38 research outputs found

    Comparative study of stripe magnetic domains in epitaxial Ni(111) and Co(0001) films

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    The evolution of stripe magnetic domain structures observed by magnetic force microscopy on epitaxial Ni(111) and Co(0001) films as a function of film thickness is successfully explained by a periodic one-dimensional model with tilted partial flux closure domains. The model predicts a sizable fraction of the magnetization not being parallel to the film’s normal, which consequentially results in an in-plane magnetization in agreement with the experimentally observed magnetization for these films. © 2002 American Institute of Physics.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/69860/2/JAPIAU-91-10-7550-1.pd

    Ferromagnetism at 300 K in spin-coated films of Co doped anatase and rutile TiO2

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    Thin films of Ti1-xCoxO2 (x=0 and 0.03) have been prepared on sapphire substrates by spin-on technique starting from metalorganic precursors. When heat treated in air at 550 and 700 C respectively, these films present pure anatase and rutile structures as shown both by X-ray diffraction and Raman spectroscopy. Optical absorption indicate a high degree of transparency in the visible region. Such films show a very small magnetic moment at 300 K. However, when the anatase and the rutile films are annealed in a vacuum of 1x10-5 Torr at 500 oC and 600 oC respectively, the magnetic moment, at 300 K, is strongly enhanced reaching 0.36 B/Co for the anatase sample and 0.68 B/Co for the rutile one. The ferromagnetic Curie temperature of these samples is above 350 K.Comment: 31 july 200

    Determination of Magnetic Exchange Stiffness and Surface Anisotropy Constants in Epitaxial Ni_ {1-x} Co_ {x}(001) Films

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    Magnetic characteristics of epitaxial Ni1-xCox(001) (x=0, 0.16, and 0.50) films with nominal 200 nm thickness on Cu(001)/Si(100) substrates have been investigated by magnetization and ferromagnetic resonance measurements in order to better clarify the rationale for the large variation in the magnetic exchange stiffness constant A, previously determined from different measurements. The exchange constant as well as the saturation magnetization, effective demagnetizing field, fourth-order magnetocrystalline, and second-order perpendicular uniaxial magnetic anisotropy fields has been determined. The analyses of low-temperature saturation magnetization data on these films yield A values that increase from 0.82×10-6erg/cm for a pure Ni film to 2.27×10-6erg/cm for the Ni0.50Co0.50 film. Furthermore, spin-wave resonance volume modes observed in x=0 and 0.16 films indicate that the surface plays a role in the exchange stiffness constant determination as the surface anisotropy constants are found to be approximately 1 and 4 erg/cm2, respectively. The latter value is substantially larger than that for any other system reported so far

    Ferromagnetism at 300 K in spin-coated anatasea and rutile Ti0.95Fe0.05O2 films

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    Thin films of Ti1-xFexO2 (x=0 and 0.05) have been prepared on sapphire substrates by spin-on technique starting from metal organic precursors. When heat treated in air at 550 and 700 degrees C respectively, these films present pure anatase and rutile structures as shown both by X-ray diffraction and Raman spectroscopy. Optical absorption indicate a high degree of transparency in the visible region. Such films show a very small magnetic moment at 300 K. However, when the anatase and the rutile films are annealed in a vacuum of 1x10-5 Torr at 500 degrees C and 600 degrees C respectively, the magnetic moment, at 300 K, is strongly enhanced reaching 0.46 μ\muB/Fe for the anatase sample and 0.48 μ\muB/Fe for the rutile one. The ferromagnetic Curie temperature of these samples is above 350 K.Comment: 13 october 200

    Room temperature ferromagnetism in spin-coated anatase- and rutile-Ti0.95Fe0.05O2 films

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    Thin films of Ti1−xFexO2 (x = 0 and 0.05) have been prepared on sapphire substrates by the spin-on technique starting from metal–organic precursors. When heat treated in air at 550 and 700 °C respectively, these films present pure anatase and rutile structures as shown both by x-ray diffraction and Raman spectroscopy. Optical absorption indicates a high degree of transparency in the visible region. Such films show a very small magnetic moment at 300 K. However, when the anatase and the rutile films are annealed in a vacuum of 1 × 10−5 Torr at 500 and 600 °C respectively, the magnetic moment, at 300 K, is strongly enhanced, reaching 0.46 μB/Fe for the anatase sample and 0.48 μB/Fe for the rutile one. The ferromagnetic Curie temperature of these samples is above 350 K. When the ferromagnetic rutile sample is reheated in air, the magnetic moment reduces strongly. The data seem to indicate that oxygen defects created as a result of vacuum annealing may be responsible for the observed ferromagnetism in our samples.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/48892/2/cm5_4_017.pd

    Forecasting: theory and practice

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    Forecasting has always been at the forefront of decision making and planning. The uncertainty that surrounds the future is both exciting and challenging, with individuals and organisations seeking to minimise risks and maximise utilities. The large number of forecasting applications calls for a diverse set of forecasting methods to tackle real-life challenges. This article provides a non-systematic review of the theory and the practice of forecasting. We provide an overview of a wide range of theoretical, state-of-the-art models, methods, principles, and approaches to prepare, produce, organise, and evaluate forecasts. We then demonstrate how such theoretical concepts are applied in a variety of real-life contexts. We do not claim that this review is an exhaustive list of methods and applications. However, we wish that our encyclopedic presentation will offer a point of reference for the rich work that has been undertaken over the last decades, with some key insights for the future of forecasting theory and practice. Given its encyclopedic nature, the intended mode of reading is non-linear. We offer cross-references to allow the readers to navigate through the various topics. We complement the theoretical concepts and applications covered by large lists of free or open-source software implementations and publicly-available databases

    Forecasting: theory and practice

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    Forecasting has always been in the forefront of decision making and planning. The uncertainty that surrounds the future is both exciting and challenging, with individuals and organisations seeking to minimise risks and maximise utilities. The lack of a free-lunch theorem implies the need for a diverse set of forecasting methods to tackle an array of applications. This unique article provides a non-systematic review of the theory and the practice of forecasting. We offer a wide range of theoretical, state-of-the-art models, methods, principles, and approaches to prepare, produce, organise, and evaluate forecasts. We then demonstrate how such theoretical concepts are applied in a variety of real-life contexts, including operations, economics, finance, energy, environment, and social good. We do not claim that this review is an exhaustive list of methods and applications. The list was compiled based on the expertise and interests of the authors. However, we wish that our encyclopedic presentation will offer a point of reference for the rich work that has been undertaken over the last decades, with some key insights for the future of the forecasting theory and practice

    A feature-based framework for detecting technical outliers in water-quality data from in situ sensors

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    Outliers due to technical errors in water-quality data from in situ sensors can reduce data quality and have a direct impact on inference drawn from subsequent data analysis. However, outlier detection through manual monitoring is unfeasible given the volume and velocity of data the sensors produce. Here, we proposed an automated framework that provides early detection of outliers in water-quality data from in situ sensors caused by technical issues.The framework was used first to identify the data features that differentiate outlying instances from typical behaviours. Then statistical transformations were applied to make the outlying instances stand out in transformed data space. Unsupervised outlier scoring techniques were then applied to the transformed data space and an approach based on extreme value theory was used to calculate a threshold for each potential outlier. Using two data sets obtained from in situ sensors in rivers flowing into the Great Barrier Reef lagoon, Australia, we showed that the proposed framework successfully identified outliers involving abrupt changes in turbidity, conductivity and river level, including sudden spikes, sudden isolated drops and level shifts, while maintaining very low false detection rates. We implemented this framework in the open source R package oddwater
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