12,859 research outputs found
Hydrogen absorption properties of amorphous (Ni0.6Nb0.4−yTay)100−xZrx membranes
Ni based amorphous materials have great potential as hydrogen purification membranes. In the present work
the melt spun (Ni0.6Nb0.4−yTay)100−xZrx with y=0, 0.1 and x=20, 30 was studied. The result of X-ray diffraction
spectra of the ribbons showed an amorphous nature of the alloys. Heating these ribbons below T < 400 °C, even
in a hydrogen atmosphere (1−10 bar), the amorphous structure was retained. The crystallization process was
characterized by differential thermal analysis and the activation energy of such process was obtained. The
hydrogen absorption properties of the samples in their amorphous state were studied by the volumetric method,
and the results showed that the addition of Ta did not significantly influence the absorption properties, a clear
change of the hydrogen solubility was observed with the variation of the Zr content. The values of the
hydrogenation enthalpy changed from ~37 kJ/mol for x=30 to ~9 kJ/mol for x=20. The analysis of the
volumetric data provides the indications about the hydrogen occupation sites during hydrogenation, suggesting
that at the beginning of the absorption process the deepest energy levels are occupied, while only shallower
energy levels are available at higher hydrogen content, with the available interstitial sites forming a continuum
of energy levels
Flux jumps, Second Magnetization Peak anomaly and the Peak Effect phenomenon in single crystals of and
We present magnetization measurements in single crystals of the tetragonal
compound, which exhibit the phenomenon of peak effect as well as
the second magnetization peak anomaly for H 0.5T (H c). At the lower
field (50mT H 200mT), we have observed the presence of flux jumps,
which seem to relate to a structural change in the local symmetry of the flux
line lattice (a first order re-orientation transition across a local field in
some parts of the sample, in the range of 100mT to 150mT). These flux jumps are
also observed in a single crystal of for H c in the field
region from 2 mT to 25 mT, which are compatible with the occurrence of a
re-orientation transition at a lower field in a cleaner crystal of this
compound, as compared to those of . Vortex phase diagrams drawn for
H c in and show that the ordered elastic glass
phase spans a larger part of (H, T) space in the former as compared to latter,
thereby, reaffirming the difference in the relative purity of the two samples.Comment: 11 pages, 14 figure
Patient reactions to a web-based cardiovascular risk calculator in type 2 diabetes: a qualitative study in primary care.
Use of risk calculators for specific diseases is increasing, with an underlying assumption that they promote risk reduction as users become better informed and motivated to take preventive action. Empirical data to support this are, however, sparse and contradictory
Fission widths of hot nuclei from Langevin dynamics
Fission dynamics of excited nuclei is studied in the framework of Langevin
equation. The one body wall-and-window friction is used as the dissipative
force in the Langevin equation. In addition to the usual wall formula friction,
the chaos weighted wall formula developed earlier to account for
nonintegrability of single-particle motion within the nuclear volume is also
considered here. The fission rate calculated with the chaos weighted wall
formula is found to be faster by about a factor of two than that obtained with
the usual wall friction. The systematic dependence of fission width on
temperature and spin of the fissioning nucleus is investigated and a simple
parametric form of fission width is obtained.Comment: RevTex, 12 pages including 9 Postscript figure
Physical Properties of OSIRIS-REx Target Asteroid (101955) 1999 RQ36 derived from Herschel, ESO-VISIR and Spitzer observations
In September 2011, the Herschel Space Observatory performed an observation
campaign with the PACS photometer observing the asteroid (101955) 1999 RQ36 in
the far infrared. The Herschel observations were analysed, together with ESO
VLT-VISIR and Spitzer-IRS data, by means of a thermophysical model in order to
derive the physical properties of 1999 RQ36. We find the asteroid has an
effective diameter in the range 480 to 511 m, a slightly elongated shape with a
semi-major axis ratio of a/b=1.04, a geometric albedo of 0.045 +0.015/-0.012,
and a retrograde rotation with a spin vector between -70 and -90 deg ecliptic
latitude. The thermal emission at wavelengths below 12 micron -originating in
the hot sub-solar region- shows that there may be large variations in roughness
on the surface along the equatorial zone of 1999 RQ36, but further measurements
are required for final proof. We determine that the asteroid has a
disk-averaged thermal inertia of Gamma = 650 Jm-2s-0.5K-1 with a 3-sigma
confidence range of 350 to 950 Jm-2s-0.5K-1, equivalent to what is observed for
25143 Itokawa and suggestive that 1999 RQ36 has a similar surface texture and
may also be a rubble-pile in nature. The low albedo indicates that 1999 RQ36
very likely contains primitive volatile-rich material, consistent with its
spectral type, and that it is an ideal target for the OSIRIS-REx sample return
mission.Comment: Accepted for publication in Astronomy & Astrophysics, 9 pages, 7
figure
A momentum-conserving, consistent, Volume-of-Fluid method for incompressible flow on staggered grids
The computation of flows with large density contrasts is notoriously
difficult. To alleviate the difficulty we consider a consistent mass and
momentum-conserving discretization of the Navier-Stokes equation.
Incompressible flow with capillary forces is modelled and the discretization is
performed on a staggered grid of Marker and Cell type. The Volume-of-Fluid
method is used to track the interface and a Height-Function method is used to
compute surface tension. The advection of the volume fraction is performed
using either the Lagrangian-Explicit / CIAM (Calcul d'Interface Affine par
Morceaux) method or the Weymouth and Yue (WY) Eulerian-Implicit method. The WY
method conserves fluid mass to machine accuracy provided incompressiblity is
satisfied which leads to a method that is both momentum and mass-conserving. To
improve the stability of these methods momentum fluxes are advected in a manner
"consistent" with the volume-fraction fluxes, that is a discontinuity of the
momentum is advected at the same speed as a discontinuity of the density. To
find the density on the staggered cells on which the velocity is centered, an
auxiliary reconstruction of the density is performed. The method is tested for
a droplet without surface tension in uniform flow, for a droplet suddenly
accelerated in a carrying gas at rest at very large density ratio without
viscosity or surface tension, for the Kelvin-Helmholtz instability, for a
falling raindrop and for an atomizing flow in air-water conditions
Physical Properties of Asteroid (308635) 2005 YU55 derived from multi-instrument infrared observations during a very close Earth-Approach
The near-Earth asteroid (308635) 2005 YU55 is a potentially hazardous
asteroid which was discovered in 2005 and passed Earth on November 8th 2011 at
0.85 lunar distances. This was the closest known approach by an asteroid of
several hundred metre diameter since 1976 when a similar size object passed at
0.5 lunar distances. We observed 2005 YU55 from ground with a recently
developed mid-IR camera (miniTAO/MAX38) in N- and Q-band and with the
Submillimeter Array (SMA) at 1.3 mm. In addition, we obtained space
observations with Herschel/PACS at 70, 100, and 160 micron. Our thermal
measurements cover a wide range of wavelengths from 8.9 micron to 1.3 mm and
were taken after opposition at phase angles between -97 deg and -18 deg. We
performed a radiometric analysis via a thermophysical model and combined our
derived properties with results from radar, adaptive optics, lightcurve
observations, speckle and auxiliary thermal data. We find that (308635) 2005
YU55 has an almost spherical shape with an effective diameter of 300 to 312 m
and a geometric albedo pV of 0.055 to 0.075. Its spin-axis is oriented towards
celestial directions (lam_ecl, beta_ecl) = (60 deg +/- 30deg, -60 deg +/- 15
deg), which means it has a retrograde sense of rotation. The analysis of all
available data combined revealed a discrepancy with the radar-derived size. Our
radiometric analysis of the thermal data together with the problem to find a
unique rotation period might be connected to a non-principal axis rotation. A
low to intermediate level of surface roughness (r.m.s. of surface slopes in the
range 0.1 - 0.3) is required to explain the available thermal measurements. We
found a thermal inertia in the range 350-800 Jm^-2s^-0.5K^-1, very similar to
the rubble-pile asteroid (25143) Itokawa and indicating a mixture of low
conductivity fine regolith with larger rocks and boulders of high thermal
inertia on the surface.Comment: Accepted for publication in Astronomy & Astrophysics, 12 pages, 10
figure
Keypad mobile phones are associated with a significant increased risk of microbial contamination compared to touch screen phones
The use of mobile phones in the clinical environment by healthcare workers has become widespread. Despite evidence that these devices can harbour pathogenic micro-organisms there is little guidance on how to reduce contamination. Recently touchscreen phones with a single flat surface have been introduced. We hypothesise that bacterial contamination of phones used in hospitals will be lower on touchscreen devices compared to keypad devices. Sixty seven mobile phones belonging to health care workers were sampled. The median colony count for touchscreen phones and keypad devices was 0·09 colony forming units (cfu)/cm2 (interquartile range (IQR) 0.05–0·14) and 0·77 cfu/cm2 (IQR range 0·45–3.52) respectively. Colony counts were significantly higher on the keypad phones (Fisher’s exact test p<0.001). Multivariate analysis showed the type of phone (keypad vs. touch screen) was associated with increased colony counts (F-statistic 14.13: p<0.001). Overall, nine (13%) phones grew either meticillin resistant Staphylococcus aureus or vancomycin resistant enterococci. Eight (24%) keypad phones were contaminated with these organisms compared with one touch screen phone (3%). Our data indicate that touchscreen mobile phones are less contaminated than their keypad counterparts, and they are less likely to harbour pathogenic bacteria in the clinical setting
Hydrogen Bond Dynamics Near A Micellar Surface: Origin of the Universal Slow Relaxation at Complex Aqueous Interfaces
The dynamics of hydrogen bonds among water molecules themselves and with the
polar head groups (PHG) at a micellar surface have been investigated by long
molecular dynamics simulations. The lifetime of the hydrogen bond between a PHG
and a water molecule is found to be much longer than that between any two water
molecules, and is likely to be a general feature of hydrophilic surfaces of
organized assemblies. Analyses of individual water trajectories suggest that
water molecules can remain bound to the micellar surface for more than a
hundred picosecond. The activation energy for such a transition from the bound
to a free state for the water molecules is estimated to be about 3.5kcal/mole.Comment: 12 pages. Phys. Rev. Lett. (Accepted) (2002
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