133 research outputs found
Molecular vibration in cold collision theory
Cold collisions of ground state oxygen molecules with Helium have been
investigated in a wide range of cold collision energies (from 1 K up to 10
K) treating the oxygen molecule first as a rigid rotor and then introducing the
vibrational degree of freedom. The comparison between the two models shows that
at low energies the rigid rotor approximation is very accurate and able to
describe all the dynamical features of the system. The comparison between the
two models has also been extended to cases where the interaction potential He -
O is made artificially stronger. In this case vibration can perturb rate
constants, but fine-tuning the rigid rotor potential can alleviate the
discrepancies between the two models.Comment: 11 pages, 3 figure
Bose-Einstein condensation in trapped dipolar gases
We discuss Bose-Einstein condensation in a trapped gas of bosonic particles
interacting dominantly via dipole-dipole forces. We find that in this case the
mean-field interparticle interaction and, hence, the stability diagram are
governed by the trapping geometry. Possible physical realisations include
ultracold heteronuclear molecules, or atoms with laser induced electric dipole
moments.Comment: 4 pages, 4 figure
Photoassociation inside an optical dipole trap: absolute rate coefficients and Franck-Condon factors
We present quantitative measurements of the photoassociation of cesium
molecules inside a far-detuned optical dipole trap. A model of the trap
depletion dynamics is derived which allows to extract absolute photoassociation
rate coefficients for the initial single-photon photoassociation step from
measured trap-loss spectra. The sensitivity of this approach is demonstrated by
measuring the Franck-Condon modulation of the weak photoassociation transitions
into the low vibrational levels of the outer well of the 0g- state that
correlates to the 6s+6p3/2 asymptote. The measurements are compared to
theoretical predictions. In a magneto-optical trap these transitions have
previously only been observed indirectly through ionization of ground state
molecules
Hyperfine Spectroscopy of Optically Trapped Atoms
We perform spectroscopy on the hyperfine splitting of Rb atoms trapped
in far-off-resonance optical traps. The existence of a spatially dependent
shift in the energy levels is shown to induce an inherent dephasing effect,
which causes a broadening of the spectroscopic line and hence an inhomogeneous
loss of atomic coherence at a much faster rate than the homogeneous one caused
by spontaneous photon scattering. We present here a number of approaches for
reducing this inhomogeneous broadening, based on trap geometry, additional
laser fields, and novel microwave pulse sequences. We then show how hyperfine
spectroscopy can be used to study quantum dynamics of optically trapped atoms.Comment: Review/Tutoria
Experimental Implementation of the Deutsch-Jozsa Algorithm for Three-Qubit Functions using Pure Coherent Molecular Superpositions
The Deutsch-Jozsa algorithm is experimentally demonstrated for three-qubit
functions using pure coherent superpositions of Li rovibrational
eigenstates. The function's character, either constant or balanced, is
evaluated by first imprinting the function, using a phase-shaped femtosecond
pulse, on a coherent superposition of the molecular states, and then projecting
the superposition onto an ionic final state, using a second femtosecond pulse
at a specific time delay
Chemical reactivity of ultracold polar molecules: investigation of H + HCl and H + DCl collisions
Quantum scattering calculations are reported for the H+HCl(v,j=0) and
H+DCl(v,j=0) collisions for vibrational levels v=0-2 of the diatoms.
Calculations were performed for incident kinetic energies in the range 10-7 to
10-1 eV, for total angular momentum J=0 and s-wave scattering in the entrance
channel of the collisions. Cross sections and rate coefficients are
characterized by resonance structures due to quasibound states associated with
the formation of the H...HCl and H...DCl van der Waals complexes in the
incident channel. For the H+HCl(v,j=0) collision for v=1,2, reactive scattering
leading to H_2 formation is found to dominate over non-reactive vibrational
quenching in the ultracold regime. Vibrational excitation of HCl from v=0 to
v=2 increases the zero-temperature limiting rate coefficient by about 8 orders
of magnitude.Comment: 9 pages, 6 figures, submitted to Euro. Phys. J. topical issue on
"Ultracold Polar Molecules: Formation and Collisions
Macrodimers: ultralong range Rydberg molecules
We study long range interactions between two Rydberg atoms and predict the
existence of ultralong range Rydberg dimers with equilibrium distances of many
thousand Bohr radii. We calculate the dispersion coefficients ,
and for two rubidium atoms in the same excited level , and find
that they scale like , and , respectively. We show that
for certain molecular symmetries, these coefficients lead to long range
potential wells that can support molecular bound levels. Such macrodimers would
be very sensitive to their environment, and could probe weak interactions. We
suggest experiments to detect these macrodimers.Comment: 4 pages, submitted to PR
Quantum computation with trapped polar molecules
We propose a novel physical realization of a quantum computer. The qubits are
electric dipole moments of ultracold diatomic molecules, oriented along or
against an external electric field. Individual molecules are held in a 1-D trap
array, with an electric field gradient allowing spectroscopic addressing of
each site. Bits are coupled via the electric dipole-dipole interaction. Using
technologies similar to those already demonstrated, this design can plausibly
lead to a quantum computer with qubits, which can perform CNOT gates in the anticipated decoherence time of s.Comment: 4 pages, RevTeX 4, 2 figures. Edited for length and converted to
RevTeX, but no substantial changes from earlier pdf versio
Rotational master equation for cold laser-driven molecules
The equations of motion for the molecular rotation are derived for
vibrationally cold dimers that are polarized by off-resonant laser light. It is
shown that, by eliminating electronic and vibrational degrees of freedom, a
quantum master equation for the reduced rotational density operator can be
obtained. The coherent rotational dynamics is caused by stimulated Raman
transitions, whereas spontaneous Raman transitions lead to decoherence in the
motion of the quantized angular momentum. As an example the molecular dynamics
for the optical Kerr effect is chosen, revealing decoherence and heating of the
molecular rotation.Comment: 11 pages, 5 figures, to appear in Phys. Rev.
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