53 research outputs found
Fermi-level pinning in ErAs nanoparticles embedded in III-V semiconductors
Embedding rare-earth pnictide (RE-V) nanoparticles into III-V semiconductors
enables unique optical, electrical, and thermal properties, with applications
in THz photoconductive switches, tunnel junctions, and thermoelectric devices.
Despite the high structural quality and control over growth, particle size, and
density, the underlying electronic structure of these nanocomposite materials
has only been hypothesized. Basic questions about the metallic or
semiconducting nature of the nanoparticles (that are typically < 3 nm in
diameter) have remained unanswered. Using first-principles calculations, we
investigated the structural and electronic properties of ErAs nanoparticles in
AlAs, GaAs, InAs, and their alloys. Formation energies of the ErAs
nanoparticles with different shapes and sizes (i.e., from cubic to spherical,
with 1.14 nm, 1.71 nm, and 2.28 nm diameters) show that spherical nanoparticles
are the most energetically favorable. As the diameter increases, the Fermi
level is lowered from near the conduction band to the middle of the gap. For
the lowest energy nanoparticles, the Fermi level is pinned near the mid-gap, at
about 0.8 eV above the valence band in GaAs and about 1.2 eV in AlAs, and it is
resonant in the conduction band in InAs. Our results show that the Fermi level
is pinned on an absolute energy scale once the band alignment at AlAs/GaAs/InAs
interfaces is considered, offering insights into the rational design of these
nanocomposite materials
The supply chain of violence
Every year, more people are killed defending the environment than are soldiers from the United Kingdom and Australia on overseas deployments in war zones combined. During the last 15 years, the number of both deaths of environmental defenders, and the countries where they occur, have increased. Recorded deaths have increased from two per week to four per week over this period. These deaths are primarily related to conflict over natural resources, across a range of sectors. Of 683 total deaths, >230 were related to mining and agribusiness between 2014 and 2017. We find that rule of law and corruption indices are closely linked to patterns of killings. Using spatial data, we investigate the drivers of these conflicts and violence and seek to identify who may be most at risk and why. We argue that businesses, investors and national governments at both ends of the chain of violence need to be more accountable
Errors in ‘BED’-Derived Estimates of HIV Incidence Will Vary by Place, Time and Age
The BED Capture Enzyme Immunoassay, believed to distinguish recent HIV infections, is being used to estimate HIV incidence, although an important property of the test--how specificity changes with time since infection--has not been not measured.We construct hypothetical scenarios for the performance of BED test, consistent with current knowledge, and explore how this could influence errors in BED estimates of incidence using a mathematical model of six African countries. The model is also used to determine the conditions and the sample sizes required for the BED test to reliably detect trends in HIV incidence.If the chance of misclassification by BED increases with time since infection, the overall proportion of individuals misclassified could vary widely between countries, over time, and across age-groups, in a manner determined by the historic course of the epidemic and the age-pattern of incidence. Under some circumstances, changes in BED estimates over time can approximately track actual changes in incidence, but large sample sizes (50,000+) will be required for recorded changes to be statistically significant.The relationship between BED test specificity and time since infection has not been fully measured, but, if it decreases, errors in estimates of incidence could vary by place, time and age-group. This means that post-assay adjustment procedures using parameters from different populations or at different times may not be valid. Further research is urgently needed into the properties of the BED test, and the rate of misclassification in a wide range of populations
Optimal Uses of Antiretrovirals for Prevention in HIV-1 Serodiscordant Heterosexual Couples in South Africa: A Modelling Study
Hallett et al use a mathematical model to examine the long-term impact and cost-effectiveness of different pre-exposure prophylaxis (PrEP) strategies for HIV prevention in serodiscordant couples
Meat consumption, health and the environment
Both the global average per capita consumption of meat and the total amount of meat consumed are rising, driven by increasing average individual incomes and by population growth. The consumption of different types of meat and meat products has substantial effects on people’s health, and livestock production can have major negative effects on the environment. Here, we explore the evidence base for these assertions and the options policy-makers have should they wish to intervene to affect population meat consumption. We highlight where more research is required and the great importance of integrating insights from the natural and social sciences
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