Fabrication of 0.95BaTiO3-0.05Pb(Mg1/3Nb2/3)O3 ceramics by conventional solid state reaction method

The possibility to obtain of ceramic solid solution between barium titanate and lead magnesium niobate by two-step sintering technique through conventional solid-state reaction method has been investigated. In the first step MgNb 2O6 has been synthesized. In the second step 0.95BaTiO3-0.05Pb(Mg1/3Nb2/3)O3 has been obtained using MgNb2O6, PbO and BaTiO 3. The two-step sintering technique is effective for the synthesized of 0.95BaTiO3-0.05Pb(Mg1/3Nb2/3)O3 ceramics. Single-phase (pyrochlore-free) ceramics with perovskite phase were obtained

Peculiar properties of phase transitions in Na0.5Bi0.5TiO3-xBaTiO3 (0<x<6) lead-free relaxor ferroelectrics seen via acoustic emission

Na0.5Bi0.5TiO3-xBaTiO3 (0<x<6) relaxor ferroelectrics crystals were investigated by means of dielectric and acoustic emission methods. Dielectric curves exhibit the slightly visible small maxima near the depolarization temperatures, Td, and the wide maxima at the temperatures of Tm, whereas the acoustic emission exhibits the sharp bursts, corresponding to Td, Tlm, which is known to be a temperature exhibiting a strong frequency dispersion, TRE, which is known to be a temperature above which a frequency dispersion vanishes, and the Tm and the Tp manifesting a transition to the paraelectric phase. Based on the AE data it was established that all these characteristic temperatures shift down as x increases, but with different slopes. A mechanism of such the differences is discussed

Effect of Sb and MnO2-Doping on Phase Transitions, Crystal Structure, Thermal, Dielectric, Ferroelectric and Piezoelectric Properties of Na0.5K0.5NbO3 Ceramics

Lead-free ceramics of Na0.5K0.5Nb1-xSbxO3 (NKNS) and Na0.5K0.5Nb1-xSbxO3 + 0.5 mol%MnO2 (NKNS + 0.5 mol%MnO2) (0 < x < 0.06) ceramics were prepared by a conventional solid-state hot pressing method. The ceramics possess a single-phase perovskite structure with orthorhombic symmetry. Microstructural examination revealed that Mn doping of NKNS leads to improvement of densification. The cubic-tetragonal and tetragonal-orthorhombic phase transitions of NKNS shifted to higher and lower temperature, respectively after introduction of Mn ion. Besides, ferroelectric and piezoelectric properties were improved. The results were discussed in term of difference in both ionic size and electronegativity of Nb5+ and Sb5+ and improvement of densification after Mn ion doping

Evaluation of the impact of adjusting the angle of the axis of a wind turbine rotor relative to the flow of air stream on operating parameters of a wind turbine model

The aim of this study was to determine the effect of regulation of an axis of a wind turbine rotor to the direction of wind on the volume of energy produced by wind turbines. A role of an optimal setting of the blades of the wind turbine rotor was specified, as well. According to the measurements, changes in the tilt angle of the axis of the wind turbine rotor in relation to the air stream flow direction cause changes in the use of wind energy. The publication explores the effects of the operating conditions of wind turbines on the possibility of using wind energy. A range of factors affect the operation of the wind turbine, and thus the volume of energy produced by the plant. The impact of design parameters of wind power plant, climatic factors or associated with the location seismic challenges can be shown from among them. One of the parameters has proved to be change settings of the rotor axis in relation to direction of flow of the air stream. Studies have shown that the accurate determination of the optimum angle of the axis of the rotor with respect to flow of air stream strongly influences the characteristics of the wind turbine

Influence of uniaxial pressure on dielectric properties of (1-x)Na0.5Bi0.5TiO3–xSrTiO3 for x = 0.01, 0.04, and 0.1 ceramics

The publication costs of this article were covered by the Estonian Academy of Sciences and the University of Tartu.The conventional solid-state sintering was applied to synthesized (1-x)Na0.5Bi0.5TiO3-xSrTiO3 (x = 0.01, 0.04, and 0.1) ceramics. Dielectric measurements of these ceramics were taken in the temperature range from 20 to 600 °C, in the frequency range from 1 kHz to 2 MHz and under uniaxial pressure ranging from 10 to 1100 bar. The study of the dielectric behaviour showed that the influence of uniaxial pressure on the investigated properties was considerable. The peaks εm gradually decreased and shifted towards lower temperatures with an increase of uniaxial pressure for all samples. The first effect developed with an increase of the strontium ion concentration. Experimental results revealed most interesting properties of the material in the context of its potential applications.Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART

Advances in Lead-Free Piezoelectric Materials for Sensors and Actuators

Piezoelectrics have widespread use in today’s sensor and actuator technologies. However, most commercially available piezoelectric materials, e.g., Pb [ZrxTi1−x] O3 (PZT), are comprised of more than 60 weight percent lead (Pb). Due to its harmful effects, there is a strong impetus to identify new lead-free replacement materials with comparable properties to those of PZT. This review highlights recent developments in several lead-free piezoelectric materials including BaTiO3, Na0.5Bi0.5TiO3, K0.5Bi0.5TiO3, Na0.5K0.5NbO3, and their solid solutions. The factors that contribute to strong piezoelectric behavior are described and a summary of the properties for the various systems is provided

Temperature and E-Poling Evolution of Structural, Vibrational, Dielectric, and Ferroelectric Properties of Ba1−xSrxTiO3 Ceramics (x = 0, 0.1, 0.2, 0.3, 0.4 and 0.45)

Poland’s high-performance computing infrastructure PLGrid (HPC Centers: ACK Cyfronet AGH) for providing computer facilities and support within computational grant no. PLG/2022/015969. Innovative research and scientific platform for a new class of nanocomposites, financed by the Ministry of Education and Science, contract number 7216/IA/SP/2021.Lead-free Ba1−xSrxTiO3 (BST) (x = 0, 0.1, 0.2, 0.3, 0.4 and 0.45) ceramics were successfully prepared via the solid-state reaction route. A pure perovskite crystalline structure was identified for all compositions by X-ray diffraction analysis. The basic phase transition temperatures in these ceramics were studied over a wide temperature range. A change in symmetry from a tetragonal to cubic phase was detected, which was further proven by phonon anomalies in composition/temperature-dependent Raman spectra. The incorporation of Sr2+ into BaTiO3 (BT) lead to a shift in the phase transitions to lower temperatures, suppressing the ferroelectric properties and inducing relaxor-like behavior. Therefore, it was reasonable to suppose that the materials progressively lack long-range ordering. The initial second-harmonic generation (SHG) measurements demonstrated that the cubic phase of BST ceramics is not purely centrosymmetric over a wide temperature interval. We discussed the possible origin of the observed effects, and showed that electric field poling seems to reconstruct the structural ordering destroyed by the introduction of Sr2+ to BT. In the first approximation, substitution of Sr for larger Ba simply reduced the space for the off-central shift in Ti in the lattice and hence the domain polarization. A-site cation ordering in BST and its influence on the density of electronic states were also explored. The effect of doping with strontium ions in the BST compound on the density of electronic states was investigated using ab initio methods. As the calculations showed, doping BT with Sr2+ atoms led to an increase in the bandgap. The proposed calculations will also be used in the subsequent search for materials optimal for applications in photovoltaics. --//-- This is an open access article Suchanicz, J.; Sitko, D.; Stanuch, K.; Świerczek, K.; Jagło, G.; Kruk, A.; Kluczewska-Chmielarz, K.; Konieczny, K.; Czaja, P.; Aleksandrowicz, J.; et al. Temperature and E-Poling Evolution of Structural, Vibrational, Dielectric, and Ferroelectric Properties of Ba1−xSrxTiO3 Ceramics (x = 0, 0.1, 0.2, 0.3, 0.4 and 0.45). Materials 2023, 16, 6316. https://doi.org/10.3390/ma16186316 published under the CC BY 4.0 licence.the Ministry of Education and Science, contract number 7216/IA/SP/2021; The Institute of Solid State Physics, University of Latvia at the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2