Stable isotopic analysis of atmospheric methane by infrared spectroscopy by use of diode laser difference-frequency generation

An infrared absorption spectrometer has been constructed to measure the stable isotopic composition of atmospheric methane samples. The spectrometer employs periodically poled lithium niobate to generate 15 μW of tunable difference-frequency radiation from two near-infrared diode lasers that probe the ν3 rotational-vibrational band of methane at 3.4 μm. To enhance the signal, methane is extracted from 25 l of air by use of a cryogenic chromatographic column and is expanded into the multipass cell for analysis. A measurement precision of 12‰ is demonstrated for both δ13C and δD

Accounting for decarbonisation and reducing capital at risk in the S&P500

This document is the Accepted Manuscript version of the following article: Colin Haslam, Nick Tsitsianis, Glen Lehman, Tord Andersson, and John Malamatenios, ‘Accounting for decarbonisation and reducing capital at risk in the S&P500’, Accounting Forum, Vol. 42 91): 119-129, March 2018. Under embargo until 7 August 2019. The final, definitive version is available online at doi: https://doi.org/10.1016/j.accfor.2018.01.004.This article accounts for carbon emissions in the S&P 500 and explores the extent to which capital is at risk from decarbonising value chains. At a global level it is proving difficult to decouple carbon emissions from GDP growth. Top-down legal and regulatory arrangements envisaged by the Kyoto Protocol are practically redundant given inconsistent political commitment to mitigating global climate change and promoting sustainability. The United Nations Environment Programme (UNEP) and European Commission (EC) are promoting the role of financial markets and financial institutions as drivers of behavioural change mobilising capital allocations to decarbonise corporate activity.Peer reviewe

Intrinsic Coulomb blockade in multi-wall carbon nanotubes

Carbon nanotubes provide a new class of molecular wires that display new and exciting mesoscopic transport properties. We provide a detailed theoretical description for transport in multi-wall nanotubes, where both disorder and strong interactions are important. The interplay of both aspects leads to a particularly effective intrinsic Coulomb blockade for tunneling. The relation to recent experiments is discussed.Comment: 13 pages, incl 2 figs, for: Special issue "Transport in Molecular Wires" in Chemical Physics, ed. by P. Hanggi, M. Ratner, S. Yalirak

dc Josephson Effect in Metallic Single-Walled Carbon Nanotubes

The dc Josephson effect is investigated in a single-walled metallic carbon nanotube connected to two superconducting leads. In particular, by using the Luttinger liquid theory, we analyze the effects of the electron-electron interaction on the supercurrent. We find that in the long junction limit the strong electronic correlations of the nanotube, together with its peculiar band structure, induce oscillations in the critical current as a function of the junction length and/or the nanotube electron filling. These oscillations represent a signature of the Luttinger liquid physics of the nanotube, for they are absent if the interaction is vanishing. We show that this effect can be exploited to reverse the sign of the supercurrent, realizing a tunable \pi-junction.Comment: 7 pages, 5 figure

Effects of magnetic field and disorder on electronic properties of Carbon Nanotubes

Electronic properties of metallic and semiconducting carbon nanotubes are investigated in presence of magnetic field perpendicular to the CN-axis, and disorder introduced through energy site randomness. The magnetic field field is shown to induce a metal-insulator transition (MIT) in absence of disorder, and surprisingly disorder does not affect significantly the MIT. These results may find confirmation through tunneling experimentsComment: 4 pages, 6 figures. Phys. Rev. B (in press

Role of Single Defects in Electronic Transport through Carbon Nanotube Field-Effect Transistors

The influence of defects on electron transport in single-wall carbon nanotube field effect transistors (CNFETs) is probed by combined scanning gate microscopy (SGM) and scanning impedance microscopy (SIM). SGM reveals a localized field effect at discrete defects along the CNFET length. The depletion surface potential of individual defects is quantified from the SGM-imaged radius of the defect as a function of tip bias voltage. This provides a measure of the Fermi level at the defect with zero tip voltage, which is as small as 20 meV for the strongest defects. The effect of defects on transport is probed by SIM as a function of backgate and tip-gate voltage. When the backgate voltage is set so the CNFET is "on" (conducting), SIM reveals a uniform potential drop along its length, consistent with diffusive transport. In contrast, when the CNFET is "off", potential steps develop at the position of depleted defects. Finally, high-resolution imaging of a second set of weak defects is achieved in a new "tip-gated" SIM mode.Comment: to appear in Physical Review Letter

Carbon cycle research after Kyoto

Recent progress in research of the global carbon cycle is reviewed and research needs for the immediate future are discussed, in light of the challenge posed to society to come to grips with the problem of man-made climate change. The carbon cycle in the oceans and on the land is reviewed, and how the atmosphere functions to couple them together. Major uncertainties still exist for any projection of the future atmospheric burden of carbon dioxide resulting from postulated emission scenarios of CO2. We present some ideas on how future policies designed to limit emissions or to sequester carbon can possibly be supported by scientific evidence of their effectiveness

Subband population in a single-wall carbon nanotube diode

We observe current rectification in a molecular diode consisting of a semiconducting single-wall carbon nanotube and an impurity. One half of the nanotube has no impurity, and it has a current-voltage (I-V) charcteristic of a typical semiconducting nanotube. The other half of the nanotube has the impurity on it, and its I-V characteristic is that of a diode. Current in the nanotube diode is carried by holes transported through the molecule's one-dimensional subbands. At 77 Kelvin we observe a step-wise increase in the current through the diode as a function of gate voltage, showing that we can control the number of occupied one-dimensional subbands through electrostatic doping.Comment: to appear in Physical Review Letters. 4 pages & 3 figure

Zo verkopen gemeenten hun vastgoed

Bijna elke gemeente heeft vastgoed in bezit dat uit de analyse komt rollen als niet-kernvoorraad dat vervolgens verkocht kan worden. Elke gemeente pakt dit op een eigen manier aan. Interessant om verschillende benaderingen de revue te laten passeren om vervolgens te kijken of er ook overeenkomsten zijn