Effect of dielectric barrier on rectification, injection and transport properties of printed organic diodes

International audienceRectification ratios of 10 5 were observed in printed organic copper/polytriarylamine (PTAA)/silver diodes with a thin insulating barrier layer at the copper/PTAA interface. To clarify the origin of the high rectification ratio in the diodes, the injection, transport and structure of the diodes with two different copper cathodes were examined using impedance spectroscopy and X-ray photoelectron spectroscopy (XPS). The impedance data confirm that the difference in diode performance arises from the copper/PTAA interface. The XPS measurements show that the copper surface in both diode structures is covered by a layer of Cu 2 O topped by an organic layer. The organic layer is thicker on one of the surfaces, which results in lower reverse currents and higher rectification ratios in the printed diodes. We suggest a model where a dipole at the dual insulating layer induces a shift in the semiconductor energy levels explaining the difference between the diodes with different cathodes

Ultraviolet absorption spectra of carbon dioxide and oxygen at elevated temperatures

Measurements of ultraviolet absorption spectra in lean and stochiometric premixed C2H4/O-2 flames have been performed with different flame temperatures (1400--1700 K). The spectra of the light transmitted through the flame were measured in the 200-270 nm range by using as an incoherent broadband light source the plasma kernel of optical breakdown generated by a focused pulsed laser beam. Measurements were performed far downstream of the main dame zone in a region where the concentrations of flame products reach equilibrium values. CO2 and O-2 are the major absorbing species, and their absorption cross sections at flame temperature have been evaluated by changing the flame conditions and thus obtaining different concentration of these species at the dame exit. At temperatures above 1500 K there is strong absorption (sigma (a) > 10 (20) cm(2)) due to both CO2 and O-2 in the 200-230 nm range. A clear increase can be seen in absorption of both CO2 and O-2 with increasing temperature. CO2 absorption cross sections also show a different dependence with respect to temperature for the different wavelengths