Diarylethene Self-Assembled Monolayers: Cocrystallization and Mixing-Induced Cooperativity Highlighted by Scanning Tunneling Microscopy at the Liquid/Solid Interface

International audienceThe control over 2-D multi-component molecular orderings on surfaces is a key technology to realize advanced materials with stimuli-responsive properties. The fractional coverage (θ) at a given concentration can be determined from two parameters: the equilibrium constant (Ke) and the degree of cooperativity (σ). The parameters for the formation of self-assembled monolayer of pure diarylethene isomers were obtained by STM measurements on HOPG. These mono-component parameters were used as references to highlight a cocrystallization process between the open-and closed-ring isomers. Moreover it was observed that the presence of the closed-ring isomer induces cooperativity in the formation of the molecular ordering of the open-ring isomer. The quantitative analysis of the ordering formation process by using a model simulation presented in this work provides a better understanding of mixing of components in a molecular ordering and photoinduced interchanges at the liquid/solid interface. (1) Sakano, T.; Imaizumi, Y.; Hirose, T.; Matsuda, K. Chem. Lett. 2013, 42, 1537. (2) Yokoyama, S.; Hirose, T.; Matsuda, K. Chem. Commun. 2014, 50, 5964. (3) Frath, D.; Sakano, T.; Imaizumi, Y.; Yokoyama, S.; Hirose, T.; Matsuda, K. Chem. Eur. J. 2015, 21, 11350

Turbulent Stresses in Local Simulations of Radiation-Dominated Accretion Disks, and the Possibility of the LIghtman-Eardley Instability

We present the results of a series of radiation-MHD simulations of a local patch of an accretion disk, with fixed vertical gravity profile but with different surface mass densities and a broad range of radiation to gas pressure ratios. Each simulation achieves a thermal equilibrium that lasts for many cooling times. After averaging over times long compared to a cooling time, we find that the vertically integrated stress is approximately proportional to the vertically-averaged total thermal (gas plus radiation) pressure. We map out--for the first time on the basis of explicit physics--the thermal equilibrium relation between stress and surface density: the stress decreases (increases) with increasing surface mass density when the simulation is radiation (gas) pressure dominated. The dependence of stress on surface mass density in the radiation pressure dominated regime suggests the possibility of a Lightman-Eardley inflow instability, but global simulations or shearing box simulations with much wider radial boxes will be necessary to confirm this and determine its nonlinear behavior.Comment: accepted for publication in The Astrophysical Journa

Understanding Simulations of Thin Accretion Disks by Energy Equation

We study the fluctuations of standard thin accretion disks by linear analysis of the time-dependent energy equation together with the vertical hydrostatic equilibrium and the equation of state. We show that some of the simulation results in Hirose et al. (2009b), such as the time delay, the relationship of power spectra, and the correlation between magnetic energy and radiation energy, can be well understood by our analytic results.Comment: 13 pages, 3 figure, accepted for publication in Ap

Unsolved problems in the lowermost mantle

Many characteristics of D '' layer may be attributed to the recently discovered MgSiO3 post-perovskite phase without chemical heterogeneities. They include a sharp discontinuity at the top of D '', regional variation in seismic anisotropy, and a steep Clapeyron slope. However, some features remain unexplained. The seismically inferred velocity jump is too large in comparison to first principles calculations, and the sharpness of the discontinuity may require a chemical boundary. Chemical heterogeneity may play an important role in addition to the phase transformation from perovskite to post-perovskite. Phase transformation and chemical heterogeneity and the attendant changes in physical properties, such as rheology and thermal conductivity, are likely to play competing roles in defining the dynamical stability of the D '' layer. Revealing the relative roles between phase transition and chemical anomalies is an outstanding challenge in the study of the role of D '' in thermal-chemical evolution of the Earth

Suppression of cell-spreading and phagocytic activity on nano-pillared surface: in vitro experiment using hemocytes of the colonial ascidian Botryllus schlosseri.

Nano-scale nipple array on the body surface has been described from various invertebrates including endoparasitic and mesoparasitic copepods, but the functions of the nipple array is not well understood. Using the hydrophilized nanopillar sheets made of polystyrene as a mimetic material of the nipple arrays on the parasites\u2019 body surface, we assayed the cell spreading and phagocytosis of the hemocytes of the colonial ascidian Botryllus schlosseri. On the pillared surface, the number of spreading amebocytes and the number of phagocytizing hemocytes per unit area were always smaller than those on the flat surface (Mann-Whitney test, p < 0.05 - 0.001), probably because the effective area for the cell attachment on the pillared surface is much smaller than the area on the flat sheet. The present results supports the idea that the nipple array on the parasites' body surface reduces the innate immune reaction from the host hemocytes