13 research outputs found

    Review of Feminists and Sciences: Critiques and Changing Perspectives in India Volume 1 & 2 (Sage Publications, 2015-2017)

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    Book Review of Feminists and Sciences: Critiques and Changing Perspectives in India Volume 1 & 2, edited by Sumi Krishna and Gita Chadh

    Anna Mani

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    REASSIGNMENT OF Br2Br_{2} ULTRAVIOLET LASER TRANSITION

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    Author Institution: Department of Chemistry, Vanderbilt UniversityThe Br2Br_{2} laser transition near 2900 {\AA} has been re-examined using a single isotope of bromine. The vibrational analysis contradicts previous assignments, according to which the lower state was designated B(O+u3π)B (O^{+}u 3\pi). The new analysis indicates this transition is very likely 1432, 2g3Π→2431,2u3Π2g^{3}\Pi \rightarrow 2431, 2u^{3} \Pi, the same as the preferred designation for the I2I_{2} 3400 {\AA} laser transition. The prominent bands in the laser spectrum (2913-2926 {\AA}) are 0-10, 2-13, 1-12, 0-11, and 2-14

    ANALYSIS OF THE UV LASER TRANSITION IN Br2Br_{2}

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    Author Institution: Department of ChemistryThe previously reported vibrational analysis of the d′→A′d^{\prime} \rightarrow A^{\prime} transition (2900 {\AA}) in Br2Br_{2} is extended to include additional bands obtained by photographing the emission from isotopically separated 79Br2^{79}Br_{2} and 81Br2^{81} Br_{2}. From measurements of the partially resolved rotational structure in several prominent bands, employed together with Franck-Condon and centrifugal distortion calculations, we obtain a rotational analysis. The results indicate that Re′′=2.69R_{e}^{\prime\prime} = 2.69 \AA, which is comparable to the known values for the B(0^{+} u \; ^{3}\Pi) and A(1u3Π)A(1u^{3}\Pi) states. The analysis supports the 2g3Π→2u3Π2g ^{3}\Pi \rightarrow 2u ^{3}\Pi designation for this transition

    THE B→XB \to X AND D→D\to X SYSTEMS OF XeCl

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    Author Institution: Department of ChemistryThe B→XB \rightarrow X (3050 {\AA}) and D→D \rightarrow X(2350 {\AA}) band systems of XeCl are photographed using sources containing both natural Cl2Cl_{2} and isotopically pure 35C12^{35}C1_{2}. The spectra permit us to refine the existing vibrational analysis of the B→XB \rightarrow X laser transition and obtain a complementary analysis of the D→XD \rightarrow X transition. The results show that the D state has smaller ReR_{e} larger ωe\omega_{e}, and larger DeD_{e} than does the B state, as is found also in XeF. Higher v′′v^{\prime\prime} levels are observed in the D→XD\rightarrow X spectrum, permitting us to obtain a more precise estimate of De′′D_{e}^{\prime\prime} than was obtained previously from the B→XB\rightarrow X system alone

    TWO- AND THREE-PHOTON ABSORPTION STUDIES OF THE O2O_{2} MOLECULE

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    Author Institution: Department of Chemistry, Yale UniversityResonance enhanced multiphoton ionization studies in the 275-330 nm region reveal a large number of 2- and 3-photon transitions to previously unknown states. We have analyzed, in detail, four vibrational components of a rotationally resolved electronic transition at 8.2 eV. The vibrational frequency of 1870cm−11870 cm^{-1} and a rotational constant of 1.68cm−11.68 cm^{-1} suggest that the upper state is the lowest Rydberg state (3sσ\sigma) of O2O_{2}. The rotational structure is consistent with an electronic designation of 3Π0g−^{3}\Pi_{0_{g}^{-}} for this state

    SPECTROSCOPY WITH A TESLA COIL

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    1^{1}A.K. Hui, M. R. McKeever, and J. Tellinghuisen, J. Quant. Spectrosc. Radiat. Transfer (in press).Author Institution:For several years we have been using a Telsa discharge to produce emission from molecular and excimer systems of interest in laser development. This source has proved very useful because of its low cost, low discharge temperature. The light emitted from a Telsa discharge consists of roughly 10310^{3} pulses/s, each having a width of from 0.5 to 5 μ\mus, depending on the design of the coil. Total photon production for the rare gas halides is typified by the value of 2×10122 \times 10^{12} quanta/pulse (average radiant power 1 mW) measured for the B→XB \rightarrow X system of XeCL. Rotational intensity measurements1measurements^{1} on the 0-0 band of the O-H A→XA \rightarrow X system yield discharge temperatures only 10-30 K above the measured wall temperatures for T = 300-800 K and P = 100-700 torr
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