Controlling nickel nanoparticle size in an organic/metal-organic matrix through the use of different solvents

Nickel nanoparticles have been created in an organic-based matrix by the reaction of Ni(COD)2 (COD = 1,5-bis-cyclooctadiene) and 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (TCNQF4). The size of the nickel nanoparticles can be controlled by the use of different solvents and inclusion of tetrahydrofuran (THF) within the reaction to stabilise the Ni(0) atoms from the Ni(COD)2. Materials are characterised with a combination of X-ray diffraction, electron microscopy and magnetometry and it is found that samples made using a halocarbon solvent resulted in clustered bulk Ni particles (size ≤ 10 nm) with anomalously high superparamagnetic blocking temperatures. Using an isocyanide solvent produces smaller (size [similar] 1 nm), well dispersed particles that show little evidence of superparamagnetic blocking in the range of temperatures investigated (>2 K). In all samples there is another component which dominates the magnetic response at low temperatures and shows an interesting temperature dependent scaling behaviour when plotted as M vs. B/T which we believe is related to the organo-metallic matrix that the particles are trapped within. We propose that the enhanced blocking temperature of particles synthesised using halocarbon solvents can be attributed to inter-particle dipolar interactions and nanoparticle–matrix exchange interactions

Temperature dependence of non-linear electrical conduction behavior in a screen-printed multi-component nanocomposite

Nanocomposite materials are of growing applications importance in many areas, particularly touch sensitive surfaces. Here, current-voltage measurements were performed over a range of temperatures and static compressive loadings on a new variant of a multi-component, screen-printed nanocomposite ink, in order to understand the physical nature of the electrical transport behavior. A physical model, combining a linear percolative electrical conductance and a highly non-linear conductance, that is ascribed to field assisted quantum tunneling, was successful in describing the temperature dependence of the I-V. This provides a theoretical underpinning for conduction in these functional nanocomposites

Using interactive screen experiments as pre-laboratory tasks to enhance student learning

The teaching of first year undergraduate practical physics is currently faced with a difficult problem: the disparity in the level of practical physics many university entrant students have encountered prior to their arrival. Those with little practical physics experience enter the laboratory for the first time with a great deal of anxiety, which represents a barrier to their learning. This anxiety is magnified when their fellow students, some of whom have significant practical laboratory experience in their recent educational background, deal easily with the same situation. At Durham University, Interactive Screen Experiments (ISEs) have been used to familiarise students with laboratory equipment as part of an assessed pre-laboratory task for the first year physics laboratory, after which they perform real experiments

Variability of Cu 2 ZnSnS 4 nanoparticle hot injection synthesis and modifications by thin film annealing

As a quaternary semiconductor with a direct energy bandgap of around 1.4 eV, Cu2ZnSnS4 is a promising candidate for absorber layers in next generation thin-film solar PV devices. It has the advantage of being based on low cost earth-abundant elements. Solution based synthesis approaches show the greatest potential for scaling up manufacture. Cu2ZnSnS4 devices are currently limited in efficiency because of a large open circuit voltage deficit, arising predominantly from high concentrations of point defects and charge compensation defect complexes. To drive device efficiency robust, reliable and reproducible synthesis protocols are required. We have produced a series of Cu2ZnSnS4 thin films by spin coating nanoparticle ink suspensions fabricated under nominally identical conditions to investigate the inherent variability in hot injection synthesis of Cu2ZnSnS4 nanoparticles by fabricating 11 batches using the same initial conditions. We use two different chemical routes to extratct nanoparticles from solution after synthesis. We find that the lattice constants of the nanocrystalline material do not change significantly. The relative concentration of the constituent elements varies with S having the largest anion variation of ±3.8% as compared to metal cation variations of Zn ±2.4%, Cu ±1.8%, and Sn ±1.4% with Zn having the largest cation variation. We compare data from energy dispersive X-ray (EDX) and inductively coupled plasma mass spectroscopy (ICPMS) chemical analysis methods and find that the ICPMS analysis has a consistently smaller standard deviation, an average of 0.1 lower, as this technique samples a large volume of material. We observe variation in the kesterite tetragonal lattice constants a and c, and energy bandgap Eg across the different samples, although there is no systematic change in the chemical composition. The average bandgap of as-synthesised films is 1.14 eV. We find that annealing in a sulphur rich environment has no systematic impact on the Cu/(Zn + Sn) cation ratio and leads to a decrease of −0.4 in the Zn/Sn ratio. At higher annealing temperatures, 500–600 °C, the bandgap shows a linear increase of +0.15 eV accompanied by the formation of abnormal grains and an increase in the size of the crystalline scattering domain τ, determined from the X-ray spectra, from 30–100 nm. The most dramatic changes occur in the first 0.5 hours of annealing. These findings will help in the design of fabrication strategies for higher efficiency Cu2ZnSnS4 photovoltaic devices

Vapor sensing properties of a conductive polymer composite containing Nickel particles with nano-scale surface features

This paper presents an unusual conductive polymer composite, produced by Peratech Ltd under the trademark QTC™, which has many vapor sensing applications. Nickel particles are intimately coated by an elastomeric binder such that no percolative conduction can occur. However, the nickel particles are shown to possess spiky nanoscale surface features, which promote conduction by a field-assisted quantum tunneling mechanism. Granular QTC™ can be dispersed into a polymer matrix to produce a vapor sensor. Under exposure to vapor, the polymer swells and the resistance of the composite increases. In this work, granular sensors are subjected to acetone and tetrahydrofuran (THF) vapors. The response for THF shows an increase in resistance of a factor of 108, over a time-scale of a few seconds. This response is larger and faster than many conventional vapor sensing composites. This is a significantly larger response than that obtained historically for the same sensor, suggesting that some degree of sensor aging is desirable. The response and subsequent recovery can be explained by a case II diffusion model, and linked to Hildebrand solubility parameters of the vapor and polymer components

A novel screen-printed multi-component nanocomposite ink with a pressure sensitive electrical resistance functionality

Here, a novel functional ink is described that is composed of multiple nanoscale components and exhibits pronounced touch pressure sensitive electrical properties ideal for applications in switching, sensing and touch sensitive surfaces. The ink can be screen-printed and the as-printed ink displays a large and reproducible touch pressure sensitive electrical resistance and, in contrast to some other composite materials, the resistance changes occur down to the smallest applied pressures. Detailed scanning electron microscopy shows the complex nanoscale structure of the composite that is critical for the electrical behavior. Current-voltage measurements, under static compressive loading, show monotonic non-linear behavior at low compression and ohmic behavior at higher loadings

Effect of age of Japanese quail on physical and biochemical characteristics of eggs

The aim of the study was to investigate the effects of age of birds on egg quality in Japanese quail. The eggs were randomly selected from among all eggs laid on the same day when the birds were 15, 23 and 31 weeks old. At each time point, 90 fresh eggs were evaluated for their physical and biochemical characteristics. Egg weights were similar over time. At 23 and 31 weeks, the eggs had less shell than at 15 weeks. Crude fat and ash contents of the eggs increased with the age of the birds. Crude protein was also highest in eggs of the oldest quail. At 31 weeks old, the eggs were lowest in pH of yolk and white. Quail that were 23 and 31 weeks old laid eggs with significantly higher polyunsaturated fatty acid (PUFA) and lower saturated fatty acid (SFA) contents. The lowest cholesterol content was in egg yolks from 23-week-old quail. The oldest birds had the highest contents of sodium, potassium, zinc, selenium, copper, and manganese. The content and activity of lysozyme decreased with ageing of the birds. From the consumers’ point of view, eggs from older birds appeared to be the most valuable. At the same time, as the quail ages, the antibacterial properties of eggs deteriorate, which may indicate a shorter shelf life

Evidence of a double-double morphology in B0818+214

The so-called double-double structure in radio sources is the most conspicuous signature of their restarted activity. Observations indicate that in the majority of double-double radio sources (DDRS), the span of the radio lobes is larger than 0.7 Mpc. This lower limit is also suggested by theory. However, it seemed likely that the apparent core of B0818+214, a radio galaxy with an overall linear size of its radio structure below that limit, could harbour a compact double well aligned with the outer lobes so that the whole object would fulfil the criteria of a DDRS. Here, we present evidence that the central component of B0818+214, when magnified through the EVN+MERLIN 18-cm observations, shows two FR II-like lobes. As the separation of the inner lobes is not greater than 5.7 kpc, they are immersed in the ISM of the host galaxy. This circumstance is the likely reason why the inner double has become visible, despite the predictions of the theory according to which B0818+214 as a whole is too small for a new double to develop inside the cocoon inflated during the previous active phase. Moreover, we speculate that its host galaxy is not active at the moment and so the inner double may be in the coasting phase often observed in other medium-sized symmetric objects with intermittent activity. It could be, therefore, that two different mechanisms of accretion disk instabilities, ionisation and radiation-pressure driven, may be independently responsible for triggering active phases, manifesting as the outer and the inner doubles, respectively.Comment: 4 pages, A&A in pres