investigation of obese men\u27s experiences with their weight

Objectives: To investigate obese men\u27s health behaviors and strategies for change. Methods: Qualitative interviews with 36 men (BMI 30 and over). Results: All men felt personally responsible for their weight gain. Sedentary lifestyles, stress, lack of worklife balance and weight-based stigma were all significant causes of weight gain and barriers to weight loss. These factors also contributed to men\u27s unwillingness to seek help for their overweight. Conclusion: Addressing the self-blame and stigma associated with obesity is important in developing strategies to improve the health and well-being of obese men

Update on the hadron spectrum with two flavors of staggered quarks

We present an update on the MILC Collaboration's light hadron spectrum calculation with two flavors of dynamical, staggered quarks. We present extrapolations of the nucleon to rho mass ratio to the continuum limit for fixed values of the pi to rho mass ratio including the physical one.Comment: 3 pages, LaTex with espcrc2 and epsf, 5 postscript figures included, Lattice '97 Proceeding

Heavy-light decay constants---MILC results with the Wilson action

We present the current status of our ongoing calculations of pseudoscalar meson decay constants for mesons that contain one light and one heavy quark (f_B, f_{B_s}, f_D, f_{D_s}). We are currently generating new gauge configurations that include dynamical quarks and calculating the decay constants. In addition, we have several new results for the static approximation. Those results, as well as several refinements to the analysis, are new since Lattice '96. Our current (still preliminary) value for f_B is 156 +- 11 +- 30 +- 14 MeV, where the first error is from statistical and fitting errors, the second error is an estimate of other systematic errors within the quenched approximation and the third error is an estimate of the quenching error. For the ratio f_{B_s}/f_B, we get 1.11 +- 0.02 +- 0.03 +- 0.07.Comment: 8 pages, 9 figures, LaTeX, uses espcrs2, epsf, Invited talk presented by S. Gottlieb at Lattice QCD on Parallel Computers, University of Tsukuba, March, 1997, to appear in the proceeding