Ultra-high sensitivity magnetic field and magnetization measurements with an atomic magnetometer

We describe an ultra-sensitive atomic magnetometer using optically-pumped potassium atoms operating in spin-exchange relaxation free (SERF) regime. We demonstrate magnetic field sensitivity of 160 aT/Hz$^{1/2}$ in a gradiometer arrangement with a measurement volume of 0.45 cm$^3$ and energy resolution per unit time of $44 \hbar$. As an example of a new application enabled by such a magnetometer we describe measurements of weak remnant rock magnetization as a function of temperature with a sensitivity on the order of 10$^{-10}$ emu/cm$^3$/Hz$^{1/2}$ and temperatures up to 420$^\circ$C

High-Fidelity Archeointensity Results for the Late Neolithic Period From Central China

Archeomagnetism focuses on exploring high-resolution variations of the geomagnetic field over hundreds to thousands of years. In this study, we carried out a comprehensive study of chronology, absolute and relative paleointensity on a late Neolithic site in central China. Ages of the samples are constrained to be ~3,500–3,000 BCE, a period when available paleointensity data are sparse. We present a total of 64 high-fidelity absolute paleointensities, demonstrating the field varied quickly from ~55 to ~90 ZAm2 between ~3,500–3,000 BCE. Our results record a new archeomagnetic jerk around 3,300 BCE, which is probably non-dipolar origin. The new results provide robust constraints on global geomagnetic models. We calculated a revised Chinese archeointensity reference curve for future application. The variations of absolute and relative paleointensity versus depth show good consistency, reinforcing the reliability of our results. This new attempt of combining absolute and relative paleointenstiy provides a useful tool for future archeomagnetic research

Chasing tails: Insights from micromagnetic modeling for thermomagnetic recording in non-uniform magnetic structures

Paleointensities are key to understanding the formation and evolution of Earth and are determined from rocks which record magnetic fields upon cooling; however, experimental protocols for estimating paleointensities frequently fail. The primary reason is that laboratory protocols assume that rocks are dominated by uniformly magnetized, single-domain grains, instead of much more common non-uniformly magnetized grains. Our model for larger grains shows a multiplicity of stable domain states; with preferred states changing as a function of temperature. We show that domain state distribution depends on the thermal history of the sample—in nature and the laboratory. From numerical thermomagnetic modeling, we show that particles with non-uniform domain states will theoretically fail standard experimental paleointensity protocols, preventing us from determining reliable ancient geomagnetic field intensities. We propose that recognizing this type of behavior, and the resulting bias, will yield more reliable paleointensity records, and a better understanding of the Earth

IODP Proposal 626: "Cenozoic Equatorial Age Transect – Following the Palaeo-equator"

As the largest ocean, the Pacific is intricately linked to major changes in the global climate system that took place during the Cenozoic. Throughout the Cenozoic the Pacific plate has had a northward component. Thus, the Pacific is unique, in that the thick sediment bulge of biogenic rich deposits from the currently narrowly focused zone of equatorial upwelling is slowly moving away from the equator. Hence, older sections are not deeply buried and can be recovered by drilling. Previous ODP Legs 138 and 199 were designed as transects across the paleo-equator in order to study the changing patterns of sediment deposition across equatorial regions, while this proposal aims to recover an orthogonal “age-transect” along the paleo-equator. Both previous legs were remarkably successful in giving us new insights into the workings of the climate and carbon system, productivity changes across the zone of divergence, time dependent calcium carbonate dissolution, bio- and magnetostratigraphy, the location of the ITCZ, and evolutionary patterns for times of climatic change and upheaval. Together with older DSDP drilling in the eastern equatorial Pacific, both Legs also helped to delineate the position of the paleo-equator and variations in sediment thickness from approximately 150°W to 110°W. As we have gained more information about the past movement of plates, and where in time “critical” climate events are located, we now propose to drill an age-transect (“flow-line”) along the position of the paleo-equator in the Pacific, targeting selected time-slices of interest where calcareous sediments have been preserved best. Leg 199 enhanced our understanding of extreme changes of the calcium carbonate compensation depth across major geological boundaries during the last 55 million years. A very shallow CCD during most of the Paleogene makes it difficult to obtain well preserved sediments, but we believe our siting strategy will allow us to drill the most promising sites and to obtain a unique sedimentary biogenic carbonate archive for time periods just after the Paleocene- Eocene boundary event, the Eocene cooling, the Eocene/Oligocene transition, the “one cold pole” Oligocene, the Oligocene-Miocene transition, and the Miocene, contributing to the objectives of the IODP Extreme Climates Initiative, and providing material that the previous legs were not able to recover

Chasing tails: Insights from micromagnetic modeling for thermomagnetic recording in non-uniform magnetic structures

Paleointensities are key to understanding the formation and evolution of Earth and are determined from rocks which record magnetic fields upon cooling; however, experimental protocols for estimating paleointensities frequently fail. The primary reason is that laboratory protocols assume that rocks are dominated by uniformly magnetized, single-domain grains, instead of much more common non-uniformly magnetized grains. Our model for larger grains shows a multiplicity of stable domain states; with preferred states changing as a function of temperature. We show that domain state distribution depends on the thermal history of the sample—in nature and the laboratory. From numerical thermomagnetic modeling, we show that particles with non-uniform domain states will theoretically fail standard experimental paleointensity protocols, preventing us from determining reliable ancient geomagnetic field intensities. We propose that recognizing this type of behavior, and the resulting bias, will yield more reliable paleointensity records, and a better understanding of the Earth

On improving the selection of Thellier-type paleointensity data

The selection of paleointensity data is a challenging, but essential step for establishing data reliability. There is, however, no consensus as to how best to quantify paleointensity data and which data selection processes are most effective. To address these issues, we begin to lay the foundations for a more unified and theoretically justified approach to the selection of paleointensity data. We present a new compilation of standard definitions for paleointensity statistics to help remove ambiguities in their calculation. We also compile the largest‐to‐date data set of raw paleointensity data from historical locations and laboratory control experiments with which to test the effectiveness of commonly used sets of selection criteria. Although most currently used criteria are capable of increasing the proportion of accurate results accepted, criteria that are better at excluding inaccurate results tend to perform poorly at including accurate results and vice versa. In the extreme case, one widely used set of criteria, which is used by default in the ThellierTool software (v4.22), excludes so many accurate results that it is often statistically indistinguishable from randomly selecting data. We demonstrate that, when modified according to recent single domain paleointensity predictions, criteria sets that are no better than a random selector can produce statistically significant increases in the acceptance of accurate results and represent effective selection criteria. The use of such theoretically derived modifications places the selection of paleointensity data on a more justifiable theoretical foundation and we encourage the use of the modified criteria over their original forms

Magnetic characterization of synthetic titanomagnetites: Quantifying the recording fidelity of ideal synthetic analogs

A series of four synthetic basalts comprising titanomagnetite (Fe3-xTixO4) grains of varied size and titanium content have been produced by a glass-ceramic method. Complementary characterization techniques of X-ray diffractometry, secondary electron microscopy, and transmission electron microscopy (TEM) demonstrate the reaction product composition consisted of mainly Fe3-xTixO4, pyroxene hedenbergite, fayalite, and SiO2. The samples exhibit bimodal distributions of larger (<2 µm) and smaller Fe3-xTixO4 particles (<50 nm in diameter), the latter found inside pyroxene crystals, as well as the sporadic occurance of dendritic Fe3-xTixO4 structures. Magnetic measurements show their bulk characteristics fall into two groups: Ti-rich titanomagnetite samples with varying Ti content; and near-stoichiometric magnetite. The TEM technique of off-axis electron holography allowed for visualization of the magnetic behavior of the synthetic Fe3-xTixO4 grains. Energy dispersive X-ray analysis and off-axis electron holography confirmed the small Fe3-xTixO4 grains (<50 nm) confined within glassy pyroxene regions to be Fe-rich and single domain, carrying strong magnetic signals, compared to the relatively magnetically weak larger Fe3-xTixO4 grains (x ∼ 0.6). The large grains in the pure magnetite sample are shown to be pseudo-single domain in nature. The quenching process involved in synthesis is considered similar to that of pillow basalts found at mid-ocean ridges and hence the reaction products are thought ideal in terms of characterization and understanding, for the purpose of studying natural systems