Adsorption and diffusion of selenite on Boda Claystone Formation

This study provides adsorption and diffusion data of selenite on Boda Claystone Formation (BCF) which is a potential host rock of a deep geological disposal of high-level radioactive waste. The experiments were performed on two diverse core samples: one albitic claystone sample characteristic for the entire BCF and one pyrite containing sample sparsely occurring in BCF. The experiments were carried out under atmospheric conditions. Batch experiments were carried out to study the kinetics of adsorption at a high initial concentration (1.2 × 10−3 M), the adsorption isotherms and reversibility were investigated in the 10−10–10−3 M concentration range. Adsorption onto petrographic thin sections was done to study the elemental distribution on the microscale and the oxidation state of selenium. The maximum of the distribution coefficient was found as Kd ≈ 200 L/kg and a decrease was experienced around 10−6–10−7 M equilibrium concentration, which showed similarities to other argillaceous rocks. Isotopic exchange experiments revealed reversibility of selenite adsorption. Diffusion was studied with through-diffusion and in-diffusion experiments. Using X-ray fluorescence, despite a low initial concentration of 2.3 × 10−5 M in the in-diffusion experiment, a meaningful diffusion profile of selenium could be obtained, from which the selenite apparent diffusion coefficient Dappselenite = (1.5–4.3) × 10−14 m2/s and the selenite rock capacity factor αselenite = 1.4–2.2 were determined. As selenium species are redox sensitive the oxidation state of adsorbed species was studied with X-ray absorption near edge structure spectroscopy on Se–K edge. Adsorbed selenium remained in +IV oxidation state, however reduction was experienced on the pyritic sample

The 1.4 GHz light curve of GRB 970508

We report on Westerbork 1.4 GHz radio observations of the radio counterpart to $\gamma$-ray burst GRB~970508, between 0.80 and 138 days after this event. The 1.4 GHz light curve shows a transition from optically thick to thin emission between 39 and 54 days after the event. We derive the slope $p$ of the spectrum of injected electrons ($dN/d\gamma_{e}\propto\gamma_{e}^{-p}$) in two independent ways which yield values very close to $p=2.2$. This is in agreement with a relativistic dynamically near-adiabatic blast wave model whose emission is dominated by synchrotron radiation and in which a significant fraction of the electrons cool fast.Comment: Paper I. Accepted for publication in the Astrophysical Journal Letter

SPT-CL J0546-5345: A Massive z > 1 Galaxy Cluster Selected Via the Sunyaev-Zel'dovich Effect with the South Pole Telescope

We report the spectroscopic confirmation of SPT-CL J0546-5345 at = 1.067. To date this is the most distant cluster to be spectroscopically confirmed from the 2008 South Pole Telescope (SPT) catalog, and indeed the first z > 1 cluster discovered by the Sunyaev-Zel'dovich Effect (SZE). We identify 21 secure spectroscopic members within 0.9 Mpc of the SPT cluster position, 18 of which are quiescent, early-type galaxies. From these quiescent galaxies we obtain a velocity dispersion of 1179^{+232}_{-167} km/s, ranking SPT-CL J0546-5345 as the most dynamically massive cluster yet discovered at z > 1. Assuming that SPT-CL J0546-5345 is virialized, this implies a dynamical mass of M_200 = 1.0^{+0.6}_{-0.4} x 10^{15} Msun, in agreement with the X-ray and SZE mass measurements. Combining masses from several independent measures leads to a best-estimate mass of M_200 = (7.95 +/- 0.92) x 10^{14} Msun. The spectroscopic confirmation of SPT-CL J0546-5345, discovered in the wide-angle, mass-selected SPT cluster survey, marks the onset of the high redshift SZE-selected galaxy cluster era.Comment: ApJ, in pres

UBVRI Light Curves of 44 Type Ia Supernovae

We present UBVRI photometry of 44 type-Ia supernovae (SN Ia) observed from 1997 to 2001 as part of a continuing monitoring campaign at the Fred Lawrence Whipple Observatory of the Harvard-Smithsonian Center for Astrophysics. The data set comprises 2190 observations and is the largest homogeneously observed and reduced sample of SN Ia to date, nearly doubling the number of well-observed, nearby SN Ia with published multicolor CCD light curves. The large sample of U-band photometry is a unique addition, with important connections to SN Ia observed at high redshift. The decline rate of SN Ia U-band light curves correlates well with the decline rate in other bands, as does the U-B color at maximum light. However, the U-band peak magnitudes show an increased dispersion relative to other bands even after accounting for extinction and decline rate, amounting to an additional ~40% intrinsic scatter compared to B-band.Comment: 84 authors, 71 pages, 51 tables, 10 figures. Accepted for publication in the Astronomical Journal. Version with high-res figures and electronic data at http://astron.berkeley.edu/~saurabh/cfa2snIa

Discovery and Cosmological Implications of SPT-CL J2106-5844, the Most Massive Known Cluster at z > 1

Using the South Pole Telescope (SPT), we have discovered the most massive known galaxy cluster at z > 1, SPT-CL J2106-5844. In addition to producing a strong Sunyaev-Zel'dovich effect signal, this system is a luminous X-ray source and its numerous constituent galaxies display spatial and color clustering, all indicating the presence of a massive galaxy cluster. VLT and Magellan spectroscopy of 18 member galaxies shows that the cluster is at z = 1.132^+0.002_-0.003. Chandra observations obtained through a combined HRC-ACIS GTO program reveal an X-ray spectrum with an Fe K line redshifted by z = 1.18 +/- 0.03. These redshifts are consistent with galaxy colors in extensive optical, near-infrared, and mid-infrared imaging. SPT-CL J2106-5844 displays extreme X-ray properties for a cluster, having a core-excluded temperature of kT = 11.0^+2.6_-1.9 keV and a luminosity (within r_500) of L_X (0.5 - 2.0 keV) = (13.9 +/- 1.0) x 10^44 erg/s. The combined mass estimate from measurements of the Sunyaev-Zel'dovich effect and X-ray data is M_200 = (1.27 +/- 0.21) x 10^15 M_sun. The discovery of such a massive gravitationally collapsed system at high redshift provides an interesting laboratory for galaxy formation and evolution, and is a powerful probe of extreme perturbations of the primordial matter density field. We discuss the latter, determining that, under the assumption of LambdaCDM cosmology with only Gaussian perturbations, there is only a 7% chance of finding a galaxy cluster similar to SPT-CL J2106-5844 in the 2500 deg^2 SPT survey region, and that only one such galaxy cluster is expected in the entire sky.Comment: 10 pages, submitted to Ap

Effect of sitagliptin on cardiovascular outcomes in type 2 diabetes

BACKGROUND: Data are lacking on the long-term effect on cardiovascular events of adding sitagliptin, a dipeptidyl peptidase 4 inhibitor, to usual care in patients with type 2 diabetes and cardiovascular disease. METHODS: In this randomized, double-blind study, we assigned 14,671 patients to add either sitagliptin or placebo to their existing therapy. Open-label use of antihyperglycemic therapy was encouraged as required, aimed at reaching individually appropriate glycemic targets in all patients. To determine whether sitagliptin was noninferior to placebo, we used a relative risk of 1.3 as the marginal upper boundary. The primary cardiovascular outcome was a composite of cardiovascular death, nonfatal myocardial infarction, nonfatal stroke, or hospitalization for unstable angina. RESULTS: During a median follow-up of 3.0 years, there was a small difference in glycated hemoglobin levels (least-squares mean difference for sitagliptin vs. placebo, -0.29 percentage points; 95% confidence interval [CI], -0.32 to -0.27). Overall, the primary outcome occurred in 839 patients in the sitagliptin group (11.4%; 4.06 per 100 person-years) and 851 patients in the placebo group (11.6%; 4.17 per 100 person-years). Sitagliptin was noninferior to placebo for the primary composite cardiovascular outcome (hazard ratio, 0.98; 95% CI, 0.88 to 1.09; P<0.001). Rates of hospitalization for heart failure did not differ between the two groups (hazard ratio, 1.00; 95% CI, 0.83 to 1.20; P = 0.98). There were no significant between-group differences in rates of acute pancreatitis (P = 0.07) or pancreatic cancer (P = 0.32). CONCLUSIONS: Among patients with type 2 diabetes and established cardiovascular disease, adding sitagliptin to usual care did not appear to increase the risk of major adverse cardiovascular events, hospitalization for heart failure, or other adverse events

Shedding Light on the Galaxy Luminosity Function

From as early as the 1930s, astronomers have tried to quantify the statistical nature of the evolution and large-scale structure of galaxies by studying their luminosity distribution as a function of redshift - known as the galaxy luminosity function (LF). Accurately constructing the LF remains a popular and yet tricky pursuit in modern observational cosmology where the presence of observational selection effects due to e.g. detection thresholds in apparent magnitude, colour, surface brightness or some combination thereof can render any given galaxy survey incomplete and thus introduce bias into the LF. Over the last seventy years there have been numerous sophisticated statistical approaches devised to tackle these issues; all have advantages -- but not one is perfect. This review takes a broad historical look at the key statistical tools that have been developed over this period, discussing their relative merits and highlighting any significant extensions and modifications. In addition, the more generalised methods that have emerged within the last few years are examined. These methods propose a more rigorous statistical framework within which to determine the LF compared to some of the more traditional methods. I also look at how photometric redshift estimations are being incorporated into the LF methodology as well as considering the construction of bivariate LFs. Finally, I review the ongoing development of completeness estimators which test some of the fundamental assumptions going into LF estimators and can be powerful probes of any residual systematic effects inherent magnitude-redshift data.Comment: 95 pages, 23 figures, 3 tables. Now published in The Astronomy & Astrophysics Review. This version: bring in line with A&AR format requirements, also minor typo corrections made, additional citations and higher rez images adde