Thallium isotopes reveal protracted anoxia during the Toarcian (Early Jurassic) associated with volcanism, carbon burial, and mass extinction

For this study, we generated thallium (Tl) isotope records from two anoxic basins to track the earliest changes in global bottom water oxygen contents over the Toarcian Oceanic Anoxic Event (TOAE; ∼183 Ma) of the Early Jurassic. The T-OAE, like other Mesozoic OAEs, has been interpreted as an expansion of marine oxygen depletion based on indirect methods such as organic-rich facies, carbon isotope excursions, and biological turnover. Our Tl isotope data, however, reveal explicit evidence for earlier global marine deoxygenation of ocean water, some 600 ka before the classically defined T-OAE. This antecedent deoxygenation occurs at the Pliensbachian/Toarcian boundary and is coeval with the onset of initial large igneous province (LIP) volcanism and the initiation of a marine mass extinction. Thallium isotopes are also perturbed during the T-OAE interval, as defined by carbon isotopes, reflecting a second deoxygenation event that coincides with the acme of elevated marine mass extinctions and the main phase of LIP volcanism. This suggests that the duration of widespread anoxic bottom waters was at least 1 million years in duration and spanned early to middle Toarcian time. Thus, the Tl data reveal a more nuanced record of marine oxygen depletion and its links to biological change during a period of climatic warming in Earth’s past and highlight the role of oxygen depletion on past biological evolution

Mercury records covering the past 90 000 years from lakes Prespa and Ohrid, SE Europe

The element mercury (Hg) is a key pollutant, and much insight has been gained by studying the present-day Hg cycle. However, many important processes within this cycle operate on timescales responsive to centennial- to millennial-scale environmental variability, highlighting the importance of also investigating the longer-term Hg records in sedimentary archives. To this end, we here explore the timing, magnitude, and expression of Hg signals retained in sediments over the past ∼ 90 kyr from two lakes, linked by a subterranean karst system: Lake Prespa (Greece, North Macedonia, and Albania) and Lake Ohrid (North Macedonia and Albania). Results suggest that Hg fluctuations are largely independent of variability in common host phases in each lake, and the recorded sedimentary Hg signals show distinct differences first during the Late Pleistocene (Marine Isotope Stages 2–5). The Hg signals in Lake Prespa sediments highlight an abrupt, short-lived peak in Hg accumulation coinciding with local deglaciation. In contrast, Lake Ohrid shows a broader interval with enhanced Hg accumulation and, superimposed, a series of low-amplitude oscillations in Hg concentration peaking during the Last Glacial Maximum, which may result from elevated clastic inputs. Divergent Hg signals are also recorded during the Early and Middle Holocene (Marine Isotope Stage 1). Here, Lake Prespa sediments show a series of large Hg peaks, while Lake Ohrid sediments show a progression to lower Hg values. Since ∼ 3 ka, anthropogenic influences overwhelm local fluxes in both lakes. The lack of coherence in Hg accumulation between the two lakes suggests that, in the absence of an exceptional perturbation, local differences in sediment composition, lake structure, Hg sources, and water balance all influence the local Hg cycle and determine the extent to which Hg signals reflect local- or global-scale environmental changes

Sediment Cores from White Pond, South Carolina, contain a Platinum Anomaly, Pyrogenic Carbon Peak, and Coprophilous Spore Decline at 12.8 ka

A widespread platinum (Pt) anomaly was recently documented in Greenland ice and 11 North American sedimentary sequences at the onset of the Younger Dryas (YD) event (~12,800 cal yr BP), consistent with the YD Impact Hypothesis. We report high-resolution analyses of a 1-meter section of a lake core from White Pond, South Carolina, USA. After developing a Bayesian age-depth model that brackets the late Pleistocene through early Holocene, we analyzed and quantified the following: (1) Pt and palladium (Pd) abundance, (2) geochemistry of 58 elements, (3) coprophilous spores, (4) sedimentary organic matter (OC and sedaDNA), (5) stable isotopes of C (δ13C) and N (δ15N), (6) soot, (7) aciniform carbon, (8) cryptotephra, (9) mercury (Hg), and (10) magnetic susceptibility. We identified large Pt and Pt/Pd anomalies within a 2-cm section dated to the YD onset (12,785 ± 58 cal yr BP). These anomalies precede a decline in coprophilous spores and correlate with an abrupt peak in soot and C/OC ratios, indicative of large-scale regional biomass burning. We also observed a relatively large excursion in δ15N values, indicating rapid climatic and environmental/hydrological changes at the YD onset. Our results are consistent with the YD Impact Hypothesis and impact-related environmental and ecological changes

Organic carbon isotopes, total organic carbon contents and carbonate contents from a stratigraphic section of the Jurassic Fernie Formation located at the East Tributary of Bighorn Creek, Alberta, Canada

The Mesozoic Era experienced several instances of abrupt environmental change that are associated with instabilities in the climate, reorganizations of the global carbon cycle, and elevated extinction rates. Often during these perturbations, oxygen-deficient conditions developed in the oceans resulting in the widespread deposition of organic-rich sediments - these events are referred to as Oceanic Anoxic Events or OAEs. Such events have been linked to massive injections of greenhouse gases into the ocean- atmosphere system by transient episodes of voluminous volcanism and the destabilization of methane clathrates within marine environments. Nevertheless, uncertainty surrounds the specific environmental drivers and feedbacks that occurred during the OAEs that caused perturbations in the carbon cycle; this is particularly true of the Early Jurassic Toarcian OAE (ca. 183.1 Ma). Here, we present biostratigraphically constrained carbon isotope data from western North America (Alberta and British Columbia, Canada) to better assess the global extent of the carbon cycle perturbations. We identify the large negative carbon isotope excursion associated with the OAE along with high-frequency oscillations and steps within the onset of this excursion. We propose that these high-frequency carbon isotope excursions reflect changes to the global carbon cycle and also that they are related to the production and release of greenhouse gases from terrestrial environments on astronomical timescales. Furthermore, increased terrestrial methanogenesis should be considered an important climatic feedback during Ocean Anoxic Events and other similar events in Earth history after the proliferation of land plants

New evidence for a long Rhaetian from a Panthalassan succession (Wrangell Mountains, Alaska) and regional differences in carbon cycle perturbations at the Triassic-Jurassic transition

The end-Triassic mass extinction is one of the big five extinction events in Phanerozoic Earth history. It is linked with the emplacement of the Central Atlantic Magmatic Province and a host of interconnected environmental and climatic responses that caused profound deterioration of terrestrial and marine biospheres. Current understanding, however, is hampered by (i) a geographically limited set of localities and data; (ii) incomplete stratigraphic records caused by low relative sea-level in European sections during the Late Triassic and earliest Jurassic; and (iii) major discrepancies in the estimated duration of the latest Triassic Rhaetian that limit spatiotemporal evaluation of climatic and biotic responses locally and globally. Here, we investigate the Late Triassic–Early Jurassic time interval from a stratigraphically well-preserved sedimentary succession deposited in tropical oceanic Panthalassa. We present diverse new data from the lower McCarthy Formation exposed at Grotto Creek (Wrangell Mountains, southern Alaska), including ammonoid, bivalve, hydrozoan, and conodont biostratigraphy; organic carbon isotope (δ13Corg) stratigraphy; and CA-ID TIMS zircon U–Pb dates. These data are consistent with a Norian-Rhaetian Boundary (NRB) of ∼209 Ma, providing new evidence to support a long duration of the Rhaetian. They also constrain the Triassic-Jurassic boundary (TJB) to a ∼6 m interval in the section. Our TJB δ13Corg record from Grotto Creek, in conjunction with previous data, demonstrates consistent features that not only appear correlative on a global scale but also shows local heterogeneities compared to some Tethyan records. Notably, smaller excursions within a large negative carbon isotope excursion [NCIE] known from Tethyan localities are absent in Panthalassan records. This new comparative isotopic record becomes useful for (i) distinguishing regional overprinting of the global signal; (ii) raising questions about the ubiquity of smaller-scale NCIEs across the TJB; and (iii) highlighting the largely unresolved regional vs. global scale of some presumed carbon cycle perturbations. These paleontological and geochemical data establish the Grotto Creek section as an important Upper Triassic to Lower Jurassic succession due to its paleogeographic position and complete marine record. Our record represents the best documentation of the NRB and TJB intervals from Wrangellia, and likely the entire North American Cordillera

New evidence for a long Rhaetian from a Panthalassan succession (Wrangell Mountains, Alaska) and regional differences in carbon cycle perturbations at the Triassic-Jurassic transition

The end-Triassic mass extinction is one of the big five extinction events in Phanerozoic Earth history. It is linked with the emplacement of the Central Atlantic Magmatic Province and a host of interconnected environmental and climatic responses that caused profound deterioration of terrestrial and marine biospheres. Current understanding, however, is hampered by (i) a geographically limited set of localities and data; (ii) incomplete stratigraphic records caused by low relative sea-level in European sections during the Late Triassic and earliest Jurassic; and (iii) major discrepancies in the estimated duration of the latest Triassic Rhaetian that limit spatiotemporal evaluation of climatic and biotic responses locally and globally. Here, we investigate the Late Triassic–Early Jurassic time interval from a stratigraphically well-preserved sedimentary succession deposited in tropical oceanic Panthalassa. We present diverse new data from the lower McCarthy Formation exposed at Grotto Creek (Wrangell Mountains, southern Alaska), including ammonoid, bivalve, hydrozoan, and conodont biostratigraphy; organic carbon isotope (δ13Corg) stratigraphy; and CA-ID TIMS zircon U–Pb dates. These data are consistent with a Norian-Rhaetian Boundary (NRB) of ∼209 Ma, providing new evidence to support a long duration of the Rhaetian. They also constrain the Triassic-Jurassic boundary (TJB) to a ∼6 m interval in the section. Our TJB δ13Corg record from Grotto Creek, in conjunction with previous data, demonstrates consistent features that not only appear correlative on a global scale but also shows local heterogeneities compared to some Tethyan records. Notably, smaller excursions within a large negative carbon isotope excursion [NCIE] known from Tethyan localities are absent in Panthalassan records. This new comparative isotopic record becomes useful for (i) distinguishing regional overprinting of the global signal; (ii) raising questions about the ubiquity of smaller-scale NCIEs across the TJB; and (iii) highlighting the largely unresolved regional vs. global scale of some presumed carbon cycle perturbations. These paleontological and geochemical data establish the Grotto Creek section as an important Upper Triassic to Lower Jurassic succession due to its paleogeographic position and complete marine record. Our record represents the best documentation of the NRB and TJB intervals from Wrangellia, and likely the entire North American Cordillera