Action research on electrochemistry learning. Conceptual modelling intervention to promote disciplinary understanding, scientific inquiry, and reasoning

Students in engineering-science programmes often struggle with theoretical concepts, while they tend to adopt a surface approach to learning. We suggest that this can be tackled by promoting a specific higher-order thinking skill (HOTS) that enables drawing connections between physical phenomena and theoretical concepts representing them. We designed an intervention to support students in achieving deep insight into electrochemical phenomena, while developing this HOTS. Such intervention aims to scaffold students’ learning and development by introducing conceptual modelling as an essential thinking skill of engineering-scientists, and as a strategy to build scientific understanding of natural phenomena. Therefore, conceptual modelling constitutes a main learning objective of this novel course. This paper reports an empirical investigation into how students deal with concepts and complexity, and to what extent the intervention has any measurable effects on the learning outcomes. This phenomenological investigation integrates considerations from various disciplines, and relies on multiple data sources, i.e., students’ documents (lab journals and reports), observations of students in action (in discussions with their tutors and while performing lab experiments), and video stimulated-recall interviews. The results show little effect of the intervention, as implemented, suggesting how challenging it is for students (and instructors) to shift from traditional learning-and-teaching approaches, towards an epistemology of knowledge construction for specific problems. The findings are informative for revision of the intervention and generate specific recommendations. Concurrently, our operationalisation of the conceptual framework proves powerful in detecting qualitative differences in HOTS. Plausible implications for research and educational practice in science-engineering education are discussed

Building micro-soccer-balls with evaporating colloidal fakir drops

Evaporation-driven particle self-assembly can be used to generate three-dimensional microstructures. We present a new method to create these colloidal microstructures, in which we can control the amount of particles and their packing fraction. To this end, we evaporate colloidal dispersion droplets on a special type of superhydrophobic micro-structured surface, on which the droplet re- mains in Cassie-Baxter state during the entire evaporative process. The remainders of the droplet consist of a massive spherical cluster of the microspheres, with diameters ranging from a few tens up to several hundreds of microns. We present scaling arguments to show how the final particle packing fraction of these balls depends on the dynamics of the droplet evaporation.Comment: Manuscript Submitted to Physical Review Letters, 29th February 201

In Situ Plasmonic Nanospectroscopy of the CO Oxidation Reaction over Single Pt Nanoparticles

The ongoing quest to develop single-particle methods for the in situ study of heterogeneous catalysts is driven by the fact that heterogeneity in terms of size, shape, grain structure, and composition is a general feature among nanoparticles in an ensemble. This heterogeneity hampers the generation of a deeper understanding for how these parameters affect catalytic properties. Here we present a solution that in a single benchtop experimental setup combines single-particle plasmonic nanospectroscopy with mass spectrometry for gas phase catalysis under reaction conditions at high temperature. We measure changes in the surface state of polycrystalline platinum model catalyst particles in the 70 nm size range and the corresponding bistable kinetics during the carbon monoxide oxidation reaction via the peak shift of the dark-field scattering spectrum of a closely adjacent plasmonic nanoantenna sensor and compare these changes with the total reaction rate measured by the mass spectrometer from an ensemble of nominally identical particles. We find that the reaction kinetics of simultaneously measured individual Pt model catalysts are dictated by the grain structure and that the superposition of the individual nanoparticle response can account for the significant broadening observed in the corresponding nanoparticle ensemble data. In a wider perspective our work enables in situ plasmonic nanospectroscopy in controlled gas environments at high temperature to investigate the role of the surface state on transition metal catalysts during reaction and of processes such as alloying or surface segregation in situ at the single-nanoparticle level for model catalysts in the few tens to hundreds of nanometer size range

Color Tuning of Electrochromic TiO₂ Nanofibrous Layers Loaded with Metal and Metal Oxide Nanoparticles for Smart Colored Windows

Co-axial electrospinning was applied for the structuring of non-woven webs of TiO2 nanofibers loaded with Ag, Au, and CuO nanoparticles. The composite layers were tested in an electrochromic half-cell assembly. A clear correlation between the nanoparticle composition and electrochromic effect in the nanofibrous composite is observed: TiO2 loaded with Ag reveals a black-brown color, Au shows a dark-blue color, and CuO shows a dark-green color. For electrochromic applications, the Au/TiO2 layer is the most promising choice, with a color modulation time of 6 s, transmittance modulation of 40%, coloration efficiency of 20 cm2/C, areal capacitance of 300 F/cm2, and cyclic stability of over 1000 cycles in an 18 h period. In this study, an unexplored path for the rational design of TiO2-based electrochromic device is offered with unique color-switching and optical efficiency gained by the fibrous layer. It is also foreseen that co-axial electrospinning can be an alternative nanofabrication technique for smart colored windows. </p