Adding Salt to an Aqueous Solution of t-Butanol: Is Hydrophobic Association Enhanced or Reduced?

Recent neutron scattering experiments on aqueous salt solutions of amphiphilic t-butanol by Bowron and Finney [Phys. Rev. Lett. {\bf 89}, 215508 (2002); J. Chem. Phys. {\bf 118}, 8357 (2003)] suggest the formation of t-butanol pairs, bridged by a chloride ion via ${O}-{H}...{Cl}^-$ hydrogen-bonds, and leading to a reduced number of intermolecular hydrophobic butanol-butanol contacts. Here we present a joint experimental/theoretical study on the same system, using a combination of molecular dynamics simulations and nuclear magnetic relaxation measurements. Both theory and experiment clearly support the more intuitive scenario of an enhanced number of hydrophobic contacts in the presence of the salt, as it would be expected for purely hydrophobic solutes [J. Phys. Chem. B {\bf 107}, 612 (2003)]. Although our conclusions arrive at a structurally completely distinct scenario, the molecular dynamics simulation results are within the experimental errorbars of the Bowron and Finney work.Comment: 15 pages twocolumn revtex, 11 figure

Spatial characterization of the magnetic field profile of a probe tip used in magnetic resonance force microscopy

We have developed the experimental approach to characterize spatial distribution of the magnetic field produced by cantilever tips used in magnetic resonance force microscopy (MRFM). We performed MRFM measurements on a well characterized diphenyl-picrylhydrazyl (DPPH) film and mapped the 3D field profile produced by a Nd2Fe14B probe tip. Using our technique field profiles of arbitrarily shaped probe magnets can be imaged.Comment: 10 pages, 5 figure

Enhanced dynamic nuclear polarization via swept microwave frequency combs

Dynamic Nuclear Polarization (DNP) has enabled enormous gains in magnetic resonance signals and led to vastly accelerated NMR/MRI imaging and spectroscopy. Unlike conventional cw-techniques, DNP methods that exploit the full electron spectrum are appealing since they allow direct participation of all electrons in the hyperpolarization process. Such methods typically entail sweeps of microwave radiation over the broad electron linewidth to excite DNP, but are often inefficient because the sweeps, constrained by adiabaticity requirements, are slow. In this paper we develop a technique to overcome the DNP bottlenecks set by the slow sweeps, employing a swept microwave frequency comb that increases the effective number of polarization transfer events while respecting adiabaticity constraints. This allows a multiplicative gain in DNP enhancement, scaling with the number of comb frequencies and limited only by the hyperfine-mediated electron linewidth. We demonstrate the technique for the optical hyperpolarization of 13C nuclei in powdered microdiamonds at low fields, increasing the DNP enhancement from 30 to 100 measured with respect to the thermal signal at 7T. For low concentrations of broad linewidth electron radicals, e.g. TEMPO, these multiplicative gains could exceed an order of magnitude.Comment: Contains supplementary inf

Charge degree of freedom and single-spin fluid model in YBa_2Cu_4O_8

We present a 17O nuclear magnetic resonance study in the stoichiometric superconductor YBa_2Cu_4O_8. A double irradiation method enables us to show that, below around 180 K, the spin-lattice relaxation rate of plane oxygen is not only driven by magnetic, but also significantly by quadrupolar fluctuations, i.e. low-frequency charge fluctuations. In the superconducting state, on lowering the temperature, the quadrupolar relaxation diminishes faster than the magnetic one. These findings show that, with the opening of the pseudo spin gap, a charge degree of freedom of mainly oxygen character is present in the electronic low-energy excitation spectrum.Comment: 4 pages, 3 figures, REVTE

Intense beam of metastable Muonium

Precision spectroscopy of the Muonium Lamb shift and fine structure requires a robust source of 2S Muonium. To date, the beam-foil technique is the only demonstrated method for creating such a beam in vacuum. Previous experiments using this technique were statistics limited, and new measurements would benefit tremendously from the efficient 2S production at a low energy muon ($<20$ keV) facility. Such a source of abundant low energy $\mathrm{\mu^+}$ has only become available in recent years, e.g. at the Low-Energy Muon beamline at the Paul Scherrer Institute. Using this source, we report on the successful creation of an intense, directed beam of metastable Muonium. We find that even though the theoretical Muonium fraction is maximal in the low energy range of $2-5$ keV, scattering by the foil and transport characteristics of the beamline favor slightly higher $\mathrm{\mu^+}$ energies of $7-10$ keV. We estimate that an event detection rate of a few events per second for a future Lamb shift measurement is feasible, enabling an increase in precision by two orders of magnitude over previous determinations

Direct observation of non-local effects in a superconductor

We have used the technique of low energy muon spin rotation to measure the local magnetic field profile B(z) beneath the surface of a lead film maintained in the Meissner state (z depth from the surface, z <= 200 nm). The data unambiguously show that B(z) clearly deviates from an exponential law and represent the first direct, model independent proof for a non-local response in a superconductor.Comment: 5 pages, 3 figure

Quantum Critical Behavior in Disordered Itinerant Ferromagnets: Instability of the Ferromagnetic Phase

An effective field theory is derived that describes the quantum critical behavior of itinerant ferromagnets as the transition is approached from the ferromagnetic phase. This complements a recent study of the critical behavior on the paramagnetic side of the phase transition, and investigates the role of the ferromagnetic Goldstone modes near criticality. We find that the Goldstone modes have no direct impact on the critical behavior, and that the critical exponents are the same as determined by combining results from the paramagnetic phase with scaling arguments.Comment: 11 pp., revtex4, no fig

Observation of non-exponential magnetic penetration profiles in the Meissner state - A manifestation of non-local effects in superconductors

Implanting fully polarized low energy muons on the nanometer scale beneath the surface of a superconductor in the Meissner state enabled us to probe the evanescent magnetic field profile B(z)(0<z<=200nm measured from the surface). All the investigated samples [Nb: kappa \simeq 0.7(2), Pb: kappa \simeq 0.6(1), Ta: kappa \simeq 0.5(2)] show clear deviations from the simple exponential B(z) expected in the London limit, thus revealing the non-local response of these superconductors. From a quantitative analysis within the Pippard and BCS models the London penetration depth lambda_L is extracted. In the case of Pb also the clean limit coherence length xi0 is obtained. Furthermore we find that the temperature dependence of the magnetic penetration depth follows closely the two-fluid expectation 1/lambda^2 \propto 1-(T/T_c)^4. While B(z) for Nb and Pb are rather well described within the Pippard and BCS models, for Ta this is only true to a lesser degree. We attribute this discrepancy to the fact that the superfluid density is decreased by approaching the surface on a length scale xi0. This effect, which is not taken self-consistently into account in the mentioned models, should be more pronounced in the lowest kappa regime consistently with our findings.Comment: accepted in PRB 14 pages, 17 figure

A suggested search for 207Pb nuclear Schiff moment in PbTiO3 ferroelectric

We suggest two types of experiments, NMR and macroscopic magnetometry, with solid PbTiO3 to search for the nuclear Schiff moment of 207Pb. Both kinds of experiments promise substantial improvement over the presently achieved sensitivities. Statistical considerations show that the improvement of the current sensitivity can be up to 10 orders of magnitude for the magnetometry experiment and up to 6 orders of magnitude for the NMR experiment. Such significant enhancement is due to the strong internal electric field of the ferroelectric, as well as due to the possibility to cool the nuclear-spin subsystem in the compound down to nanokelvin temperatures.Comment: 4 pages; revised sensitivity estimate for NMR experimen