10,906 research outputs found
Excitations in time-dependent density-functional theory
An approximate solution to the time-dependent density functional theory
(TDDFT) response equations for finite systems is developed, yielding
corrections to the single-pole approximation. These explain why allowed
Kohn-Sham transition frequencies and oscillator strengths are usually good
approximations to the true values, and why sometimes they are not. The
approximation yields simple expressions for G\"orling-Levy perturbation theory
results, and a method for estimating expectation values of the unknown
exchange-correlation kernel.Comment: 4 pages, 1 tabl
Crop Identification Technology Assessment for Remote Sensing (CITARS)
The results of classifications and experiments performed for the Crop Identification Technology Assessment for Remote Sensing (CITARS) project are summarized. Fifteen data sets were classified using two analysis procedures. One procedure used class weights while the other assumed equal probabilities of occurrence for all classes. In addition, 20 data sets were classified using training statistics from another segment or date. The results of both the local and non-local classifications in terms of classification and proportion estimation are presented. Several additional experiments are described which were performed to provide additional understanding of the CITARS results. These experiments investigated alternative analysis procedures, training set selection and size, effects of multitemporal registration, the spectral discriminability of corn, soybeans, and other, and analysis of aircraft multispectral data
Crop identification technology assessment for remote sensing (CITARS). Volume 6: Data processing at the laboratory for applications of remote sensing
The results of classifications and experiments for the crop identification technology assessment for remote sensing are summarized. Using two analysis procedures, 15 data sets were classified. One procedure used class weights while the other assumed equal probabilities of occurrence for all classes. Additionally, 20 data sets were classified using training statistics from another segment or date. The classification and proportion estimation results of the local and nonlocal classifications are reported. Data also describe several other experiments to provide additional understanding of the results of the crop identification technology assessment for remote sensing. These experiments investigated alternative analysis procedures, training set selection and size, effects of multitemporal registration, spectral discriminability of corn, soybeans, and other, and analyses of aircraft multispectral data
Novel technique for the CO<sub>2</sub> laser fabrication of optical devices with sub-micrometer ablation depth precision
We present novel techniques for the processing of fibre end face and cladding surfaces using a 9.6 µm CO2 laser. We investigate the effects of pulse duration on process parameters
Biometric analysis of brushtooth lizard fish Saurida undosquamis (Richardson, 1848) from Mumbai waters
The aim of the present study was to investigate the relationship between various morphometric measurements and meristic counts, and to establish the length-weight relationships (LWRs) and length-length relationships (LLRs) of Saurida undosquamis based on specimens collected from New Ferry Wharf landing centre of Mumbai coast during September 2013 to June 2015. The morphometric variables for the species under study exhibited high level of correlation with each other. Based on present study results, the fin formula of S. undosquamis in Mumbai water can be written as B 13-15, D 11-13, P 13-15, V 9, A 10-11, C 18-20, L47-53. Different values of regression coefficient (b) and correlation coefficient (r) in LLRs illustrates that different organ grows differently. The values of the regression coefficient b in the LWRs equations (W = aLb) were 2.90, 3.04 and 2.99 for male, female and pooled individuals respectively indicating an isometric growth with high correlation coefficient (r2). These parameters are useful for evaluating the relative condition of fish as well as for subsequent biological and population based studies
Coupled Fluctuations near Critical Wetting
Recent work on the complete wetting transition has emphasized the role played
by the coupling of fluctuations of the order parameter at the wall and at the
depinning fluid interface. Extending this approach to the wetting transition
itself we predict a novel crossover effect associated with the decoupling of
fluctuations as the temperature is lowered towards the transition temperature
T_W. Using this we are able to reanalyse recent Monte-Carlo simulation studies
and extract a value \omega(T_W)=0.8 at T_W=0.9T_C in very good agreement with
long standing theoretical predictions.Comment: 4 pages, LaTex, 1 postscript figur
Drug Loaded Biodegradable Load-Bearing Nanocomposites for Damaged Bone Repair
In this paper we present a short review-scientific report on processing and properties, including in vitro degradation, of load bearing biodegradable nanocomposites as well as of macroporous 3D scaffolds for bone ingrowth. Biodegradable implantable devices should slowly degrade over time and disappear with ingrown of natural bone replacing the synthetic graft. Compared to low strength biodegradable polymers, and brittle CaP ceramics, biodegradable CaP-polymer and CaP-metal nanocomposites, mimicking structure of natural bone, as well as strong and ductile metal nanocomposites can provide to implantable devices both strengths and toughness. Nanostructuring of biodegradable [beta]- TCP (tricalcium phosphate)-polymer (PCL and PLA), [beta]-TCP-metal (FeMg and FeAg) and of Fe-Ag composites was achieved employing high energy attrition milling of powder blends. Nanocomposite powders were consolidated to densities close to theoretical by high pressure consolidation at ambient temperature-cold sintering, with retention of nanoscale structure. The strength of developed nanocomposites was significantly higher as compared with microscale composites of the same or similar composition. Heat treatment at moderate temperatures in hydrogen flow resulted in retention of nanoscale structure and higher ductility. Degradation of developed biodegradable [beta]-TCP-polymer, [beta]-TCPmetal and of Fe-Ag nanocomposites was studied in physiological solutions. Immersion tests in Ringer's and saline solution for 4 weeks resulted in 4 to 10% weight loss and less than 50% decrease in compression or bending strength, the remaining strength being significantly higher than the values reported for other biodegradable materials. Nanostructuring of Fe-Ag based materials resulted also in an increase of degradation rate because of creation on galvanic Fe-Ag nanocouples. In cell culture experiments, the developed nanocomposites supported the attachment the human osteoblast cells and exhibited no signs of cytotoxicity. Interconnected system of nanopores formed during processing of nanocomposites was used for incorporation of drugs, including antibiotics and anticancer drugs, and can be used for loading of bioactive molecules enhancing bone ingrowth
Surface induced disorder in body-centered cubic alloys
We present Monte Carlo simulations of surface induced disordering in a model
of a binary alloy on a bcc lattice which undergoes a first order bulk
transition from the ordered DO3 phase to the disordered A2 phase. The data are
analyzed in terms of an effective interface Hamiltonian for a system with
several order parameters in the framework of the linear renormalization
approach due to Brezin, Halperin and Leibler. We show that the model provides a
good description of the system in the vicinity of the interface. In particular,
we recover the logarithmic divergence of the thickness of the disordered layer
as the bulk transition is approached, we calculate the critical behavior of the
maxima of the layer susceptibilities, and demonstrate that it is in reasonable
agreement with the simulation data. Directly at the (110) surface, the theory
predicts that all order parameters vanish continuously at the surface with a
nonuniversal, but common critical exponent. However, we find different
exponents for the order parameter of the DO3 phase and the order parameter of
the B2 phase. Using the effective interface model, we derive the finite size
scaling function for the surface order parameter and show that the theory
accounts well for the finite size behavior of the DO3 ordering but not for that
of B2 ordering. The situation is even more complicated in the neighborhood of
the (100) surface, due to the presence of an ordering field which couples to
the B2 order.Comment: To appear in Physical Review
Quantum Mechanical Aspects of Cell Microtubules: Science Fiction or Realistic Possibility?
Recent experimental research with marine algae points towards quantum
entanglement at ambient temperature, with correlations between essential
biological units separated by distances as long as 20 Angstr\"oms. The
associated decoherence times, due to environmental influences, are found to be
of order 400 fs. This prompted some authors to connect such findings with the
possibility of some kind of quantum computation taking place in these
biological entities: within the decoherence time scales, the cell "quantum
calculates" the optimal "path" along which energy and signal would be
transported more efficiently. Prompted by these experimental results, in this
talk I remind the audience of a related topic proposed several years ago in
connection with the possible r\^ole of quantum mechanics and/or field theory on
dissipation-free energy transfer in microtubules (MT), which constitute
fundamental cell substructures. Quantum entanglement between tubulin dimers was
argued to be possible, provided there exists sufficient isolation from other
environmental cell effects. The model was based on certain ferroelectric
aspects of MT. In the talk I review the model and the associated experimental
tests so far and discuss future directions, especially in view of the algae
photo-experiments.Comment: 31 pages latex, 11 pdf figures, uses special macros, Invited Plenary
Talk at DICE2010, Castello Pasquini, Castiglioncello (Italy), September 13-18
201
Charge transfer and coherence dynamics of tunnelling system coupled to a harmonic oscillator
We study the transition probability and coherence of a two-site system,
interacting with an oscillator. Both properties depend on the initial
preparation. The oscillator is prepared in a thermal state and, even though it
cannot be considered as an extended bath, it produces decoherence because of
the large number of states involved in the dynamics. In the case in which the
oscillator is intially displaced a coherent dynamics of change entangled with
oscillator modes takes place. Coherency is however degraded as far as the
oscillator mass increases producing a increasingly large recoherence time.
Calculations are carried on by exact diagonalization and compared with two
semiclassical approximations. The role of the quantum effects are highlighted
in the long-time dynamics, where semiclassical approaches give rise to a
dissipative behaviour. Moreover, we find that the oscillator dynamics has to be
taken into account, even in a semiclassical approximation, in order to
reproduce a thermally activated enhancement of the transition probability
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