Shock wave study and theoretical modeling of the thermal decomposition of c-C4F8

The thermal dissociation of octafluorocyclobutane, c-C4F8, was studied in shock waves over the range 1150-2300 K by recording UV absorption signals of CF2. It was found that the primary reaction nearly exclusively produces 2 C2F4 which afterwards decomposes to 4 CF2. A primary reaction leading to CF2 + C3F6 is not detected (an upper limit to the yield of the latter channel was found to be about 10 percent). The temperature range of earlier single pulse shock wave experiments was extended. The reaction was shown to be close to its high pressure limit. Combining high and low temperature results leads to a rate constant for the primary dissociation of k1 = 1015.97 exp(-310.5 kJ mol-1/RT) s-1 in the range 630-1330 K, over which k1 varies over nearly 14 orders of magnitude. Calculations of the energetics of the reaction pathway and the rate constants support the conclusions from the experiments. Also they shed light on the role of the 1,4-biradical CF2CF2CF2CF2 as an intermediate of the reaction.Fil: Cobos, Carlos Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Hintzer, K.. Dyneon Gmbh; AlemaniaFil: Sölter, L.. Universität Göttingen; AlemaniaFil: Tellbach, E.. Universität Göttingen; AlemaniaFil: Thaler, A.. Dyneon Gmbh; AlemaniaFil: Troe, J.. Universität Göttingen; Alemania. Max-Planck-Institut fu¨r biophysikalische Chemie; Alemani

Prospects for Mirage Mediation

Mirage mediation reduces the fine-tuning in the minimal supersymmetric standard model by dynamically arranging a cancellation between anomaly-mediated and modulus-mediated supersymmetry breaking. We explore the conditions under which a mirage "messenger scale" is generated near the weak scale and the little hierarchy problem is solved. We do this by explicitly including the dynamics of the SUSY-breaking sector needed to cancel the cosmological constant. The most plausible scenario for generating a low mirage scale does not readily admit an extra-dimensional interpretation. We also review the possibilities for solving the mu/Bmu problem in such theories, a potential hidden source of fine-tuning.Comment: 14 page

Quasiparticle Description of Hot QCD at Finite Quark Chemical Potential

We study the extension of a phenomenologically successful quasiparticle model that describes lattice results of the equation of state of the deconfined phase of QCD for Tc <= T < 4 Tc, to finite quark chemical potential mu. The phase boundary line Tc(mu), the pressure difference (p(T,mu)-p(T,mu=0))/T^4 and the quark number density nq(T,mu)/T^3 are calculated and compared to recent lattice results. Good agreement is found up to quark chemical potentials of order mu = Tc.Comment: 12 pages, 7 figures; added reference

Combined effects of pressure and Ru substitution on BaFe2As2

The ab-plane resistivity of Ba(Fe1-xRux)2As2 (x = 0.00, 0.09, 0.16, 0.21, and 0.28) was studied under nearly hydrostatic pressures, up to 7.4 GPa, in order to explore the T-P phase diagram and to compare the combined effects of iso-electronic Ru substitution and pressure. The parent compound BaFe2As2 exhibits a structural/magnetic phase transition near 134 K. At ambient pressure, progressively increasing Ru concentration suppresses this phase transition to lower temperatures at the approximate rate of ~5 K/% Ru and is correlated with the emergence of superconductivity. By applying pressure to this system, a similar behavior is seen for each concentration: the structural/magnetic phase transition is further suppressed and superconductivity induced and ultimately, for larger x Ru and P, suppressed. A detailed comparison of the T-P phase diagrams for all Ru concentrations shows that 3 GPa of pressure is roughly equivalent to 10% Ru substitution. Furthermore, due to the sensitivity of Ba(Fe1-xRux)2As2 to pressure conditions, the melting of the liquid media, 4 : 6 light mineral oil : n-pentane and 1 : 1 iso-pentane : n-pentane, used in this study could be readily seen in the resistivity measurements. This feature was used to determine the freezing curves for these media and infer their room temperature, hydrostatic limits: 3.5 and 6.5 GPa, respectively.Comment: 27 pages, 19 figure

Why do people opt-out or not opt-out of automatic enrolment? A focus group study of automatic enrolment into a workplace pension in the United Kingdom

Automatic enrolment (AE) into a workplace pension is an important recent development in pension policy. An important question for this policy is why do people opt-out or not opt-out of AE? This question is important for understanding the power of suggestion associated with AE as well as responding to concerns that women might face undue pressure to opt-out. This article addresses this question through a focus group study into the United Kingdom’s new AE policy. Women were more likely than men to cite lack of affordability as a reason for opting out. Lack of information also seemed important for the power of suggestion associated with AE. Further research should explore how to make AE less gender blind as well as the types of information or advice that should be provided alongside AE

Nearly Optimal Private Convolution

We study computing the convolution of a private input $x$ with a public input $h$, while satisfying the guarantees of $(\epsilon, \delta)$-differential privacy. Convolution is a fundamental operation, intimately related to Fourier Transforms. In our setting, the private input may represent a time series of sensitive events or a histogram of a database of confidential personal information. Convolution then captures important primitives including linear filtering, which is an essential tool in time series analysis, and aggregation queries on projections of the data. We give a nearly optimal algorithm for computing convolutions while satisfying $(\epsilon, \delta)$-differential privacy. Surprisingly, we follow the simple strategy of adding independent Laplacian noise to each Fourier coefficient and bounding the privacy loss using the composition theorem of Dwork, Rothblum, and Vadhan. We derive a closed form expression for the optimal noise to add to each Fourier coefficient using convex programming duality. Our algorithm is very efficient -- it is essentially no more computationally expensive than a Fast Fourier Transform. To prove near optimality, we use the recent discrepancy lowerbounds of Muthukrishnan and Nikolov and derive a spectral lower bound using a characterization of discrepancy in terms of determinants

Gauge theory of Faddeev-Skyrme functionals

We study geometric variational problems for a class of nonlinear sigma-models in quantum field theory. Mathematically, one needs to minimize an energy functional on homotopy classes of maps from closed 3-manifolds into compact homogeneous spaces G/H. The minimizers are known as Hopfions and exhibit localized knot-like structure. Our main results include proving existence of Hopfions as finite energy Sobolev maps in each (generalized) homotopy class when the target space is a symmetric space. For more general spaces we obtain a weaker result on existence of minimizers in each 2-homotopy class. Our approach is based on representing maps into G/H by equivalence classes of flat connections. The equivalence is given by gauge symmetry on pullbacks of G-->G/H bundles. We work out a gauge calculus for connections under this symmetry, and use it to eliminate non-compactness from the minimization problem by fixing the gauge.Comment: 34 pages, no figure

Diboson-Jets and the Search for Resonant Zh Production

New particles at the TeV-scale may have sizeable decay rates into boosted Higgs bosons or other heavy scalars. Here, we investigate the possibility of identifying such processes when the Higgs/scalar subsequently decays into a pair of W bosons, constituting a highly distinctive "diboson-jet." These can appear as a simple dilepton (plus MET) configuration, as a two-prong jet with an embedded lepton, or as a four-prong jet. We study jet substructure methods to discriminate these objects from their dominant backgrounds. We then demonstrate the use of these techniques in the search for a heavy spin-one Z' boson, such as may arise from strong dynamics or an extended gauge sector, utilizing the decay chain Z' -> Zh -> Z(WW^(*)). We find that modes with multiple boosted hadronic Zs and Ws tend to offer the best prospects for the highest accessible masses. For 100/fb luminosity at the 14 TeV LHC, Z' decays into a standard 125 GeV Higgs can be observed with 5-sigma significance for masses of 1.5-2.5 TeV for a range of models. For a 200 GeV Higgs (requiring nonstandard couplings, such as fermiophobic), the reach may improve to up to 2.5-3.0 TeV.Comment: 23 pages plus appendices, 9 figure

Operator renewal theory and mixing rates for dynamical systems with infinite measure

We develop a theory of operator renewal sequences in the context of infinite ergodic theory. For large classes of dynamical systems preserving an infinite measure, we determine the asymptotic behaviour of iterates $L^n$ of the transfer operator. This was previously an intractable problem. Examples of systems covered by our results include (i) parabolic rational maps of the complex plane and (ii) (not necessarily Markovian) nonuniformly expanding interval maps with indifferent fixed points. In addition, we give a particularly simple proof of pointwise dual ergodicity (asymptotic behaviour of $\sum_{j=1}^nL^j$) for the class of systems under consideration. In certain situations, including Pomeau-Manneville intermittency maps, we obtain higher order expansions for $L^n$ and rates of mixing. Also, we obtain error estimates in the associated Dynkin-Lamperti arcsine laws.Comment: Preprint, August 2010. Revised August 2011. After publication, a minor error was pointed out by Kautzsch et al, arXiv:1404.5857. The updated version includes minor corrections in Sections 10 and 11, and corresponding modifications of certain statements in Section 1. All main results are unaffected. In particular, Sections 2-9 are unchanged from the published versio

After the Standard Model: New Resonances at the LHC

Experiments will soon start taking data at CERN's Large Hadron Collider (LHC) with high expectations for discovery of new physics phenomena. Indeed, the LHC's unprecedented center-of-mass energy will allow the experiments to probe an energy regime where the standard model is known to break down. In this article, the experiments' capability to observe new resonances in various channels is reviewed.Comment: Preprint version of a Brief Review for Modern Physics Letters A. Changes w.r.t. the fully corrected version are smal