Recent advances in homogeneous catalysis via metal–ligand cooperation involving aromatization and dearomatization

Recently, an increasing number of metal complex catalysts have been developed to achieve the activation or transformation of substrates based on cooperation between the metal atom and its ligands. In such “cooperative catalysis, ” the ligand not only is bound to the metal, where it exerts steric and electronic effects, but also functionally varies its structure during the elementary processes of the catalytic reaction. In this review article, we focus on metal–ligand cooperation involving aromatization and dearomatization of the ligand, thus introducing the newest developments and examples of homogeneous catalytic reactions

Physical Phenomenology of Phyllotaxis

We propose an evolutionary mechanism of phyllotaxis, regular arrangement of leaves on a plant stem. It is shown that the phyllotactic pattern with the Fibonacci sequence has a selective advantage, for it involves the least number of phyllotactic transitions during plant growth

Introduction of Low-Carbon Community Energy Systems by Combining Information Networks and Cogeneration-Type District Heating and Cooling Systems

Achievement of a low-carbon society is becoming extremely important. In this report, we introduce an example of carbon dioxide (CO2) emission reductions and energy savings, using a local energy-control system. Our research is focused on the town of Shinchi in the Fukushima Prefecture, Japan. Shinchi is pursuing initiatives to create a low-carbon, energy-efficient society and a disaster-resilient community. The National Institute for Environmental Studies provides academic support for the design and planning of low-carbon community energy systems by the local government of Shinchi, based on the Basic Cooperation Agreement. For the redevelopment of the Japan Railway (JR) Shinchi Station district that is being carried out, construction of a cogeneration-type district heating and cooling system is currently in progress. CO2 reductions of about 20% can be expected by introducing this community energy system. To support these initiatives, we have developed an information and communication technology (ICT) system that shares a wide range of local information to support energy conservation. By analyzing electricity consumption data from the ICT, we evaluated the pattern of residential power consumption and confirmed that the project supports energy-saving behavior within the community. Additionally, the community energy project in the JR Shinchi Station district enables adjustment of the supply and demand balance