The Effect of Zonally Asymmetric Ozone Heating on the Northern Hemisphere Winter Polar Stratosphere

[1] Previous modeling studies have found significant differences in winter extratropical stratospheric temperatures depending on the presence or absence of zonally asymmetric ozone heating (ZAOH), yet the physical mechanism causing these differences has not been fully explained. The present study describes the effect of ZAOH on the dynamics of the Northern Hemisphere extratropical stratosphere using an ensemble of free-running atmospheric general circulation model simulations over the 1 December - 31 March period. We find that the simulations including ZAOH produce a significantly warmer and weaker stratospheric polar vortex in mid-February due to more frequent major stratospheric sudden warmings compared to the simulations using only zonal mean ozone heating. This is due to regions of enhanced Eliassen-Palm flux convergence found in the region between 40°N–70°N latitude and 10–0.05 hPa. These results are consistent with changes in the propagation of planetary waves in the presence of ZAOH predicted by an ozone-modified refractive index

Controls on Cyclic Formation of Quaternary Early Diagenetic Dolomite

The origin of sedimentary dolomite and the factors that control its formation within the geological record remain speculative. In most models, dolomite formation is linked to evaporative conditions, high water temperature, increasing Mg/Ca ratio, increasing alkalinity, and high amounts of biomass. Here we challenge these archetypal views, by documenting a case example of Quaternary dolomite which formed in Lake Van at constantly low temperature (<4°C) and without direct control of the latter conditions. Dolomite occurs within highstand sediments related to suborbital climate variability (Dansgaard‐Oeschger cycles). We propose that dolomite precipitation is a product of a microbially influenced process, triggered by ecological stress, resulting from reventilation of the water‐sediment interface. Independently from the validity of this hypothesis, our results call for a reevaluation of the paleoenvironmental conditions often invoked for early diagenetic dolomite‐rich intervals within sedimentary sequences and for caution when interpreting time series of subrecent lacustrine carbonates