1,133 research outputs found
Relationship between resistivity and specific heat in a canonical non-magnetic heavy fermion alloy system: UPt_5-xAu_x
UPt_(5-x)Au_x alloys form in a single crystal structure, cubic AuBe_5-type,
over a wide range of concentrations from x = 0 to at least x = 2.5. All
investigated alloys, with an exception for x = 2.5, were non-magnetic. Their
electronic specific heat coefficient varies from about 60 (x = 2) to
about 700 mJ/mol K^2 (x = 1). The electrical resistivity for all alloys has a
Fermi-liquid-like temperature variation, \rho = \rho_o + AT^2, in the limit of
T -> 0 K. The coefficient A is strongly enhanced in the heavy-fermion regime in
comparison with normal and transition metals. It changes from about 0.01 (x =
0) to over 2 micro-ohm cm/K^2 (x = 1). A/\gamma^2, which has been postulated to
have a universal value for heavy-fermions, varies from about 10^-6 (x = 0, 0.5)
to 10^-5 micro-ohm cm (mol K/mJ)^2 (x > 1.1), thus from a value typical of
transition metals to that found for some other heavy-fermion metals. This ratio
is unaffected, or only weakly affected, by chemical or crystallographic
disorder. It correlates with the paramagnetic Curie-Weiss temperature of the
high temperature magnetic susceptibility.Comment: 5 pages, 5 eps figures, RevTe
Role of Solvent Compatibility in the Phase Behavior of Binary Solutions of Weakly Associating Multivalent Polymers
[Image: see text] Condensate formation of biopolymer solutions, prominently those of various intrinsically disordered proteins (IDPs), is often driven by “sticky” interactions between associating residues, multivalently present along the polymer backbone. Using a ternary mean-field “stickers-and-spacers” model, we demonstrate that if sticker association is of the order of a few times the thermal energy, a delicate balance between specific binding and nonspecific polymer–solvent interactions gives rise to a particularly rich ternary phase behavior under physiological circumstances. For a generic system represented by a solution comprising multiassociative scaffold and client polymers, the difference in solvent compatibility between the polymers modulates the nature of isothermal liquid–liquid phase separation (LLPS) between associative and segregative. The calculations reveal regimes of dualistic phase behavior, where both types of LLPS occur within the same phase diagram, either associated with the presence of multiple miscibility gaps or a flip in the slope of the tie-lines belonging to a single coexistence region
Unusual behaviours and Impurity Effects in the Noncentrosymmetric Superconductor CePt3Si
We report a study in which the effect of defects/impurities, growth process,
off-stoichiometry, and presence of impurity phases on the superconducting
properties of noncentrosymmetric CePt3Si is analysed by means of the
temperature dependence of the magnetic penetration depth. We found that the
linear low-temperature response of the penetration depth -indicative of line
nodes in this material- is robust regarding sample quality, in contrast to what
is observed in unconventional centrosymmetric superconductors with line nodes.
We discuss evidence that the broadness of the superconducting transition may be
intrinsic, though not implying the existence of a second superconducting
transition. The superconducting transition temperature systematically occurs
around 0.75 K in our measurements, in agreement with resistivity and ac
magnetic susceptibility data but in conflict with specific heat, thermal
conductivity and NMR data in which Tc is about 0.5 K. Random defects do not
change the linear low-temperature dependence of the penetration depth in the
heavy-fermion CePt3Si with line nodes, as they do in unconventional
centrosymmetric superconductors with line nodes.Comment: To appear in New Journal of Physic
SARS-CoV-2 vaccination in cardiothoracic organ transplant recipients: effective strategies wanted
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SARS-CoV-2 vaccination in cardiothoracic organ transplant recipients: effective strategies wanted
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Evolution of Quantum Criticality in CeNi_{9-x}Cu_xGe_4
Crystal structure, specific heat, thermal expansion, magnetic susceptibility
and electrical resistivity studies of the heavy fermion system
CeNi_{9-x}Cu_xGe_4 (0 <= x <= 1) reveal a continuous tuning of the ground state
by Ni/Cu substitution from an effectively fourfold degenerate non-magnetic
Kondo ground state of CeNi_9Ge_4 (with pronounced non-Fermi-liquid features)
towards a magnetically ordered, effectively twofold degenerate ground state in
CeNi_8CuGe_4 with T_N = 175 +- 5 mK. Quantum critical behavior, C/T ~ \chi ~
-ln(T), is observed for x about 0.4. Hitherto, CeNi_{9-x}Cu_xGe_4 represents
the first system where a substitution-driven quantum phase transition is
connected not only with changes of the relative strength of Kondo effect and
RKKY interaction, but also with a reduction of the effective crystal field
ground state degeneracy.Comment: 15 pages, 9 figure
AC/DC Susceptibility of the Heavy-Fermion Superconductor CePt3Si under Pressure
We have investigated the pressure dependence of ac and dc susceptibilities of
the heavy-fermion superconductor CePt3Si (Tc= 0.75 K) that coexists with
antiferromagnetism (TN = 2.2 K). As hydrostatic pressure is increased, Tc first
decreases rapidly, then rather slowly near the critical pressure Pc = 0.6 GPa
and shows a stronger decrease again at higher pressures, where Pc is the
pressure at which TN becomes zero. A transition width and a difference in the
two transition temperatures defined in the form of structures in the
out-of-phase component of ac susceptibilities also become small near Pc,
indicating that a double transition observed in CePt3Si is caused by some
inhomogeneous property in the sample that leads to a spatial variation of local
pressure. A sudden increase in the Meissner fraction above Pc suggests the
influence of antiferromagnetism on superconductivity.Comment: 4 pages with 5 figures. This paper will be published in J. Phys. Soc.
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Visual, Motor and Attentional Influences on Proprioceptive Contributions to Perception of Hand Path Rectilinearity during Reaching
We examined how proprioceptive contributions to perception of hand path straightness are influenced by visual, motor and attentional sources of performance variability during horizontal planar reaching. Subjects held the handle of a robot that constrained goal-directed movements of the hand to the paths of controlled curvature. Subjects attempted to detect the presence of hand path curvature during both active (subject driven) and passive (robot driven) movements that either required active muscle force production or not. Subjects were less able to discriminate curved from straight paths when actively reaching for a target versus when the robot moved their hand through the same curved paths. This effect was especially evident during robot-driven movements requiring concurrent activation of lengthening but not shortening muscles. Subjects were less likely to report curvature and were more variable in reporting when movements appeared straight in a novel “visual channel” condition previously shown to block adaptive updating of motor commands in response to deviations from a straight-line hand path. Similarly, compromised performance was obtained when subjects simultaneously performed a distracting secondary task (key pressing with the contralateral hand). The effects compounded when these last two treatments were combined. It is concluded that environmental, intrinsic and attentional factors all impact the ability to detect deviations from a rectilinear hand path during goal-directed movement by decreasing proprioceptive contributions to limb state estimation. In contrast, response variability increased only in experimental conditions thought to impose additional attentional demands on the observer. Implications of these results for perception and other sensorimotor behaviors are discussed
A Physiologically Based Clinical Measure for Spastic Reflexes in Spinal Cord Injury
Objective: To test the validity of the Spinal Cord Assessment Tool for Spastic reflexes (SCATS), a clinical tool intended to rate spastic motor behavior after spinal cord injury (SCI).
Design: By using correlational analyses, the SCATS was validated using concurrent measurements of kinematics and electromyograms and traditional assessments of spasms and spastic hypertonia.
Setting: Research laboratory (kinematics and electromyography) and outpatient medical clinic (traditional measures of spastic hypertonia).
Participants: Eleven people with SCI were used for kinematic and electromyographic measurements. Seventeen people with SCI were used for comparison with other clinical scales.
Interventions: Not applicable.
Main outcome measures: Kinematic and surface electromyographic measurements of the tested lower extremity were used to quantify magnitude and/or duration of motor behaviors, and the Penn Spasm Frequency Scale (PSFS) and the Ashworth Scale were used to measure spasm frequency and resistance to joint movement for the hip flexors, knee flexors, and ankle plantarflexors, respectively. Concurrently, the SCATS was used to assess the clonus response to an imposed ankle dorsiflexion, the flexion response to a stimulus to the foot, and the knee extensor activity in response to an imposed leg extension. Each component of the SCATS was compared with the Ashworth Scale, the PSFS, and kinematic and electromyographic measurements by using the Spearman rank correlation test.
Results:Clonus, flexor spasm, and extensor spasm responses measured by using the SCATS correlated significantly with kinematic and electromyographic recordings (PP\u3c.05).
Conclusions: The SCATS produced a valid measure of 3 distinct types of spastic motor behaviors in SCI and may provide a complementary tool for measuring spastic hypertonia. Such a measure is valuable because current assessment tools do not differentiate between the different types of spastic motor behaviors that manifest after SCI. Distinguishing the 3 spastic reactions using an efficient and valid clinical tool may help guide management of spastic hypertonia in SCI
Catalytic Kinetic Resolution of a Dynamic Racemate: Highly Stereoselective β-Lactone Formation by N-Heterocyclic Carbene Catalysis
This study describes the combined experimental and computational elucidation of the mechanism and origins of stereoselectivities in the NHC-catalyzed dynamic kinetic resolution (DKR) of α-substituted-β-ketoesters. Density functional theory computations reveal that the NHC-catalyzed DKR proceeds by two mechanisms, depending on the stereochemistry around the forming bond: 1) a concerted, asynchronous formal (2+2) aldol-lactonization process, or 2) a stepwise spiro-lactonization mechanism where the alkoxide is trapped by the NHC-catalyst. These mechanisms contrast significantly from mechanisms found and postulated in other related transformations. Conjugative stabilization of the electrophile and non-classical hydrogen bonds are key in controlling the stereoselectivity. This reaction constitutes an interesting class of DKRs in which the catalyst is responsible for the kinetic resolution to selectively and irreversibly capture an enantiomer of a substrate undergoing rapid racemization with the help of an exogenous base
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