379 research outputs found
Body-assisted van der Waals interaction between two atoms
Using fourth-order perturbation theory, a general formula for the van der
Waals potential of two neutral, unpolarized, ground-state atoms in the presence
of an arbitrary arrangement of dispersing and absorbing magnetodielectric
bodies is derived. The theory is applied to two atoms in bulk material and in
front of a planar multilayer system, with special emphasis on the cases of a
perfectly reflecting plate and a semi-infinite half space. It is demonstrated
that the enhancement and reduction of the two-atom interaction due to the
presence of a perfectly reflecting plate can be understood, at least in the
nonretarded limit, by using the method of image charges. For the semi-infinite
half space, both analytical and numerical results are presented.Comment: 17 pages, 9 figure
Enhanced dispersion interaction in confined geometry
The dispersion interaction between two point-like particles confined in a
dielectric slab between two plates of another dielectric medium is studied
within a continuum (Lifshitz) theory. The retarded (Casimir-Polder) interaction
at large inter-particle distances is found to be strongly enhanced as the
mismatch between the dielectric permittivities of the two media is increased.
The large-distance interaction is multiplied due to confinement by a factor of
at zero temperature, and by
at finite temperature, \gamma=\ein(0)/\eout(0)
being the ratio between the static dielectric permittivities of the inner and
outer media. This confinement-induced amplification of the dispersion
interaction can reach several orders of magnitude.Comment: 4 page
REDD+ on the rocks? Conflict over forest and politics of justice in Vietnam
In Vietnam, villagers involved in a REDD+ (reduced emissions from deforestation and forest degradation) pilot protect areas with rocks which have barely a tree on them. The apparent paradox indicates how actual practices differ from general ideas about REDD+ due to ongoing conflict over forest, and how contestations over the meaning of justice are a core element in negotiations over REDD+. We explore these politics of justice by examining how the actors involved in the REDD+ pilot negotiate the particular subjects, dimensions, and authority of justice considered relevant, and show how politics of justice are implicit to practical decisions in project implementation. Contestations over the meaning of justice are an important element in the practices and processes constituting REDD+ at global, national and local levels, challenging uniform definitions of forest justice and how forests ought to be managed
Excluded volume effects in macromolecular forces and ion-interface interactions
A charged Yukawa liquid confined in a slit nanopore is studied in order to
understand excluded volume effects in the interaction force between the pore
walls. A previously developed self-consistent scheme (S. Buyukdagli el al., J.
Stat. Mech. P05033 (2011)) and a new simpler variational procedure that
self-consistently couple image forces, surface charge induced electric field
and pore modified core interactions are used to this aim. For neutral pores, it
is shown that with increasing pore size, the theory predicts a transition of
the interplate pressure from an attractive to a strongly repulsive regime
associated with an ionic packing state, an effect observed in previous Monte
Carlo simulations for hard core charges. The role of the range of core
interactions in the ionic rejection and interplate pressure is thoroughly
analyzed. We show that the physics of the system can be split into two
screening regimes. The ionic packing effect takes place in the regime of
moderately screened core interactions characterized with the bare screening
parameter of the Yukawa potential b<3/lB, where lB is the Bjerrum length. In
the second regime of strongly screened core interactions b>3/lB, solvation
forces associated with these interactions positively contribute to the ionic
rejection driven by electrostatic forces and enhance the magnitude of the
attractive pressure. The pronounced dependence of the interplate pressure and
ionic partition coefficients on the magnitude and the range of core
interactions indicates excluded volume effects as an important ion specificity
and a non-negligible ingredient for the stability of macromolecules in
electrolyte solutions.Comment: Accepted for publication in J. Chem. Phy
Hydrodynamic Processes and Inlet Dynamics of Chilka, A Tropical Lagoon on East Coast of India
Source: ICHE Conference Archive - https://mdi-de.baw.de/icheArchiv
The Van der Waals interaction of the hydrogen molecule - an exact local energy density functional
We verify that the van der Waals interaction and hence all dispersion
interactions for the hydrogen molecule given by: W"= -{A/R^6}-{B/R^8}-{C/R^10}-
..., in which R is the internuclear separation, are exactly soluble. The
constants A=6.4990267..., B=124.3990835 ... and C=1135.2140398... (in Hartree
units) first obtained approximately by Pauling and Beach (PB) [1] using a
linear variational method, can be shown to be obtainable to any desired
accuracy via our exact solution. In addition we shall show that a local energy
density functional can be obtained, whose variational solution rederives the
exact solution for this problem. This demonstrates explicitly that a static
local density functional theory exists for this system. We conclude with
remarks about generalising the method to other hydrogenic systems and also to
helium.Comment: 11 pages, 13 figures and 28 reference
Shear Viscosity of Clay-like Colloids in Computer Simulations and Experiments
Dense suspensions of small strongly interacting particles are complex
systems, which are rarely understood on the microscopic level. We investigate
properties of dense suspensions and sediments of small spherical Al_2O_3
particles in a shear cell by means of a combined Molecular Dynamics (MD) and
Stochastic Rotation Dynamics (SRD) simulation. We study structuring effects and
the dependence of the suspension's viscosity on the shear rate and shear
thinning for systems of varying salt concentration and pH value. To show the
agreement of our results to experimental data, the relation between bulk pH
value and surface charge of spherical colloidal particles is modeled by
Debye-Hueckel theory in conjunction with a 2pK charge regulation model.Comment: 15 pages, 8 figure
Genetically altered AMPA-type glutamate receptor kinetics in interneurons disrupt long-range synchrony of gamma oscillation
Gamma oscillations synchronized between distant neuronal populations may be critical for binding together brain regions devoted to common processing tasks. Network modeling predicts that such synchrony depends in part on the fast time course of excitatory postsynaptic potentials (EPSPs) in interneurons, and that even moderate slowing of this time course will disrupt synchrony. We generated mice with slowed interneuron EPSPs by gene targeting, in which the gene encoding the 67-kDa form of glutamic acid decarboxylase (GAD67) was altered to drive expression of the α-amino-3-hydroxy-5-methyl-4-isoxazolepropionic acid (AMPA) glutamate receptor subunit GluR-B. GluR-B is a determinant of the relatively slow EPSPs in excitatory neurons and is normally expressed at low levels in γ-aminobutyric acid (GABA)ergic interneurons, but at high levels in the GAD-GluR-B mice. In both wild-type and GAD-GluR-B mice, tetanic stimuli evoked gamma oscillations that were indistinguishable in local field potential recordings. Remarkably, however, oscillation synchrony between spatially separated sites was severely disrupted in the mutant, in association with changes in interneuron firing patterns. The congruence between mouse and model suggests that the rapid time course of AMPA receptor-mediated EPSPs in interneurons might serve to allow gamma oscillations to synchronize over distance
(N)-methanocarba-2MeSADP (MRS2365) is a subtype-specific agonist that induces rapid desensitization of the P2Y1 receptor of human platelets
Adenosine diphosphate (ADP) initiates and maintains sustained aggregation of platelets through simultaneous activation of both the Gq-coupled P2Y1 receptor and the Gi-coupled P2Y12 receptor. We recently described the synthesis and P2Y1 receptor-specific agonist activity of (N)-methano-carba-2MeSADP (MRS2365). Consequences of selective activation of the P2Y1 receptor by MRS2365 have been further examined in human platelets. Whereas MRS2365 alone only induced shape change, addition of MRS2365 following epinephrine treatment, which activates the Gi/z-linked, α2A-adrenergic receptor, resulted in sustained aggregation that was indistinguishable from that observed with ADP. Conversely, the platelet shape change promoted by ADP in the presence of the GPIIb/IIIa antagonist eptifibatide was similar to that promoted by MRS2365. Preaddition of the high affinity P2Y1 receptor antagonist MRS2500 inhibited the effect of MRS2365, whereas addition of MRS2500 subsequent to MRS2365 reversed the MRS2365-induced shape change. Preactivation of the P2Y1 receptor with MRS2365 for 2 min resulted in marked loss of capacity of ADP to induce aggregation as evidenced by a greater than 20-fold rightward shift in the concentration effect curve of ADP. This inhibitory effect of P2Y1 receptor activation was dependent on the concentration of MRS2365 (EC50 = 34 nM). The inhibitory effect of preincubation with MRS2365 was circumvented by activation of the Gq-coupled 5-HT2a receptor suggesting that MRS2365 induces loss of the ADP response as a consequence of desensitization of the Gq-coupled P2Y1 receptor. The time course of MRS2365-induced loss of aggregation response to epinephrine was similar to that observed with ADP. These results further demonstrate the P2Y1 receptor selectivity of MRS2365 and illustrate the occurrence of agonist-induced desensitization of the P2Y1 receptor of human platelets studied in the absence of P2Y12 receptor activation
Phase behavior and material properties of hollow nanoparticles
Effective pair potentials for hollow nanoparticles like the ones made from
carbon (fullerenes) or metal dichalcogenides (inorganic fullerenes) consist of
a hard core repulsion and a deep, but short-ranged, van der Waals attraction.
We investigate them for single- and multi-walled nanoparticles and show that in
both cases, in the limit of large radii the interaction range scales inversely
with the radius, , while the well depth scales linearly with . We predict
the values of the radius and the wall thickness at which the gas-liquid
coexistence disappears from the phase diagram. We also discuss unusual material
properties of the solid, which include a large heat of sublimation and a small
surface energy.Comment: Revtex, 13 pages with 8 Postscript files included, submitted to Phys.
Rev.
- …