Particle-stabilized oscillating diver: a self-assembled responsive capsule

We report the experimental discovery of a self-assembled capsule, with density set by interfacial glass beads and an internal bubble, that automatically performs regular oscillations up and down a vial in response to a temperature gradient. Similar composites featuring interfacial particles and multiple internal compartments could be the solution to a variety of application challenges.Comment: 7 pages, 3 figure

Electric-field control of interfering transport pathways in a single-molecule anthraquinone transistor

It is understood that molecular conjugation plays an important role in charge transport through single-molecule junctions. Here, we investigate electron transport through an anthraquinone based single-molecule three-terminal device. With the use of an electric-field induced by a gate electrode, the molecule is reduced resulting into a ten-fold increase in the off-resonant differential conductance. Theoretical calculations link the change in differential conductance to a reduction-induced change in conjugation, thereby lifting destructive interference of transport pathways.Comment: Nano Letters (2015

Oxygen enhanced atomic chain formation

We report experimental evidence for atomic chain formation during stretching of atomic-sized contacts for gold and silver, that is strongly enhanced due to oxygen incorporation. While gold has been known for its tendency to form atomic chains, for silver this is only observed in the presence of oxygen. With oxygen the silver chains are as long as those for gold, but the conductance drops with chain length to about 0.1 conductance quantum. A relation is suggested with previous work on surface reconstructions for silver (110) surfaces after chemisorption of oxygen.Comment: 4 pages, 4 figure

Formation and properties of metal-oxygen atomic chains

Suspended chains consisting of single noble metal and oxygen atoms have been formed. We provide evidence that oxygen can react with and be incorporated into metallic one-dimensional atomic chains. Oxygen incorporation reinforces the linear bonds in the chain, which facilitates the creation of longer atomic chains. The mechanical and electrical properties of these diatomic chains have been investigated by determining local vibration modes of the chain and by measuring the dependence of the average chain-conductance on the length of the chain. Additionally, we have performed calculations that give insight in the physical mechanism of the oxygen-induced strengthening of the linear bonds and the conductance of the metal-oxygen chains.Comment: 10 pages, 9 fig

An optical linewidth study of a chromoprotein-C-phycocyanin in a low-temperature glass

The temperature dependence of spectral holes burnt into a phycocyanin-doped ethylene glycol/water glass is investigated in the temperature range between 1.5 and 15 K. The data are well described by a power law with an exponent of 1.16 ± 0.1. Chromoproteins thus behave very much the same as glasses doped with small impurity molecules

Vibrationally Induced Two-Level Systems in Single-Molecule Junctions

Single-molecule junctions are found to show anomalous spikes in dI/dV spectra. The position in energy of the spikes are related to local vibration mode energies. A model of vibrationally induced two-level systems reproduces the data very well. This mechanism is expected to be quite general for single-molecule junctions. It acts as an intrinsic amplification mechanism for local vibration mode features and may be exploited as a new spectroscopic tool.Comment: 4 pages, 4 figure

Role of an intermediate state in homogeneous nucleation

We explore the role of an intermediate state (phase) in homogeneous nucleation phenomenon by examining the decay process through a doubly-humped potential barrier. As a generic model we use the fourth- and sixth-order Landau potentials and analyze the Fokker-Planck equation for the one-dimensional thermal diffusion in the system characterized by a triple-well potential. In the low temperature case we apply the WKB method to the decay process and obtain the decay rate which is accurate for a wide range of depth and curvature of the middle well. In the case of a deep middle well, it reduces to a doubly-humped-barrier counterpart of the Kramers escape rate: the barrier height and the curvature of an initial well in the Kramers rate are replaced by the arithmetic mean of higher(or outer) and lower(or inner) partial barriers and the geometric mean of curvatures of the initial and intermediate wells, respectively. It seems to be a universal formula. In the case of a shallow-enough middle well, Kramers escape rate is alternatively evaluated within the standard framework of the mean-first-passage time problem, which certainly supports the WKB result. The criteria whether or not the existence of an intermediate state can enhance the decay rate are revealed.Comment: 9pages, 11figure