30 research outputs found
Andreev Bound States in High Temperature Superconductors
Andreev bound states (ABS) at the surface of superconductors are expected for
any pair potential showing a sign change in different k-directions with their
spectral weight depending on the relative orientation of the surface and the
pair potential. We report on the observation of ABS in HTS employing tunneling
spectroscopy on bicrystal grain boundary Josephson junctions (GBJs). The
tunneling spectra were studied as a function of temperature and applied
magnetic field. The tunneling spectra of GBJ formed by YBCO, BSCCO, and LSCO
show a pronounced zero bias conductance peak that can be interpreted in terms
of Andreev bound states at zero energy that are expected at the surface of HTS
having a d-wave symmetry of the order parameter. In contrast, for the most
likely s-wave HTS NCCO no zero bias conductance peak was observed. Applying a
magnetic field results in a shift of spectral weight from zero to finite
energy. This shift is found to depend nonlinearly on the applied magnetic
field. Further consequences of the Andreev bound states are discussed and
experimental evidence for anomalous Meissner currents is presented.Comment: 17 pages, 10 figures, to appear in Eur. Phys. J.
Anomalous Low Temperature Behavior of Superconducting Nd(1.85)Ce(0.15)CuO(4-y)
We have measured the temperature dependence of the in-plane London
penetration depth lambda(T) and the maximum Josephson current Ic(T) using
bicrystal grain boundary Josephson junctions of the electron-doped cuprate
superconductor Nd(1.85)Ce(0.15)CuO(4-y). Both quantities reveal an anomalous
temperature dependence below about 4 K. In contrast to the usual monotonous
decrease (increase) of lambda(T) (Ic(T)) with decreasing temperature, lambda(T)
and Ic(T) are found to increase and decrease, respectively, with decreasing
temperature below 4 K resulting in a non-monotonous overall temperature
dependence. This anomalous behavior was found to be absent in analogous
measurements performed on Pr(1.85)Ce(0.15)CuO(4-y). From this we conclude that
the anomalous behavior of Nd(1.85)Ce(0.15)CuO(4-y) is caused by the presence of
the Nd3+ paramagnetic moments. Correcting the measured lambda(T) dependence of
Nd(1.85)Ce(0.15)CuO(4-y) for the temperature dependent susceptibility due to
the Nd moments, an exponential dependence is obtained indicating isotropic
s-wave pairing. This result is fully consistent with the lambda(T) dependence
measured for Pr(1.85)Ce(0.15)CuO(4-y).Comment: 4 pages including 4 figures, to appear in Phys. Rev. Let
Possible pseudogap behavior of electron doped high-temperature superconductors
We have measured the low-energy quasiparticle excitation spectrum of the
electron doped high-temperature superconductors (HTS) Nd(1.85)Ce(0.15)CuO(4-y)
and Pr(1.85)Ce(0.15)CuO(4-y) as a function of temperature and applied magnetic
field using tunneling spectroscopy. At zero magnetic field, for these optimum
doped samples no excitation gap is observed in the tunneling spectra above the
transition temperature Tc. In contrast, below Tc for applied magnetic fields
well above the resistively determined upper critical field, a clear excitation
gap at the Fermi level is found which is comparable to the superconducting
energy gap below Tc. Possible interpretations of this observation are the
existence of a normal state pseudogap in the electron doped HTS or the
existence of a spatially non-uniform superconducting state.Comment: 4 pages, 4 ps-figures included, to be published in Phys. Rev. B,
Rapid Com
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Oxygen transport by oxygen potential gradient in dense ceramic oxide membranes
Numerous studies have been conducted in recent years on the partial oxidation of methane to synthesis gas (syngas: CO + H{sub 2}) with air as the oxidant. In partial oxidation, a mixed-oxide ceramic membrane selectively transports oxygen from the air; this transport is driven by the oxygen potential gradient. Of the several ceramic materials the authors have tested, a mixed oxide based on the Sr-Fe-Co-O system has been found to be very attractive. Extensive oxygen permeability data have been obtained for this material in methane conversion experiments carried out in a reactor. The data have been analyzed by a transport equation based on the phenomenological theory of diffusion under oxygen potential gradients. Thermodynamic calculations were used to estimate the driving force for the transport of oxygen ions. The results show that the transport equation deduced from the literature describes the permeability data reasonably well and can be used to determine the diffusion coefficients and the associated activation energy of oxygen ions in the ceramic membrane material
Possible Z2 phase and spin-charge separation in electron doped cuprate superconductors
The SU(2) slave-boson mean-field theory for the tt'J model is analyzed. The
role of next-nearest-neighbor hopping t' on the phase-diagram is studied. We
find a pseudogap phase in hole-doped materials (where t'<0). The pseudo-gap
phase is a U(1) spin liquid (the staggered-flux phase) with a U(1) gauge
interaction and no fractionalization. This agrees with experiments on hole
doped samples. The same calculation also indicates that a positive t' favors a
Z2 state with true spin-charge separation. The Z2 state that exists when t' >
0.5J can be a candidate for the pseudo-gap phase of electron-doped cuprates (if
such a phase exists). The experimental situation in electron-doped materials is
also addressed.Comment: 6 pages, 2 figures, RevTeX4. Homepage http://dao.mit.edu/~wen
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Separation of gases with solid electrolyte ionic conductors
The authors have developed a novel method of gas separation based on electrolyte ionic membrane technology. Separation of one gas from another occurs through an ion-conducting membrane by the passage of selected ions. Most systems studied have focused on oxygen ion conduction for the separation of oxygen from air, although protonic and halide-conducting solid materials also exist. As an example of this system, this paper concentrates on a study of a membrane reactor used in the production of syngas (CO + H{sub 2}) from methane. The membrane material is a modified perovskite-type oxide exhibiting mixed (electronic/ionic) conductivity. Mixed-conductivity oxides are promising materials for oxygen-permeating membranes that can operate without electrodes or external electrical circuitry. Extruded tubes of this material have been evaluated in a reactor operating at {approx} 850 C for partial oxidation of methane into syngas in the presence of a reforming catalyst. Separated oxygen on one side of the reactor wall was obtained from air on the other side. Methane conversion efficiencies of > 99% were observed, and some of the reactor tubes have been operated for > 1,000 h. Membrane tubes were fabricated from calcined powders by a plastic extrusion technique. Characterization of the mechanical, physical, and chemical properties of this material confirmed the stability exhibited in the reactor
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Development of dense ceramic membranes for methane conversion
The most significant cost associated with partial oxidation of methane to syngas is that of the oxygen plant. In this paper, the authors offer a technology, based on dense ceramic membranes, that uses air as the oxidant for methane conversion reactions, thus eliminating the need for the oxygen plant. Certain ceramic materials exhibit both electronic and ionic conductivities (of particular interest is oxygen-ion conductivity). These materials transport not only oxygen ions (functioning as selective oxygen separators) but also electrons back from the reactor side to the oxygen/reduction interface. No external electrodes are required, and, if the driving potential of transport is adequate, the partial oxidation reactions should be spontaneous. Such a system will operate without an externally applied potential. Oxygen is transported across the ceramic material in the form of oxygen ions, not oxygen molecules. Recent reports in the literature suggest that dense ceramic membranes made of these mixed conductors can successfully separate oxygen from air at flux rates that could be considered commercially feasible. Thus, these membranes have the potential to improve the economics of methane conversion processes. In principle, the dense ceramic materials can be shaped into hollow-tube reactors, in which air passes over the outside of the membrane and methane flows through the inside. The surfaces can also be reversed. The membrane is permeable to oxygen at high temperatures, but not to nitrogen or other gases. Thus, only oxygen from air can be transported through the membrane to the inside of the reactor surface, where it reacts with methane. Other geometric forms, such as honeycombs or corrugations, of the reactor are possible and can provide substantially greater surface areas for reaction
Breakdown of Fermi-liquid theory in a cuprate superconductor
The behaviour of electrons in solids is remarkably well described by Landau's
Fermi-liquid theory, which says that even though electrons in a metal interact
they can still be treated as well-defined fermions, called ``quasiparticles''.
At low temperature, the ability of quasiparticles to transport heat is strictly
given by their ability to transport charge, via a universal relation known as
the Wiedemann-Franz law, which no material in nature has been known to violate.
High-temperature superconductors have long been thought to fall outside the
realm of Fermi-liquid theory, as suggested by several anomalous properties, but
this has yet to be shown conclusively. Here we report on the first experimental
test of the Wiedemann-Franz law in a cuprate superconductor,
(Pr,Ce)CuO. Our study reveals a clear departure from the universal law
and provides compelling evidence for the breakdown of Fermi-liquid theory in
high-temperature superconductors.Comment: 7 pages, 3 figure
Electron Dynamics in NdCeCuO: Evidence for the Pseudogap State and Unconventional c-axis Response
Infrared reflectance measurements were made with light polarized along the a-
and c-axis of both superconducting and antiferromagnetic phases of electron
doped NdCeCuO. The results are compared to
characteristic features of the electromagnetic response in hole doped cuprates.
Within the CuO planes the frequency dependent scattering rate,
1/, is depressed below 650 cm; this behavior is a
hallmark of the pseudogap state. While in several hole doped compounds the
energy scales associated with the pseudogap and superconducting states are
quite close, we are able to show that in NdCeCuO
the two scales differ by more than one order of magnitude. Another feature of
the in-plane charge response is a peak in the real part of the conductivity,
, at 50-110 cm which is in sharp contrast with the
Drude-like response where is centered at . This
latter effect is similar to what is found in disordered hole doped cuprates and
is discussed in the context of carrier localization. Examination of the c-axis
conductivity gives evidence for an anomalously broad frequency range from which
the interlayer superfluid is accumulated. Compelling evidence for the pseudogap
state as well as other characteristics of the charge dynamics in
NdCeCuO signal global similarities of the cuprate
phase diagram with respect to electron and hole doping.Comment: Submitted to PR
Competing Orders and Quantum Phase Fluctuations on the Low-Energy Excitations and Pseudogap Phenomena of Cuprate Superconductors
We investigate the low-energy quasiparticle excitation spectra of cuprate
superconductors by incorporating both superconductivity (SC) and competing
orders (CO) in the bare Green's function and quantum phase fluctuations in the
proper self-energy. Our approach provides consistent explanations for various
empirical observations, including the excess subgap quasiparticle density of
states, ``dichotomy'' in the momentum-dependent quasiparticle coherence and the
temperature-dependent gap evolution, and the presence (absence) of the
low-energy pseudogap in hole- (electron-) type cuprates depending on the
relative scale of the CO and SC energy gaps.Comment: 6 pages, 4 figures. Corresponding author: Nai-Chang Yeh
([email protected]