1,144 research outputs found
Antiresonance phase shift in strongly coupled cavity QED
We investigate phase shifts in the strong coupling regime of single-atom
cavity quantum electrodynamics (QED). On the light transmitted through the
system, we observe a phase shift associated with an antiresonance and show that
both its frequency and width depend solely on the atom, despite the strong
coupling to the cavity. This shift is optically controllable and reaches 140
degrees - the largest ever reported for a single emitter. Our result offers a
new technique for the characterization of complex integrated quantum circuits.Comment: 5 pages, 5 figure
Optically trapped atom interferometry using the clock transition of large Rb-87 Bose-Einstein condensates
We present a Ramsey-type atom interferometer operating with an optically
trapped sample of 10^6 Bose-condensed Rb-87 atoms. The optical trap allows us
to couple the |F =1, mF =0>\rightarrow |F =2, mF =0> clock states using a
single photon 6.8GHz microwave transition, while state selective readout is
achieved with absorption imaging. Interference fringes with contrast
approaching 100% are observed for short evolution times. We analyse the process
of absorption imaging and show that it is possible to observe atom number
variance directly, with a signal-to-noise ratio ten times better than the
atomic projection noise limit on 10^6 condensate atoms. We discuss the
technical and fundamental noise sources that limit our current system, and
outline the improvements that can be made. Our results indicate that, with
further experimental refinements, it will be possible to produce and measure
the output of a sub-shot-noise limited, large atom number BEC-based
interferometer.
In an addendum to the original paper, we attribute our inability to observe
quantum projection noise to the stability of our microwave oscillator and
background magnetic field. Numerical simulations of the Gross-Pitaevskii
equations for our system show that dephasing due to spatial dynamics driven by
interparticle interactions account for much of the observed decay in fringe
visibility at long interrogation times. The simulations show good agreement
with the experimental data when additional technical decoherence is accounted
for, and suggest that the clock states are indeed immiscible. With smaller
samples of 5 \times 10^4 atoms, we observe a coherence time of {\tau} =
(1.0+0.5-0.3) s.Comment: 22 pages, 6 figures Addendum: 11 pages, 6 figure
Cold atom gravimetry with a Bose-Einstein Condensate
We present a cold atom gravimeter operating with a sample of Bose-condensed
Rubidium-87 atoms. Using a Mach-Zehnder configuration with the two arms
separated by a two-photon Bragg transition, we observe interference fringes
with a visibility of 83% at T=3 ms. We exploit large momentum transfer (LMT)
beam splitting to increase the enclosed space-time area of the interferometer
using higher-order Bragg transitions and Bloch oscillations. We also compare
fringes from condensed and thermal sources, and observe a reduced visibility of
58% for the thermal source. We suspect the loss in visibility is caused partly
by wavefront aberrations, to which the thermal source is more susceptible due
to its larger transverse momentum spread. Finally, we discuss briefly the
potential advantages of using a coherent atomic source for LMT, and present a
simple mean-field model to demonstrate that with currently available
experimental parameters, interaction-induced dephasing will not limit the
sensitivity of inertial measurements using freely-falling, coherent atomic
sources.Comment: 6 pages, 4 figures. Final version, published PR
Continuous parametric feedback cooling of a single atom in an optical cavity
We demonstrate a new feedback algorithm to cool a single neutral atom trapped
inside a standing-wave optical cavity. The algorithm is based on parametric
modulation of the confining potential at twice the natural oscillation
frequency of the atom, in combination with fast and repetitive atomic position
measurements. The latter serve to continuously adjust the modulation phase to a
value for which parametric excitation of the atomic motion is avoided. Cooling
is limited by the measurement back action which decoheres the atomic motion
after only a few oscillations. Nonetheless, applying this feedback scheme to a
~ 5 kHz oscillation mode increases the average storage time of a single atom in
the cavity by a factor of 60 to more than 2 seconds. In contrast to previous
feedback schemes, our algorithm is also capable of cooling a much faster ~ 500
kHz oscillation mode within just microseconds. This demonstrates that
parametric cooling is a powerful technique that can be applied in all
experiments where optical access is limited.Comment: 7 pages, 5 figure
Optically guided linear Mach Zehnder atom interferometer
We demonstrate a horizontal, linearly guided Mach Zehnder atom interferometer
in an optical waveguide. Intended as a proof-of-principle experiment, the
interferometer utilises a Bose-Einstein condensate in the magnetically
insensitive |F=1,mF=0> state of Rubidium-87 as an acceleration sensitive test
mass. We achieve a modest sensitivity to acceleration of da = 7x10^-4 m/s^2.
Our fringe visibility is as high as 38% in this optically guided atom
interferometer. We observe a time-of-flight in the waveguide of over half a
second, demonstrating the utility of our optical guide for future sensors.Comment: 6 pages, 3 figures. Submitted to Phys. Rev.
Enhanced photocatalytic activity of CuWO4 doped TiO2 photocatalyst towards carbamazepine removal under UV irradiation
Abatement of contaminants of emerging concerns (CECs) in water sources has been widely studied employing TiO2 based heterogeneous photocatalysis. However, low quantum energy yield among other limitations of titania has led to its modification with other semiconductor materials for improved photocatalytic activity. In this work, a 0.05 wt.% CuWO4 over TiO2 was prepared as a powder composite. Each component part synthesized via the sol-gel method for TiO2, and CuWO4 by co-precipitation assisted hydrothermal method from precursor salts, underwent gentle mechanical agitation. Homogenization of the nanopowder precursors was performed by zirconia ball milling for 2 h. The final material was obtained after annealing at 500◦C for 3.5 h. Structural and morphological characterization of the synthesized material has been achieved employing X-ray diffraction (XRD), Fourier transform infra-red (FTIR) spectroscopy, Brunauer–Emmett–Teller (BET) N2 adsorption–desorption analysis, Scanning electron microscopy-coupled Energy dispersive X-ray spectroscopy (SEM-EDS), Transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and UV-Vis diffuse reflectance spectroscopy (UV-vis DRS) for optical characterization. The 0250.05 wt.% CuWO4-TiO2 catalyst was investigated for its photocatalytic activity over carbamazepine (CBZ), achieving a degradation of almost 100% after 2 h irradiation. A comparison with pure TiO2 prepared under those same conditions was made. The effect of pH, chemical scavengers, H2O2 as well as contaminant ion effects (anions, cations), and humic acid (HA) was investigated, and their related influences on the photocatalyst efficiency towards CBZ degradation highlighted accordingly
'Dopamine-first' mechanism enables the rational engineering of the norcoclaurine synthase aldehyde activity profile
Norcoclaurine synthase (NCS) (EC 4.2.1.78) catalyzes the Pictet–Spengler condensation of dopamine and an aldehyde, forming a substituted (S)-tetrahydroisoquinoline, a pharmaceutically important moiety. This unique activity has led to NCS being used for both in vitro biocatalysis and in vivo recombinant metabolism. Future engineering of NCS activity to enable the synthesis of diverse tetrahydroisoquinolines is dependent on an understanding of the NCS mechanism and kinetics. We assess two proposed mechanisms for NCS activity: (a) one based on the holo X-ray crystal structure and (b) the ‘dopamine-first’ mechanism based on computational docking. Thalictrum flavum NCS variant activities support the dopamine-first mechanism. Suppression of the non-enzymatic background reaction reveals novel kinetic parameters for NCS, showing it to act with low catalytic efficiency. This kinetic behaviour can account for the ineffectiveness of recombinant NCS in in vivo systems, and also suggests NCS may have an in planta role as a metabolic gatekeeper. The amino acid substitution L76A, situated in the proposed aldehyde binding site, results in the alteration of the enzyme's aldehyde activity profile. This both verifies the dopamine-first mechanism and demonstrates the potential for the rational engineering of NCS activity
Precision atomic gravimeter based on Bragg diffraction
We present a precision gravimeter based on coherent Bragg diffraction of
freely falling cold atoms. Traditionally, atomic gravimeters have used
stimulated Raman transitions to separate clouds in momentum space by driving
transitions between two internal atomic states. Bragg interferometers utilize
only a single internal state, and can therefore be less susceptible to
environmental perturbations. Here we show that atoms extracted from a
magneto-optical trap using an accelerating optical lattice are a suitable
source for a Bragg atom interferometer, allowing efficient beamsplitting and
subsequent separation of momentum states for detection. Despite the inherently
multi-state nature of atom diffraction, we are able to build a Mach-Zehnder
interferometer using Bragg scattering which achieves a sensitivity to the
gravitational acceleration of with an
integration time of 1000s. The device can also be converted to a gravity
gradiometer by a simple modification of the light pulse sequence.Comment: 13 pages, 11 figure
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