Spatial mapping of ordered and disordered domains of GaInP by near-field scanning optical microscopy and scanning capacitance microscopy

Journal ArticleImaging of topography, locally induced photoluminescence and Fermi-level pinning in adjacent ordered and disordered domains on a cleaved GaInP sample is performed using a near-field scanning optical microscope and scanning capacitance microscope at room temperature in air. Highly localized photoluminescence spectra obtained by the near-field scanning optical microscope on these domains show spectral peaks at 680 nm (ordered) and 648 nm (disordered) GaInP. The near-field scanning optical microscope and scanning capacitance microscope data confirm previously published data, indicating that the electronic surface structure of ordered GaInP is significantly different from that of disordered GaInP. Both approaches indicate that the Fermi-level at the surface of ordered GaInP is pinned, while the Fermi-level at the surface of disordered GaInP is not pinned. The size, structure, and position of the ordered and disordered domains observed by the near-field scanning optical microscope and scanning capacitance microscope agree with those obtained by cathodoluminescence and Kelvin probe force microscop

Effect of bismuth citrate, lactose, and organic acid on necrotic enteritis in broilers

Clostridium perfringens-associated ne- crotic enteritis causes significant economic losses. The objective of this study was to evaluate the effect of bismuth citrate, lactose, and organic acid on the devel- opment of necrotic enteritis in broilers. The first study was a dose response that evaluated bismuth citrate at 50, 100, or 200 ppm on bacterial intestinal coloniza- tion and lesion development associated with our C. perfringens challenge model. The second study evalu- ated bismuth citrate, lactose, and citric acid on intes- tinal pH and lesion development. For the third study, we determined if lactose would enhance the efficacy of bismuth citrate against intestinal colonization and lesion development associated with C. perfringens. In study 1, intestinal lesion scores at the 50, 100, and 200 ppm bismuth citrate treatment level were reduced (P ≤ 0.05) when compared with the birds fed 0 ppm bismuth citrate. Intestinal C. perfringens colonization of the 100 and 200 ppm bismuth citrate treatment group was sig- nificantly reduced when compared with birds fed 0 ppm bismuth citrate. In study 2, we found no significant differences in lesion development, after C. perfringens challenge, between birds fed 100 ppm bismuth citrate or fed a combination of 100 ppm bismuth citrate with dietary lactose or citric acid relative to the controls. The intestinal pH of birds fed 100 ppm bismuth cit- rate or fed a combination of 100 ppm bismuth citrate with dietary lactose or citric acid was not significantly reduced when compared with the controls. However, a significant reduction in pH was observed in birds fed a combination of 100 ppm bismuth citrate and lactose relative to the negative controls. In study 3, a decrease (P ≤ 0.05) in intestinal lesion scores occurred in birds fed lactose with 100 ppm bismuth citrate, compared with the positive controls. There were no significant differences in intestinal bacterial colonization. These preliminary data suggest that bismuth citrate may re- duce intestinal lesion development and C. perfringens colonization in broilers infected with necrotic enteritis

Use of the WARMF Model to Identify Sources of Oxygen Impairment and Potential Management Strategies for the San Joaquin River Watershed

Eutrophication of the San Joaquin River (SJR) has resulted in low dissolved oxygen (DO) conditions, which has led to a regulatory response and development of total maximum daily load (TMDL) allocations. Due to the dynamic nature of processes governing oxygen depletion in the SJR, a model was needed to help stakeholders understand the fate and transport of nutrients and oxygendemanding substances that cause the low DO conditions. Here, the Watershed Analysis Risk Management Framework (WARMF) model was used to simulate nutrient removal and control strategies, accounting for the secondary effects of growth and transformation between sources and discharge. Using the management alternatives in the WARMF Consensus Module, simulations were run to test the global removal of nutrient inputs on downstream phytoplankton growth, a major contributor of oxygen demand in the SJR. In the simulations, removal of ammonia had the greatest impact on downstream phytoplankton, causing a 32% reduction, while removal of phosphate and nitrate caused reductions of 25% and 13%, respectively. When ammonia and nitrate were both removed, phytoplankton reduction was 62%. These model results suggest that nitrogen control programs would be more effective than phosphorus programs. Using the Data Module in WARMF, input files were modified to determine the impacts of individual tributaries and agricultural drainages. In each simulation, the contributing loads for individual inputs were removed while maintaining flow. According to the model output, the largest impact on phytoplankton occurred with the removal of mass loads from Salt Slough (32% less than baseline). The effect of removing the mass loads from Mud Slough had a slightly lower impact (26% less than baseline). The WARMF model proved useful for exploration of planning and management alternatives, providing an expert decision-making tool that is available to stakeholders

Use of a onedimensional link-node model to develop total maximum daily load strategies for the San Joaquin River Estuary

A one-dimensional link-node model was used to simulate water quality conditions in the tidallyinfluenced, deep water ship channel (DWSC) of the San Joaquin River located in Central California. The DWSC has been plagued with low dissolved oxygen (DO) conditions for decades and is currently a focus of restoration efforts. The model was calibrated using a six-year flow and water quality data set. Model simulations were run by removing the mass loads of each of the following major sources of oxygen depletion to determine the effects: elimination of the deepened ship channel (i.e., restore to its preexisting depth), elimination of import of oxygen-demanding substances (ODS) from the San Joaquin River watershed, elimination of import of ODS from the urban tributaries, and elimination of discharge of ODS from the City of Stockton regional wastewater control facility. The model results suggest that elimination of the deepened ship channel resulted in the best projected improvement relative to the modelled baseline with a predicted 55% improvement, while reducing ODS from the watershed would likely cause a 44% improvement. These results demonstrate that there are multiple contributing factors causing low DO in the DWSC and that removal or elimination of any single variable will not result in a complete resolution of low DO events

1-Isobutyl-4-meth­oxy-1H-imidazo[4,5-c]quinoline

In the title compound, C15H17N3O, the 1H-imidazo[4,5-c]quinoline ring system is approximately planar, with a maximum deviation of 0.036 (1) Å. The C—N—C—C torsion angles formed between this ring system and the isobutyl unit are −99.77 (16) and 79.71 (17)°. In the crystal, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into chains along the c axis

Phases in Strongly Coupled Electronic Bilayer Liquids

The strongly correlated liquid state of a bilayer of charged particles has been studied via the HNC calculation of the two-body functions. We report the first time emergence of a series of structural phases, identified through the behavior of the two-body functions.Comment: 5 pages, RevTEX 3.0, 4 ps figures; Submitted to Phys. Rev. Let

Evaluating Soybean Meal Quality Using Near-Infrared Reflectance Spectroscopy

The objective of this study was to establish a range of soybean meal quality to evaluate the correlations between official analytical methods and near-infrared reflectance spectroscopy (NIRS). Crushed soybean white flakes (Mark Hershey Farms, Lebanon, PA) exposed to mechanical oil extraction, but not heat processing, were used in this experiment. Ground samples (500 g) were put into cotton bags and autoclaved at 262°F for 0, 5, 10, 15, 30, 45, and 60 min at 29 PSI. This was done to simulate varying degrees of heat processing. A total of 2 samples per treatment were autoclaved in 3 separate blocks. The duplicate samples were divided and analyzed using NIRS and official analytical analysis (wet chemistry). Crude protein (CP), total lysine (Lys), Lys:CP, available Lys, available Lys:total Lys, protein solubility in potassium hydroxide (KOH), trypsin inhibitor activity (TIA), urease activity index (UAI), individual amino acids (AA), and total AA were analyzed to determine the degree of processing using official analytical methods. The correlation coefficient (R) and coefficient determination (r2) between NIRS and official analytical methods were established for CP, total Lys, available/reactive Lys, Lys:CP and available/reactive Lys:total Lys. Data were analyzed using the SAS (v. 9.4, SAS Institute Inc., Cary, NC) GLIMMIX procedure and the CORR procedure to determine the degree of association of NIRS and official analytical analysis. When measured using official analytical methods, CP, total AA, Ala, Asp, Glu, Gly, Iso, Leu, and Val decreased (linear, P \u3c 0.05), whereas available/reactive Lys:total Lys, Lys:CP, available Lys, KOH, trypsin inhibitor, urease, Lys, and Cys decreased (quadratic, P \u3c 0.05) with increasing exposure time to the autoclave. There was a positive correlation between official analytical and NIRS results for CP, Lys:CP, available Lys:total Lys, total AA, Ala, Cys, Lys, and a negative correlation for Thr. A linear model was best fit (P = 0.011, r2 = 0.489) to predict CP using NIRS. A quadratic model was best fit to use NIRS total Lys (P = 0.011, r2 = 0.969), reactive Lys (P = 0.001, r2 = 0.988), and their ratio (P = 0.001, r2 = 0.981) to predict official analytical results. In conclusion, increasing soybean autoclave exposure time decreased soybean meal quality as measured by crude protein, total Lys, Lys:CP, available Lys, available Lys:total Lys, KOH solubility total AA, and additional AA. In addition, regression models were successful at using NIRS for Lys, reactive Lys, Lys:CP, and reactive Lys:total Lys to predict official analytical results

Target Selection for the SDSS-IV APOGEE-2 Survey

APOGEE-2 is a high-resolution, near-infrared spectroscopic survey observing roughly 300,000 stars across the entire sky. It is the successor to APOGEE and is part of the Sloan Digital Sky Survey IV (SDSS-IV). APOGEE-2 is expanding upon APOGEE's goals of addressing critical questions of stellar astrophysics, stellar populations, and Galactic chemodynamical evolution using (1) an enhanced set of target types and (2) a second spectrograph at Las Campanas Observatory in Chile. APOGEE-2 is targeting red giant branch (RGB) and red clump (RC) stars, RR Lyrae, low-mass dwarf stars, young stellar objects, and numerous other Milky Way and Local Group sources across the entire sky from both hemispheres. In this paper, we describe the APOGEE-2 observational design, target selection catalogs and algorithms, and the targeting-related documentation included in the SDSS data releases.Comment: 19 pages, 6 figures. Accepted to A