68 research outputs found
Electroless deposition and Electroplating of Metals
The present paper summarizes the main results of the research on the electroless and electrochemical metal deposition from aqueous solutions, which has been carried out in the Research Institute of Physical-Chemical problems of the Belarussian State University and at the Department of Inorganic Chemistry of the BSU for the last three decades. The paper covers the following problems: the main peculiarities of electroless and electrochemical deposition of copper, nickel, Ni-B,Ni-P, gold films 0.1-30 mkm and more in thickness, their phase composition, morphology and properties; the characteristic features of of hydrometallurgic allowing
(e.g. electroless and electrochemical deposition of a number of binary alloy coatings such as Cu-Ni, Cu-Cd, Cu-Sn, Cu-Zn, Ni-Sn, Ni-W, Ni-Mo), methods of their chemical and phase composition and microstructure regulation, together with correlation between these parameters and alloy properties; the methods for composite metal and alloy film plating from solutions with production of materials including metal oxides and thus possessing unusual and useful properties; the peculiarities of metal film plating onto dielectrics with production of continuous films and metal conductive patterns without the use of photoresists
Some ways of filling of the vascular bed of domestic animals
In this work the assessment of some methods of filling of the mammals blood channels is presented. As injection masses there were used the gelatine solution of 5%, painted with the ink by Borisevich V.B. technique and the solution consisting of Bustilat-M glue and the water in a proportion of 2:1. The conducted researches showed that the most successful, in terms of simplicity of execution, is filling of vessels with the solution consisting of Bustilat-M glue and water, as it allows with the little effort and with the smallest expenses to fill in both large and average vessel
Biological resources of natural forage grassland of the cretaceous south of the European Russia
The main objective of the made researches was assessment of territorial confinedness of economic and valuable plant species and also a status and productivity of a natural forage grassland within agrolandscapes of the cretaceous South of the European Russia (the territory of the Belgorod region). Biological and vegetable resources of the natural forage grasslands of the East part of the Belgorod region in a subband of the southern forest-steppe were studie
ΠΠ»Π΅ΠΊΡΡΠΎΡ ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΎΠ΅ ΠΎΡΠ°ΠΆΠ΄Π΅Π½ΠΈΠ΅ ΡΠΏΠ»Π°Π²Π° Au-Sn ΠΈΠ· ΡΡΠΈΠ»Π΅Π½Π³Π»ΠΈΠΊΠΎΠ»Π΅Π²ΡΡ ΡΠ»Π΅ΠΊΡΡΠΎΠ»ΠΈΡΠΎΠ²
Stable ethylene glycol and aqua-ethylene glycol electrolytes on the base of K[Au(CN)2] and SnCl4 for the electrochemical deposition of Au-Sn alloy with metals ratio and phase composition appropriated to the low-melt eutectic (Au - 70 at.%, Sn -30 at.%, Au5Sn, AuSn) have been elaborated. The role of electrolytes components in the redox processes proceeding on the cathode and anode and their on the rate of deposition and Au : Sn ratio in the alloy have been developed. Composition and structure of Au-Sn alloy coatings have been investigated.Π Π°Π·ΡΠ°Π±ΠΎΡΠ°Π½Ρ ΡΡΠ°Π±ΠΈΠ»ΡΠ½ΡΠ΅ ΡΡΠΈΠ»Π΅Π½Π³Π»ΠΈΠΊΠΎΠ»Π΅Π²ΡΠΉ ΠΈ Π²ΠΎΠ΄Π½ΠΎ-ΡΡΠΈΠ»Π΅Π½Π³Π»ΠΈΠΊΠΎΠ»Π΅Π²ΡΠΉ ΡΠ»Π΅ΠΊΡΡΠΎΠ»ΠΈΡΡ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ K[Au(CN)4] ΠΈ SnCl4 β’ 5H2O, ΠΎΠ±Π΅ΡΠΏΠ΅ΡΠΈΠ²Π°ΡΡΠΈΠ΅ ΡΠ»Π΅ΠΊΡΡΠΎΡ
ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΎΠ΅ ΠΎΡΠ°ΠΆΠ΄Π΅Π½ΠΈΠ΅ ΡΠΏΠ»Π°Π²Π° Au-Sn Ρ ΡΠΎΠΎΡΠ½ΠΎΡΠ΅Π½ΠΈΠ΅ΠΌ ΠΌΠ΅ΡΠ°Π»Π»ΠΎΠ² ΠΈ ΡΠ°Π·ΠΎΠ²ΡΠΌ ΡΠΎΡΡΠ°Π²ΠΎΠΌ, ΡΠΎΠΎΡΠ²Π΅ΡΡΡΠ²ΡΡΡΠΈΠΌΠΈ Π»Π΅Π³ΠΊΠΎΠΏΠ»Π°Π²ΠΊΠΎΠΉ ΡΠ²ΡΠ΅ΠΊΡΠΈΠΊΠ΅ Π² ΡΠΈΡΡΠ΅ΠΌΠ΅ Π·ΠΎΠ»ΠΎΡΠΎ - ΠΎΠ»ΠΎΠ²ΠΎ (Au 70%; Sn 30%, Au5Sn, AuSn). ΠΡΡΡΠ½Π΅Π½ΠΎ Π²Π»ΠΈΡΠ½ΠΈΠ΅ ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠΎΠ² ΡΠ»Π΅ΠΊΡΡΠΎΠ»ΠΈΡΠ° Π½Π° Π·Π°ΠΊΠΎΠ½ΠΎΠΌΠ΅ΡΠ½ΠΎΡΡΠΈ ΠΏΡΠΎΡΠ΅ΠΊΠ°Π½ΠΈΡ ΠΎΠΊΠΈΡΠ»ΠΈΡΠ΅Π»ΡΠ½ΠΎ-Π²ΠΎΡΡΡΠ°Π½ΠΎΠ²ΠΈΡΠ΅Π»ΡΠ½ΡΡ
ΠΏΡΠΎΡΠ΅ΡΡΠΎΠ² Π½Π° ΡΠ»Π΅ΠΊΡΡΠΎΠ΄Π°Ρ
, ΡΠΊΠΎΡΠΎΡΡΡ ΡΠΎΡΡΠ° ΠΏΠΎΠΊΡΡΡΠΈΠΉ, ΠΈΡ
ΡΠΎΡΡΠ°Π² ΠΈ ΠΌΠΈΠΊΡΠΎΡΡΡΡΠΊΡΡΡΡ
ΠΠ»Π΅ΠΊΡΡΠΎΡ ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΎΠ΅ ΠΎΡΠ°ΠΆΠ΄Π΅Π½ΠΈΠ΅ ΡΠΏΠ»Π°Π²Π° Au-Sn ΠΈΠ· ΡΡΠΈΠ»Π΅Π½Π³Π»ΠΈΠΊΠΎΠ»Π΅Π²ΡΡ ΡΠ»Π΅ΠΊΡΡΠΎΠ»ΠΈΡΠΎΠ²
Stable ethylene glycol and aqua-ethylene glycol electrolytes on the base of K[Au(CN)2] and SnCl4 for the electrochemical deposition of Au-Sn alloy with metals ratio and phase composition appropriated to the low-melt eutectic (Au - 70 at.%, Sn -30 at.%, Au5Sn, AuSn) have been elaborated. The role of electrolytes components in the redox processes proceeding on the cathode and anode and their on the rate of deposition and Au : Sn ratio in the alloy have been developed. Composition and structure of Au-Sn alloy coatings have been investigated.Π Π°Π·ΡΠ°Π±ΠΎΡΠ°Π½Ρ ΡΡΠ°Π±ΠΈΠ»ΡΠ½ΡΠ΅ ΡΡΠΈΠ»Π΅Π½Π³Π»ΠΈΠΊΠΎΠ»Π΅Π²ΡΠΉ ΠΈ Π²ΠΎΠ΄Π½ΠΎ-ΡΡΠΈΠ»Π΅Π½Π³Π»ΠΈΠΊΠΎΠ»Π΅Π²ΡΠΉ ΡΠ»Π΅ΠΊΡΡΠΎΠ»ΠΈΡΡ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ K[Au(CN)4] ΠΈ SnCl4 β’ 5H2O, ΠΎΠ±Π΅ΡΠΏΠ΅ΡΠΈΠ²Π°ΡΡΠΈΠ΅ ΡΠ»Π΅ΠΊΡΡΠΎΡ
ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΎΠ΅ ΠΎΡΠ°ΠΆΠ΄Π΅Π½ΠΈΠ΅ ΡΠΏΠ»Π°Π²Π° Au-Sn Ρ ΡΠΎΠΎΡΠ½ΠΎΡΠ΅Π½ΠΈΠ΅ΠΌ ΠΌΠ΅ΡΠ°Π»Π»ΠΎΠ² ΠΈ ΡΠ°Π·ΠΎΠ²ΡΠΌ ΡΠΎΡΡΠ°Π²ΠΎΠΌ, ΡΠΎΠΎΡΠ²Π΅ΡΡΡΠ²ΡΡΡΠΈΠΌΠΈ Π»Π΅Π³ΠΊΠΎΠΏΠ»Π°Π²ΠΊΠΎΠΉ ΡΠ²ΡΠ΅ΠΊΡΠΈΠΊΠ΅ Π² ΡΠΈΡΡΠ΅ΠΌΠ΅ Π·ΠΎΠ»ΠΎΡΠΎ - ΠΎΠ»ΠΎΠ²ΠΎ (Au 70%; Sn 30%, Au5Sn, AuSn). ΠΡΡΡΠ½Π΅Π½ΠΎ Π²Π»ΠΈΡΠ½ΠΈΠ΅ ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠΎΠ² ΡΠ»Π΅ΠΊΡΡΠΎΠ»ΠΈΡΠ° Π½Π° Π·Π°ΠΊΠΎΠ½ΠΎΠΌΠ΅ΡΠ½ΠΎΡΡΠΈ ΠΏΡΠΎΡΠ΅ΠΊΠ°Π½ΠΈΡ ΠΎΠΊΠΈΡΠ»ΠΈΡΠ΅Π»ΡΠ½ΠΎ-Π²ΠΎΡΡΡΠ°Π½ΠΎΠ²ΠΈΡΠ΅Π»ΡΠ½ΡΡ
ΠΏΡΠΎΡΠ΅ΡΡΠΎΠ² Π½Π° ΡΠ»Π΅ΠΊΡΡΠΎΠ΄Π°Ρ
, ΡΠΊΠΎΡΠΎΡΡΡ ΡΠΎΡΡΠ° ΠΏΠΎΠΊΡΡΡΠΈΠΉ, ΠΈΡ
ΡΠΎΡΡΠ°Π² ΠΈ ΠΌΠΈΠΊΡΠΎΡΡΡΡΠΊΡΡΡΡ
Robust Phase Behavior of Model Transient networks
In order to study the viscoelastic properties of certain complex fluids which
are described in terms of a multiconnected transient network we have developed
a convenient model system composed of microemulsion droplets linked by
telechelic polymers. The phase behavior of such systems has two characteristic
features: a large monophasic region which consists of two sub-regions (a fluid
sol phase and a viscoelastic gel phase) separated by a percolation line and a
two phase region at low volume fraction with separation into a dilute sol phase
and a concentrated gel phase. From the plausible origin of these features we
expect them to be very similar in different systems. We describe here the phase
behavior of four different systems we prepared in order to vary the time scale
of the dynamical response of the transient network; they consist of the
combination of two oil(decane) in water microemulsions differing by the
stabilizing surfactant monolayer (Cetyl pyridinium chloride/octanol or
TX100/TX35) and of two telechelic polymers which are end-grafted poly (ethylene
oxide) chains, differing by the end-grafted hydrophobic aliphatic chains
(C12H25 or C18H37).Comment: April 9 200
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