Do cover crops increase or decrease nitrous oxide emissions? A meta-analysis.

There are many environmental benefits to incorporating cover crops into crop rotations, such as their potential to decrease soil erosion, reduce nitrate (NO3) leaching, and increase soil organic matter. Some of these benefits impact other agroecosystem processes, such as greenhouse gas emissions. In particular, there is not a consensus in the literature regarding the effect of cover crops on nitrous oxide (N2O) emissions. Compared to site-specific studies, meta-analysis can provide a more general investigation into these effects. Twenty-six peer-reviewed articles including 106 observations of cover crop effects on N2O emissions from the soil surface were analyzed according to their response ratio, the natural log of the N2O flux with a cover crop divided by the N2O flux without a cover crop (LRR). Forty percent of the observations had negative LRRs, indicating a cover crop treatment which decreased N2O, while 60% had positive LRRs indicating a cover crop treatment which increased N2O. There was a significant interaction between N rate and the type of cover crop where legumes had higher LRRs at lower N rates than nonlegume species. When cover crop residues were incorporated into the soil, LRRs were significantly higher than those where residue was not incorporated. Geographies with higher total precipitation and variability in precipitation tended to produce higher LRRs. Finally, data points measured during cover crop decomposition had large positive LRRs and were larger than those measured when the cover crop was alive. In contrast, those data points measuring for a full year had LRRs close to zero, indicating that there was a balance between periods when cover crops increased N2O and periods when cover crops decreased emissions. Therefore, N2O measurements over the entire year may be needed to determine the net effect of cover crops on N2O. The data included in this meta-analysis indicate some overarching crop management practices that reduce direct N2O emissions from the soil surface, such as no soil incorporation of residues and use of non-legume cover crop species. However, our results demonstrate that cover crops do not always reduce direct N2O emissions from the soil surface in the short term and that more work is needed to understand the full global warming potential of cover crop management

Do cover crops increase or decrease nitrous oxide emissions? A meta-analysis

There are many environmental benefits to incorporating cover crops into crop rotations, such as their potential to decrease soil erosion, reduce nitrate (NO3) leaching, and increase soil organic matter. Some of these benefits impact other agroecosystem processes, such as greenhouse gas emissions. In particular, there is not a consensus in the literature regarding the effect of cover crops on nitrous oxide (N2O) emissions. Compared to site-specific studies, meta-analysis can provide a more general investigation into these effects. Twenty-six peer-reviewed articles including 106 observations of cover crop effects on N2O emissions from the soil surface were analyzed according to their response ratio, the natural log of the N2O flux with a cover crop divided by the N2O flux without a cover crop (LRR). Forty percent of the observations had negative LRRs, indicating a cover crop treatment which decreased N2O, while 60% had positive LRRs indicating a cover crop treatment which increased N2O. There was a significant interaction between N rate and the type of cover crop where legumes had higher LRRs at lower N rates than nonlegume species. When cover crop residues were incorporated into the soil, LRRs were significantly higher than those where residue was not incorporated. Geographies with higher total precipitation and variability in precipitation tended to produce higher LRRs. Finally, data points measured during cover crop decomposition had large positive LRRs and were larger than those measured when the cover crop was alive. In contrast, those data points measuring for a full year had LRRs close to zero, indicating that there was a balance between periods when cover crops increased N2O and periods when cover crops decreased emissions. Therefore, N2O measurements over the entire year may be needed to determine the net effect of cover crops on N2O. The data included in this meta-analysis indicate some overarching crop management practices that reduce direct N2O emissions from the soil surface, such as no soil incorporation of residues and use of nonlegume cover crop species. However, our results demonstrate that cover crops do not always reduce direct N2O emissions from the soil surface in the short term and that more work is needed to understand the full global warming potential of cover crop management

Dibenzo[hi,st]ovalene as Highly Luminescent Nanographene: Efficient Synthesis via Photochemical Cyclodehydroiodination, Optoelectronic Properties, and Single-Molecule Spectroscopy

Dibenzo[hi,st]ovalene (DBOV), as a new nanographene, has demonstrated promising optical properties, such as red emission with a high fluorescence quantum yield of 79% and stimulated emission, as well as high thermal stability and photostability, which indicated its promise as a light-emitting and optical gain material. However, the previous synthetic routes required at least 12 steps. This obstructed access to different derivatives, e.g., to obtain crystals suitable for X-ray diffraction analysis and to tune the optoelectronic properties. Here, we report an efficient synthetic pathway to DBOV based on a sequential iodination-benzannulation of bi(naphthylphenyl)diyne, followed by photochemical cyclodehydroiodination (PCDHI). This protocol included a fused bischrysene as a key intermediate and furnished scalable amounts of meso-substituted DBOV derivatives with different substituents. DBOV with 2,6-dimethylphenyl groups could be used for single-crystal X-ray analysis, revealing the precise structure of the DBOV core. The optoelectronic properties of the DBOV derivatives were investigated by UV-vis absorption and fluorescence spectroscopy, cyclic voltammetry, and density functional theory calculations. Single-molecule spectroscopy at room and low temperatures provided novel insights into the photophysics of DBOV embedded in a polymer film. As a result of weak coupling of the optical transitions to the matrix, single-molecule emission spectra at 4.5 K showed narrow vibronic lines. The fluorescence autocorrelation function covering 9 orders of magnitude in time displayed high contrast photon antibunching and bunching, from which the fluorescence decay rate and the triplet population and depopulation rates could be retrieved. Remarkably, the intersystem crossing rate into the triplet state decreased by more than an order of magnitude at low temperature, demonstrating that temperature can be a crucial parameter to boost single photon emission of an aromatic hydrocarbon

Generating Single Microwave Photons in a Circuit

Electromagnetic signals in circuits consist of discrete photons, though conventional voltage sources can only generate classical fields with a coherent superposition of many different photon numbers. While these classical signals can control and measure bits in a quantum computer (qubits), single photons can carry quantum information, enabling non-local quantum interactions, an important resource for scalable quantum computing. Here, we demonstrate an on-chip single photon source in a circuit quantum electrodynamics (QED) architecture, with a microwave transmission line cavity that collects the spontaneous emission of a single superconducting qubit with high efficiency. The photon source is triggered by a qubit rotation, as a photon is generated only when the qubit is excited. Tomography of both qubit and fluorescence photon shows that arbitrary qubit states can be mapped onto the photon state, demonstrating an ability to convert a stationary qubit into a flying qubit. Both the average power and voltage of the photon source are characterized to verify performance of the system. This single photon source is an important addition to a rapidly growing toolbox for quantum optics on a chip.Comment: 6 pages, 5 figures, hires version at http://www.eng.yale.edu/rslab/papers/single_photon_hires.pd

Laser-induced resonance shifts of single molecules self-coupled by a metallic surface

The spectral properties of single molecules placed near a metallic surface are investigated at low temperatures. Because of the high quality factor of the optical resonance, a laser-induced shift of the molecular lines is evidenced for the first time. The shift dependence on the laser excitation intensity and on the dephasing rate of the transition dipole is studied. A simple theoretical model of a laser-driven molecule self-coupled by a mirror is developed to qualitatively interpret the observations.Peer reviewedPhysic

PG545, a dual heparanase and angiogenesis inhibitor, induces potent anti-tumour and anti-metastatic efficacy in preclinical models

BACKGROUND: PG545 is a heparan sulfate (HS) mimetic that inhibits tumour angiogenesis by sequestering angiogenic growth factors in the extracellular matrix (ECM), thus limiting subsequent binding to receptors. Importantly, PG545 also inhibits heparanase, the only endoglycosidase which cleaves HS chains in the ECM. The aim of the study was to assess PG545 in various solid tumour and metastasis models

Methodology of calculation of construction and hydrodynamic parameters of a foam layer apparatus for mass-transfer processes

Промислова реалізація методу стабілізації газорідинного шару дозволяє значно розширити галузь застосування пінних апаратів і відкриває нові можливості інтенсифікації технологічних процесів з одночасним створенням маловідходних технологій. У статті встановлені основні параметри, що впливають на гідродинаміку пінних апаратів, розглянуті основні конструкції та режими роботи пінних апаратів. Виявлено зв'язок гідродинамічних параметрів. Розглянуто гідродинамічні закономірності пінного шару. Вказані фактори, що впливають на процес масообміну, як в газовій, так і в рідкій фазах. Проведений аналіз ряду досліджень показав, що перспективним напрямком інтенсифікації процесу масообміну є розробка апаратів з трифазним псевдозрідженим шаром зрошуваної насадки складних форм із сітчастих матеріалів. Отже, необхідне проведення спеціальних досліджень гідродинамічних режимів роботи апарату з сітчастою насадкою і визначенням параметрів, що впливають на швидкість переходу насадки з одного режиму в інший.Industrial implementation of the stabilization method of the gas-liquid layer can significantly expand the field of use of foaming apparatus and opens up new opportunities for intensifying technological processes with the simultaneous creation of low-waste technologies. The article establishes the basic parameters influencing the hydrodynamics of foam apparatus, considers the basic constructions and operating modes of foam apparatus. The connection of hydrodynamic parameters is revealed. The hydrodynamic laws of the foam layer are considered. The indicated factors affecting the process of mass transfer, both in the gas and in the liquid phases. The conducted analysis of a number of studies showed that the perspective direction of intensification of the mass transfer process is the development of apparatuses with a three-phase fluidized bed of an irrigated nozzle of complex forms with mesh materials

Untersuchung der Struktur und Dynamik adsorbierter Farbstoffmolekuele mit Hilfe der optisch hochaufloesenden Methoden der Fluoreszenzlinienverschmaelerung und des permanenten spektralen Lochbrennens

Available from TIB Hannover: DW 5629 / FIZ - Fachinformationszzentrum Karlsruhe / TIB - Technische InformationsbibliothekSIGLEDEGerman