2,642 research outputs found
A common behavior of thermoelectric layered cobaltites: incommensurate spin density wave states in [CaCoCuO][CoO] and [CaCoO][CoO]
Magnetism of a misfit layered cobaltite
[CaCoCuO][CoO] ( 0.62, RS
denotes a rocksalt-type block) was investigated by a positive muon spin
rotation and relaxation (SR) experiment. A transition to an
incommensurate ({\sf IC}) spin density wave ({\sf SDW}) state was found below
180 K (= ); and a clear oscillation due to a static
internal magnetic field was observed below 140 K (= ). Furthermore,
an anisotropic behavior of the zero-field SR experiment indicated that
the {\sf IC-SDW} propagates in the - plane, with oscillating moments
directed along the c axis. These results were quite similar to those for the
related compound [CaCoO][CoO], {\sl i.e.},
CaCoO. Since the {\sf IC-SDW} field in
[CaCoCuO][CoO] was approximately
same to those in pure and doped [CaCoO][CoO], it
was concluded that the {\sf IC-SDW} exist in the [CoO] planes.Comment: 15 pages, 6 figures. accepted for publication in J. Phys.: Condens.
Matte
Hidden magnetic transitions in thermoelectric layered cobaltite, [CaCoO][CoO]
A positive muon spin rotation and relaxation (SR) experiment on
[CaCoO][CoO], ({\sl i.e.}, CaCoO, a layered
thermoelectric cobaltite) indicates the existence of two magnetic transitions
at 100 K and 400 - 600 K; the former is a transition from a paramagnetic
state to an incommensurate ({\sf IC}) spin density wave ({\sf SDW}) state. The
anisotropic behavior of zero-field SR spectra at 5 K suggests that the
{\sf IC-SDW} propagates in the - plane, with oscillating moments directed
along the c-axis; also the {\sf IC-SDW} is found to exist not in the
[CaCoO] subsystem but in the [CoO] subsystem. In addition, it is
found that the long-range {\sf IC-SDW} order completes below 30 K,
whereas the short-range order appears below 100 K. The latter transition is
interpreted as a gradual change in the spin state of Co ions %% at temperatures
above 400 K. These two magnetic transitions detected by SR are found to
correlate closely with the transport properties of
[CaCoO][CoO].Comment: 7 pages, 8 figures. to be appeared in Phys. Rev.
Thermoelectric performance of n-type Mg2Ge
Magnesium-based thermoelectric materials (Mg2X, X = Si, Ge, Sn) have received considerable attention due to their availability, low toxicity, and reasonably good thermoelectric performance. The synthesis of these materials with high purity is challenging, however, due to the reactive nature and high vapour pressure of magnesium. In the current study, high purity single phase n-type Mg2Ge has been fabricated through a one-step reaction of MgH2 and elemental Ge, using spark plasma sintering (SPS) to reduce the formation of magnesium oxides due to the liberation of hydrogen. We have found that Bi has a very limited solubility in Mg2Ge and results in the precipitation of Mg2Bi3. Bismuth doping increases the electrical conductivity of Mg2Ge up to its solubility limit, beyond which the variation is minimal. The main improvement in the thermoelectric performance is originated from the significant phonon scattering achieved by the Mg2Bi3 precipitates located mainly at grain boundaries. This reduces the lattice thermal conductivity by ~50% and increases the maximum zT for n-type Mg2Ge to 0.32, compared to previously reported maximum value of 0.2 for Sb-doped Mg2Ge
Hexyl aminolevulinate, 5-aminolevulinic acid nanoemulsion, and methyl aminolevulinate in photodynamic therapy of non-aggressive basal cell carcinomas: A non-sponsored, randomized, prospective and double-blinded trial
Abstract Background In the photodynamic therapy (PDT) of non-aggressive basal cell carcinomas (BCCs), 5-aminolevulinic acid nanoemulsion (BF-200ALA) has shown non-inferior efficacy when compared with methyl aminolevulinate (MAL), a widely used photosensitizer. Hexyl aminolevulinate (HAL) is an interesting alternative photosensitizer. To our knowledge, this is the first study using HAL-PDT in the treatment of BCCs. Objectives To compare the histological clearance, tolerability (pain and post-treatment reaction), and cosmetic outcome of MAL, BF-200 ALA, and low-concentration HAL in the PDT of non-aggressive BCCs. Methods Ninety-eight histologically verified non-aggressive BCCs met the inclusion criteria, and 54 patients with 95 lesions completed the study. The lesions were randomized to receive LED-PDT in two repeated treatments with MAL, BF-200 ALA, or HAL. Efficacy was assessed both clinically and confirmed histologically at three months by blinded observers. Furthermore, cosmetic outcome, pain, post-treatment reactions fluorescence, and photobleaching were evaluated. Results According to intention-to-treat analyses, the histologically confirmed lesion clearance was 93.8% (95% confidence interval [CI] = 79.9?98.3) for MAL, 90.9% (95% CI = 76.4?96.9) for BF-200 ALA, and 87.9% (95% CI = 72.7?95.2) for HAL, with no differences between the arms (p=0.84). There were no differences between the arms as regards pain, post-treatment reactions, or cosmetic outcome. Conclusions PDT with low-concentration HAL and BF-200 ALA have a similar efficacy, tolerability, and cosmetic outcome compared to MAL. HAL is an interesting new option in dermatological PDT, since good efficacy is achieved with a low concentration.Peer reviewe
Spectroscopy of Heavy Mesons Expanded in 1/m_Q
Operating just once with the naive Foldy-Wouthuysen-Tani transformation on
the relativistic Fermi-Yang equation for bound states described by
the semi-relativistic Hamiltonian which includes Coulomb-like as well as
confining scalar potentials, we have calculated heavy meson mass spectra of D
and B together with higher spin states. Based on the formulation recently
proposed, their masses and wave functions are expanded up to the second order
in with a heavy quark mass and the lowest order equation is
examined carefully to obtain a complete set of eigenfunctions for the
Schr\"odinger equation. Heavy quark effective theory parameters, ,
, and , are also determined at the first and second order
in .Comment: 49 pages, 5 epsf figure
Post-Stall Aerodynamic Modeling and Gain-Scheduled Control Design
A multidisciplinary research e.ort that combines aerodynamic modeling and gain-scheduled control design for aircraft flight at post-stall conditions is described. The aerodynamic modeling uses a decambering approach for rapid prediction of post-stall aerodynamic characteristics of multiple-wing con.gurations using known section data. The approach is successful in bringing to light multiple solutions at post-stall angles of attack right during the iteration process. The predictions agree fairly well with experimental results from wind tunnel tests. The control research was focused on actuator saturation and .ight transition between low and high angles of attack regions for near- and post-stall aircraft using advanced LPV control techniques. The new control approaches maintain adequate control capability to handle high angle of attack aircraft control with stability and performance guarantee
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