Room temperature ferromagnetic behavior in the hollandite-type titanium oxide

A hollandite-type K(x)Ti(8)O(16) polycrystalline sample has been prepared and studied by magnetization, resistivity and x-ray photoelectron spectroscopy (XPS). Room temperature ferromagnetic behavior is observed in the magnetic hysteresis measurement. The sample shows a semiconductive temperature dependence in the resistivity measurement. Analysis of the Ti 2p(3/2) core-level XPS spectrum indicates that the titanium ions have a mixed valence of Ti(4+) and Ti(3+). In addition, the valence band spectrum reveals that the 3d electrons tend to localize on Ti(3+) ions in the hollandite-type TiO(2) lattice. Also, analysis of the valence band spectrum shows that the prepared sample is a wide-gap oxide with a band gap of 3.6 eV. These results indicate that the present hollandite-type K(x)Ti(8)O(16) sample can be classified as a TiO(2)-based wide-gap semiconductor with Curie temperature above room temperature. Room temperature ferromagnetism (RTFM) decreases in the sample prepared under a strong reducing gas atmosphere, accompanied with the decrease in the resistivity. The results imply that the localized 3d electrons are responsible for the RTFM of the K(x)Ti(8)O(16) sample

Anisotropic Electronic Structure of the Kondo Semiconductor CeFe2Al10 Studied by Optical Conductivity

We report temperature-dependent polarized optical conductivity [$\sigma(\omega)$] spectra of CeFe$_2$Al$_{10}$, which is a reference material for CeRu$_2$Al$_{10}$ and CeOs$_2$Al$_{10}$ with an anomalous magnetic transition at 28 K. The $\sigma(\omega)$ spectrum along the b-axis differs greatly from that in the $ac$-plane, indicating that this material has an anisotropic electronic structure. At low temperatures, in all axes, a shoulder structure due to the optical transition across the hybridization gap between the conduction band and the localized $4f$ states, namely $c$-$f$ hybridization, appears at 55 meV. However, the gap opening temperature and the temperature of appearance of the quasiparticle Drude weight are strongly anisotropic indicating the anisotropic Kondo temperature. The strong anisotropic nature in both electronic structure and Kondo temperature is considered to be relevant the anomalous magnetic phase transition in CeRu$_2$Al$_{10}$ and CeOs$_2$Al$_{10}$.Comment: 5 pages, 4 figure

Cine-forum: “La felicidad en el séptimo arte"

Comunicación presentada en el Curso "La felicidad humana", dentro de los Cursos de verano UBU 201

Electronic structures of Cr1−δ_{1-\delta}X (X=S, Te) studied by Cr 2p soft x-ray magnetic circular dichroism

Cr 2p core excited XAS and XMCD spectra of ferromagnetic Cr$_{1-\delta}$Te with several concentrations of $\delta$=0.11-0.33 and ferrimagnetic Cr$_{5}$S$_{6}$ have been measured. The observed XMCD lineshapes are found to very weakly depend on $\delta$ for Cr$_{1-\delta}$Te. The experimental results are analyzed by means of a configuration-interaction cluster model calculation with consideration of hybridization and electron correlation effects. The obtained values of the spin magnetic moment by the cluster model analyses are in agreement with the results of the band structure calculation.The calculated result shows that the doped holes created by the Cr deficiency exist mainly in the Te 5porbital of Cr$_{1-\delta}$Te, whereas the holes are likely to be in Cr 3d state for Cr$_{5}$S$_{6}$.Comment: 8 pages, 6 figures, accepted for publication in Physical Review

Synchronization in Scale Free networks: The role of finite size effects

Synchronization problems in complex networks are very often studied by researchers due to its many applications to various fields such as neurobiology, e-commerce and completion of tasks. In particular, Scale Free networks with degree distribution $P(k)\sim k^{-\lambda}$, are widely used in research since they are ubiquitous in nature and other real systems. In this paper we focus on the surface relaxation growth model in Scale Free networks with $2.5< \lambda <3$, and study the scaling behavior of the fluctuations, in the steady state, with the system size $N$. We find a novel behavior of the fluctuations characterized by a crossover between two regimes at a value of $N=N^*$ that depends on $\lambda$: a logarithmic regime, found in previous research, and a constant regime. We propose a function that describes this crossover, which is in very good agreement with the simulations. We also find that, for a system size above $N^{*}$, the fluctuations decrease with $\lambda$, which means that the synchronization of the system improves as $\lambda$ increases. We explain this crossover analyzing the role of the network's heterogeneity produced by the system size $N$ and the exponent of the degree distribution.Comment: 9 pages and 5 figures. Accepted in Europhysics Letter