9,357 research outputs found
Cl electrosorption on Ag(100): Lateral interactions and electrosorption valency from comparison of Monte Carlo simulations with chronocoulometry experiments
We present Monte Carlo Simulations using an equilibrium lattice-gas model for
the electrosorption of Cl on Ag(100) single-crystal surfaces. Fitting the
simulated isotherms to chronocoulometry experiments, we extract parameters such
as the electrosorption valency gamma and the next-nearest-neighbor lateral
interaction energy phi_nnn. Both coverage-dependent and coverage independent
gamma were previously studied assuming a constant phi_nnn [I. Abou Hamad, Th.
Wandlowski, G. Brown, P.A. Rikvold, J. Electroanal. Chem. 554-555 (2003) 211].
Here, a self-consistent, entirely electrostatic picture of the lateral
interactions with a coverage-dependent phi_nnn is developed, and a relationship
between phi_nnn and gamma is investigated for Cl on Ag(100).Comment: Accepted for publication in Electrochimica Acta, 10 pages, 7 figures,
2 tables and an appendi
Magnetisation distribution in the tetragonal phase of BaFe2As2
We have determined the spatial distribution of the magnetisation induced by a
field of 9 T in the tetragonal phase of BaFe2As2 using polarised neutron
diffraction. Magnetic structure factors derived from the polarisation
dependence of the intensities of Bragg reflections were used to make a maximum
entropy reconstruction of the distribution projected on the 110 plane. The
reconstruction shows clearly that the magnetisation is confined to the region
around the iron atoms and that there is no significant magnetisation associated
with either the As or Ba atoms. The distribution of magnetisation around the Fe
atom is significantly non-spherical with a shape which is extended in the
directions in the projection. These results show that the electrons which give
rise to the paramagnetic susceptibility are confined to the Fe atoms their
distribution suggests that they occupy 3d t_2g type orbitals with about 60% in
those of xy symmetry
The origin, hormonal nature, and action of hepatotrophic substances in portal venous blood
The hepatotrophic factors previously reported to be in splanchnic venous blood are pancreatic hormones and specifically insulin and glucagon. Of these, insulin is anabolic and glucagon is mainly catabolic but not exclusively so, since glucagon also has the anabolic effect of stimulating gluconeogenesis. The insulin glucagon relationship and the interrelationship of these hormones to others, such as epinephrine, in the moment to moment regulation of nutrient and hepatic homeostasis is a central fact of liver physiology that should reconcile a number of previously divergent opinions about portoprival syndromes, mechanisms of hepatic atrophy and hyperplasia, and the control of liver regeneration
Probing the radial temperature structure of protoplanetary disks with Herschel/HIFI
Herschel/HIFI spectroscopic observations of CO J=10-9, CO J=16-15 and [CII]
towards HD 100546 are presented. The objective is to resolve the velocity
profile of the lines to address the emitting region of the transitions and
directly probe the distribution of warm gas in the disk. The spectra reveal
double-peaked CO line profiles centered on the systemic velocity, consistent
with a disk origin. The J=16-15 line profile is broader than that of the J=10-9
line, which in turn is broader than those of lower J transitions (6-5, 3-2,
observed with APEX), thus showing a clear temperature gradient of the gas with
radius. A power-law flat disk model is used to fit the CO line profiles and the
CO rotational ladder simultaneously, yielding a temperature of T_0=1100 \pm 350
K (at r_0 = 13 AU) and an index of q=0.85 \pm 0.1 for the temperature radial
gradient. This indicates that the gas has a steeper radial temperature gradient
than the dust (mean q_{dust} ~ 0.5), providing further proof of the thermal
decoupling of gas and dust at the disk heights where the CO lines form. The
[CII] line profile shows a strong single-peaked profile red-shifted by 0.5 km
s-1 compared to the systemic velocity. We conclude that the bulk of the [CII]
emission has a non-disk origin (e.g., remnant envelope or diffuse cloud).Comment: Accepted for publication in ApJ
Sub-milliKelvin spatial thermometry of a single Doppler cooled ion in a Paul trap
We report on observations of thermal motion of a single, Doppler-cooled ion
along the axis of a linear radio-frequency quadrupole trap. We show that for a
harmonic potential the thermal occupation of energy levels leads to Gaussian
distribution of the ion's axial position. The dependence of the spatial thermal
spread on the trap potential is used for precise calibration of our imaging
system's point spread function and sub-milliKelvin thermometry. We employ this
technique to investigate the laser detuning dependence of the Doppler
temperature.Comment: 5 pages, 4 figure
Magnetization distribution and orbital moment in the non-Superconducting Chalcogenide Compound K0.8Fe1.6Se2
We have used polarized and unpolarized neutron diffraction to determine the
spatial distribution of the magnetization density induced by a magnetic field
of 9 T in the tetragonal phase of K0.8Fe1.6Se2. The maximum entropy
reconstruction shows clearly that most of the magnetization is confined to the
region around the iron atoms whereas there is no significant magnetization
associated with either Se or K atoms. The distribution of magnetization around
the Fe atom is slightly nonspherical with a shape which is extended along the
[0 0 1] direction in the projection. Multipolar refinement results show that
the electrons which give rise to the paramagnetic susceptibility are confined
to the Fe atoms and their distribution suggests that they occupy 3d t2g-type
orbitals with around 66% in those of xz/yz symmetry. Detail modeling of the
magnetic form factor indicates the presence of an orbital moment to the total
paramagnetic moment of Fe2+Comment: 7 pages, accepted for publication in Physical Review
Electrosorption of Br and Cl on Ag(100): Experiments and Computer Simulations
We present chronocoulometry experiments and equilibrium Monte Carlo
simulations for the electrosorption of Br and Cl on Ag(100) single-crystal
electrode surfaces. Two different methods are used to calculate the long-range
part of the adsorbate-adsorbate interactions. The first method is a
truncated-sum approach, while the second is a mean-field-enhanced truncated-sum
approach. To compare the two methods, the resulting isotherms are fit to
experimental adsorption isotherms, assuming both a constant electrosorption
valency &gamma and also a coverage-dependent &gamma. While a constant &gamma
fits the Br/Ag(100) well, a coverage-dependent or potential-dependent &gamma is
needed for Cl/Ag(100)
Lepton interferometry in relativistic heavy ion collisions - a case study
We propose intensity interferometry with identical lepton pairs as an
efficient tool for the estimation of the source size of the expanding hot zone
produced in relativistic heavy ion collisions. This can act as a complementary
method to two photon interferometry. The correlation function of two electrons
with the same helicity has been evaluated for RHIC energies. The thermal shift
of the rho meson mass has negligible effects on the HBT radii.Comment: 5 pages and 2 figure
Weekend admission and mortality for gastrointestinal disorders across England and Wales
BACKGROUND: Little has been reported on mortality following admissions at weekends for many gastrointestinal (GI) disorders. The aim was to establish whether GI disorders are susceptible to increased mortality following unscheduled admission on weekends compared with weekdays. METHODS: Record linkage was undertaken of national administrative inpatient and mortality data for people in England and Wales who were hospitalized as an emergency for one of 19 major GI disorders. RESULTS: The study included 2 254 701 people in England and 155 464 in Wales. For 11 general surgical and medical GI disorders there were little, or no, significant weekend effects on mortality at 30 days in either country. There were large consistent weekend effects in both countries for severe liver disease (England: 26·2 (95 per cent c.i. 21·1 to 31·6) per cent; Wales: 32·0 (12·4 to 55·1 per cent) and GI cancer (England: 21·8 (19·1 to 24·5) per cent; Wales: 25·0 (15·0 to 35·9) per cent), which were lower in patients managed by surgeons. Admission rates were lower at weekends than on weekdays, most strongly for severe liver disease (by 43·3 per cent in England and 51·4 per cent in Wales) and GI cancer (by 44·6 and 52·8 per cent respectively). Both mortality and the weekend mortality effect for GI cancer were lower for patients managed by surgeons. DISCUSSION: There is little, or no, evidence of a weekend mortality effect for most major general surgical or medical GI disorders, but large weekend effects for GI cancer and severe liver disease. Lower admission rates at weekends indicate more severe cases. The findings for severe liver disease may suggest a lack of specialist hepatological resources. For cancers, reduced availability of end-of-life care in the community at weekends may be the cause
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