The evolution and storage of primitive melts in the Eastern Volcanic Zone of Iceland: the 10 ka Grímsvötn tephra series (i.e. the Saksunarvatn ash)

Major, trace and volatile elements were measured in a suite of primitive macrocrysts and melt inclusions from the thickest layer of the 10 ka Grímsvötn tephra series (i.e. Saksunarvatn ash) at Lake Hvítárvatn in central Iceland. In the absence of primitive tholeiitic eruptions (MgO > 7 wt.%) within the Eastern Volcanic Zone (EVZ) of Iceland, these crystal and inclusion compositions provide an important insight into magmatic processes in this volcanically productive region. Matrix glass compositions show strong similarities with glass compositions from the AD 1783–84 Laki eruption, confirming the affinity of the tephra series with the Grímsvötn volcanic system. Macrocrysts can be divided into a primitive assemblage of zoned macrocryst cores (An_78–An_92, Mg#_cpx = 82–87, Fo_79.5–Fo_87) and an evolved assemblage consisting of unzoned macrocrysts and the rims of zoned macrocrysts (An_60–An_68, Mg#_cpx = 71–78, Fo_70–Fo_76). Although the evolved assemblage is close to being in equilibrium with the matrix glass, trace element disequilibrium between primitive and evolved assemblages indicates that they were derived from different distributions of mantle melt compositions. Juxtaposition of disequilibrium assemblages probably occurred during disaggregation of incompatible trace element-depleted mushes (mean La/Yb_melt = 2.1) into aphyric and incompatible trace element-enriched liquids (La/Yb_melt = 3.6) shortly before the growth of the evolved macrocryst assemblage. Post-entrapment modification of plagioclase-hosted melt inclusions has been minimal and high-Mg# inclusions record differentiation and mixing of compositionally variable mantle melts that are amongst the most primitive liquids known from the EVZ. Coupled high field strength element (HFSE) depletion and incompatible trace element enrichment in a subset of primitive plagioclase-hosted melt inclusions can be accounted for by inclusion formation following plagioclase dissolution driven by interaction with plagioclase-undersaturated melts. Thermobarometric calculations indicate that final crystal-melt equilibration within the evolved assemblage occurred at ~1140°C and 0.0–1.5 kbar. Considering the large volume of the erupted tephra and textural evidence for rapid crystallisation of the evolved assemblage, 0.0–1.5 kbar is considered unlikely to represent a pressure of long-term magma accumulation and storage. Multiple thermometers indicate that the primitive assemblage crystallised at high temperatures of 1240–1300°C. Different barometers, however, return markedly different crystallisation depth estimates. Raw clinopyroxene-melt pressures of 5.5–7.5 kbar conflict with apparent melt inclusion entrapment pressures of 1.4 kbar. After applying a correction derived from published experimental data, clinopyroxene-melt equilibria return mid-crustal pressures of 4±1.5 kbar, which are consistent with pressures estimated from the major element content of primitive melt inclusions. Long-term storage of primitive magmas in the mid-crust implies that low CO_2 concentrations measured in primitive plagioclase-hosted inclusions (262–800 ppm) result from post-entrapment CO_2 loss during transport through the shallow crust. In order to reconstruct basaltic plumbing system geometries from petrological data with greater confidence, mineral-melt equilibrium models require refinement at pressures of magma storage in Iceland. Further basalt phase equilibria experiments are thus needed within the crucial 1–7 kbar range.D.A.N. was supported by a Natural Environment Research Council studentship (NE/1528277/1) at the start of this project. SIMS analyses were supported by Natural Environment Research Council Ion Microprobe Facility award (IMF508/1013).This is the final version of the article. It first appeared from Springer via http://dx.doi.org/10.1007/s00410-015-1170-

Mineralogical and geochemical analysis of Fe-phases in drill-cores from the Triassic Stuttgart Formation at Ketzin CO₂ storage site before CO₂ arrival

Reactive iron (Fe) oxides and sheet silicate-bound Fe in reservoir rocks may affect the subsurface storage of CO2 through several processes by changing the capacity to buffer the acidification by CO2 and the permeability of the reservoir rock: (1) the reduction of three-valent Fe in anoxic environments can lead to an increase in pH, (2) under sulphidic conditions, Fe may drive sulphur cycling and lead to the formation of pyrite, and (3) the leaching of Fe from sheet silicates may affect silicate diagenesis. In order to evaluate the importance of Fe-reduction on the CO2 reservoir, we analysed the Fe geochemistry in drill-cores from the Triassic Stuttgart Formation (Schilfsandstein) recovered from the monitoring well at the CO2 test injection site near Ketzin, Germany. The reservoir rock is a porous, poorly to moderately cohesive fluvial sandstone containing up to 2–4 wt% reactive Fe. Based on a sequential extraction, most Fe falls into the dithionite-extractable Fe-fraction and Fe bound to sheet silicates, whereby some Fe in the dithionite-extractable Fe-fraction may have been leached from illite and smectite. Illite and smectite were detected in core samples by X-ray diffraction and confirmed as the main Fe-containing mineral phases by X-ray absorption spectroscopy. Chlorite is also present, but likely does not contribute much to the high amount of Fe in the silicate-bound fraction. The organic carbon content of the reservoir rock is extremely low (<0.3 wt%), thus likely limiting microbial Fe-reduction or sulphate reduction despite relatively high concentrations of reactive Fe-mineral phases in the reservoir rock and sulphate in the reservoir fluid. Both processes could, however, be fuelled by organic matter that is mobilized by the flow of supercritical CO2 or introduced with the drilling fluid. Over long time periods, a potential way of liberating additional reactive Fe could occur through weathering of silicates due to acidification by CO2

Laser biospectroscopy and 5-ALA fluorescence navigation as a helpful tool in the meningioma resection

5-aminolevulinic acid (5-ALA) is a natural precursor of protoporphyrin IX (PP IX), which possesses fluorescent properties and is more intensively accumulated in tumor cells than in normal tissue. Therefore, the use of 5-ALA in the surgical treatment of intracranial tumors, particularly gliomas, has gained popularity in the last years, whereas its use in other intracranial pathological entities including meningiomas has been reported occasionally. This study describes a series of 28 patients with intracranial meningiomas, who were administered 5-ALA for a better visualization of tumor boundaries. Twelve patients underwent also laser spectroscopic analysis in order to confirm the visual impression of tumor tissue visualization. Bone infiltration was readily demonstrated. In one case, the tumor recurrence could have been prevented by removal of a tumor remnant, which would possibly have been better recognized if spectroscopic analysis had been used. Fluorescent navigation (FN) is a useful method for maximizing the radicality of meningioma surgery, particularly if the tumor infiltrates the bone, the skull base, and/or the surrounding structures

A case of brain abscess mimicking cystic brain tumor and showing intraoperative 5-aminolevulinic acid fluorescence: case report .

Intraoperative fluorescence diagnostics is proved highly sensitive and specific for surgery of highly malignant brain gliomas, meningiomas and metastases. The greatest capability of accumulating 5-ALA was found in oligodendrogliomas, piloid astrocytomas and gliomas with cystic components. In some cases, making the differential diagnosis between a cerebral cystic tumor and a brain abscess can be difficult due to the similarity of clinical and neuroimaging data. A 37 year old male was hospitalized in a local neurological hospital. On admission, he presented with headaches, nausea, episodic vomiting, and weakness in the left extremities. In the last few months the patient suffered from recurrent episods of sinusitis. Contrast-enhanced brain CT scans revealed a right parietal lobe lesion of irregular shape (70x35 mm) with perilesional contrast enhancement. Contrast-enhanced MRI showed a mass lesion, which was hypointense on T1 with a marked contrast accumulation at the periphery. To the differential diagnosis between the suspected abscess and malignant tumor, we used the method of intraoperative metabolic navigation with 5-ALA. To relive the severe tension of the brain tissue, a ultrasound-guided cyst puncture was carried out. As a result, a thick yellow purulent discharge (~30 mL) was drained. Microbiological analysis of cyst contents revealed the presence of the pathogenic Streptococcus alactolyticus in the abscess’s content. The 5-ALA-induced fluorescence can be successfully used in neurosurgery for the differential diagnosis between a intracerebral tumor cyst and an abscess in the brain

Deep roots for mid-ocean-ridge volcanoes revealed by plagioclase-hosted melt inclusions

The global mid-ocean ridge system is the most extensive magmatic system on our planet and is the site of 75 per cent of Earth’s volcanism. The vertical extent of mid-ocean-ridge magmatic systems has been considered to be restricted: even at the ultraslow- spreading Gakkel mid-ocean ridge under the Arctic Ocean, where the lithosphere is thickest, crystallization depths of magmas that feed eruptions are thought to be less than nine kilometres. These depths were determined using the volatile-element contents of melt inclusions, which are small volumes of magma that become trapped within crystallizing minerals. In studies of basaltic magmatic systems, olivine is the mineral of choice for this approach. However, pressures derived from olivine-hosted melt inclusions are at odds with pressures derived from basalt major-element barometers and geophysical measurements of lithospheric thickness. Here we present a comparative study of olivine- and plagioclase-hosted melt inclusions from the Gakkel mid-ocean ridge. We show that the volatile contents of plagioclase-hosted melt inclusions correspond to much higher crystallization pressures (with a mean value of 270 megapascals) than olivine-hosted melt inclusions (with a mean value of 145 megapascals). The highest recorded pressure that we find equates to a depth 16.4 kilometres below the seafloor. Such higher depths are consistent with both the thickness of the Gakkel mid-ocean ridge lithosphere and with pressures reconstructed from glass compositions. In contrast to previous studies using olivine-hosted melt inclusions, our results demonstrate that mid-ocean-ridge volcanoes may have magmatic roots deep in the lithospheric mantle, at least at ultraslow-spreading ridges