Interlayer excitons in MoSe 2 /2D perovskite hybrid heterostructures – the interplay between charge and energy transfer

International audienceInvestigation of 2D perovskite/MoSe 2 heterostructures shows that the charge transfer leads to the formation of inter-layer excitons

Interlayer excitons in MoSe2/2D perovskite hybrid heterostructures – the interplay between charge and energy transfer

van der Waals crystals have opened a new and exciting chapter in heterostructure research, removing the lattice matching constraint characteristics of epitaxial semiconductors. They provide unprecedented flexibility for heterostructure design. Combining two-dimensional (2D) perovskites with other 2D materials, in particular transition metal dichalcogenides (TMDs), has recently emerged as an intriguing way to design hybrid opto-electronic devices. However, the excitation transfer mechanism between the layers (charge or energy transfer) remains to be elucidated. Here, we investigate PEA(2)PbI(4)/MoSe2 and (BA)(2)PbI4/MoSe2 heterostructures by combining optical spectroscopy and density functional theory (DFT) calculations. We show that band alignment facilitates charge transfer. Namely, holes are transferred from TMDs to 2D perovskites, while the electron transfer is blocked, resulting in the formation of interlayer excitons. Moreover, we show that the energy transfer mechanism can be turned on by an appropriate alignment of the excitonic states, providing a rule of thumb for the deterministic control of the excitation transfer mechanism in TMD/2D-perovskite heterostructures

Interlayer excitons in MoSe2/2D perovskite hybrid heterostructures - the interplay between charge and energy transfer

van der Waals crystals have opened a new and exciting chapter in heterostructure research, removing the lattice matching constraint characteristics of epitaxial semiconductors. They provide unprecedented flexibility for heterostructure design. Combining two-dimensional (2D) perovskites with other 2D materials, in particular transition metal dichalcogenides (TMDs), has recently emerged as an intriguing way to design hybrid opto-electronic devices. However, the excitation transfer mechanism between the layers (charge or energy transfer) remains to be elucidated. Here, we investigate PEA2PbI4/MoSe2 and (BA)2PbI4/MoSe2 heterostructures by combining optical spectroscopy and density functional theory (DFT) calculations. We show that band alignment facilitates charge transfer. Namely, holes are transferred from TMDs to 2D perovskites, while the electron transfer is blocked, resulting in the formation of interlayer excitons. Moreover, we show that the energy transfer mechanism can be turned on by an appropriate alignment of the excitonic states, providing a rule of thumb for the deterministic control of the excitation transfer mechanism in TMD/2D-perovskite heterostructures

Unusual geologic evidence of coeval seismic shaking and tsunamis shows variability in earthquake size and recurrence in the area of the giant 1960 Chile earthquake

An uncommon coastal sedimentary record combines evidence for seismic shaking and coincident tsunami inundation since AD 1000 in the region of the largest earthquake recorded instrumentally: the giant 1960 southern Chile earthquake (Mw 9.5). The record reveals significant variability in the size and recurrence of megathrust earthquakes and ensuing tsunamis along this part of the Nazca-South American plate boundary. A 500-m long coastal outcrop on Isla Chiloé, midway along the 1960 rupture, provides continuous exposure of soil horizons buried locally by debris-flow diamicts and extensively by tsunami sand sheets. The diamicts flattened plants that yield geologically precise ages to correlate with well-dated evidence elsewhere. The 1960 event was preceded by three earthquakes that probably resembled it in their effects, in AD 898–1128, 1300–1398 and 1575, and by five relatively smaller intervening earthquakes. Earthquakes and tsunamis recurred exceptionally often between AD 1300 and 1575. Their average recurrence interval of 85 years only slightly exceeds the time already elapsed since 1960. This inference is of serious concern because no earthquake has been anticipated in the region so soon after the 1960 event, and current plate locking suggests that some segments of the boundary are already capable of producing large earthquakes. This long-term earthquake and tsunami history of one of the world's most seismically active subduction zones provides an example of variable rupture mode, in which earthquake size and recurrence interval vary from one earthquake to the next