Thermochemical properties of different 1-(R-phenyl)-1H-imidazoles

© 2016 Elsevier B.V.Phenyl substituted imidazoles exhibit versatile biological activity. 1-(R-phenyl)-1H-imidazoles with different functional groups R provide a convenient suitcase of molecules with tunable physicochemical properties adjustable for many practical applications. In this work, the absolute vapor pressures of 1-(R-phenyl)-1H-imidazoles (with R = H, 2-methyl, 4-methyl, 2-methoxy, 4-methoxy, 2-fluoro, 4-fluoro, 2-bromo and 4-bromo) at different temperatures have been measured by the transpiration method for the first time. The standard enthalpies of vaporization of these compounds were derived from the temperature dependencies of the vapor pressures. An internal consistency of the standard vaporization enthalpies has been proven by comparison with vaporization enthalpies of parent species, as well as by a group contribution method. A system of group-additivity values is suggested for a quick assessment of vaporization enthalpies of different 1-(R-phenyl)-1H-imidazoles. Gas-phase standard molar enthalpies of formation of 1-(R-phenyl)-1H-imidazoles have been calculated using the high-level quantum-chemical method G3MP2. The combination of experimentally determined standard vaporization enthalpies with the G3MP2 results allows for the prediction of the liquid-phase standard enthalpies of formation for the studied compounds

ToCo: An ontology for representing hybrid telecommunication networks

The TOUCAN project proposed an ontology for telecommunication networks with hybrid technologies – the TOUCAN Ontology (ToCo), available at http://purl.org/toco/, as well as a knowledge design pattern Device-Interface-Link (DIL) pattern. The core classes and relationships forming the ontology are discussed in detail. The ToCo ontology can describe the physical infrastructure, quality of channel, services and users in heterogeneous telecommunication networks which span multiple technology domains. The DIL pattern is observed and summarised when modelling networks with various technology domains. Examples and use cases of ToCo are presented for demonstration

Thermochemical Properties of Tunable Aryl Alkyl Ionic Liquids (TAAILs) based on Phenyl-1H-imidazoles

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, WeinheimVaporization enthalpies of five different imidazolium based Tunable Aryl Alkyl Ionic Liquids (TAAILs) with a common bis(trifluoromethylsulfonyl)imide ([NTf2]) anion were measured using a Quartz Crystalline Microbalance (QCM) and by Thermogravimetric Analysis (TGA). The counter anion and the alkyl chain of these imidazolium-based ionic liquids with one N-aryl and one N-alkyl substituent were kept constant to study the influence of the ortho- and para-substituted aryl moieties on the vaporization enthalpies of these ionic liquids. For comparison, enthalpies of vaporization measured at elevated temperatures were adjusted to the reference temperature 298 K. Structure-property relations between TAAILs and similarly shaped corresponding 1-(R-phenyl)-imidazoles were analyzed. An incremental approach to predict vaporization enthalpies of ionic liquids by group contributions was suggested. The procedure is based on vaporization enthalpy of a starting IL and group contributions well established from molecular compounds

Production of Single W Bosons at LEP

We report on the observation of single W boson production in a data sample collected by the L3 detector at LEP2. The signal consists of large missing energy final states with a single energetic lepton or two hadronic jets. The cross-section is measured to be $0.61^{+0.43}_{-0.33} \pm 0.05 \; \rm{pb}$ at the centre of mass energy \sqrt{s}=172 \GeV{}, consistent with the Standard Model expectation. From this measurement the following limits on the anomalous $\gamma$WW gauge couplings are derived at 95\% CL: $\rm -3.6 \Delta \kappa_\gamma 1.5$ and $\rm -3.6 \lambda_\gamma 3.6$

Thermochemical properties of different 1-(R-phenyl)-1H-imidazoles

© 2016 Elsevier B.V.Phenyl substituted imidazoles exhibit versatile biological activity. 1-(R-phenyl)-1H-imidazoles with different functional groups R provide a convenient suitcase of molecules with tunable physicochemical properties adjustable for many practical applications. In this work, the absolute vapor pressures of 1-(R-phenyl)-1H-imidazoles (with R = H, 2-methyl, 4-methyl, 2-methoxy, 4-methoxy, 2-fluoro, 4-fluoro, 2-bromo and 4-bromo) at different temperatures have been measured by the transpiration method for the first time. The standard enthalpies of vaporization of these compounds were derived from the temperature dependencies of the vapor pressures. An internal consistency of the standard vaporization enthalpies has been proven by comparison with vaporization enthalpies of parent species, as well as by a group contribution method. A system of group-additivity values is suggested for a quick assessment of vaporization enthalpies of different 1-(R-phenyl)-1H-imidazoles. Gas-phase standard molar enthalpies of formation of 1-(R-phenyl)-1H-imidazoles have been calculated using the high-level quantum-chemical method G3MP2. The combination of experimentally determined standard vaporization enthalpies with the G3MP2 results allows for the prediction of the liquid-phase standard enthalpies of formation for the studied compounds

Thermochemical properties of different 1-(R-phenyl)-1H-imidazoles

© 2016 Elsevier B.V.Phenyl substituted imidazoles exhibit versatile biological activity. 1-(R-phenyl)-1H-imidazoles with different functional groups R provide a convenient suitcase of molecules with tunable physicochemical properties adjustable for many practical applications. In this work, the absolute vapor pressures of 1-(R-phenyl)-1H-imidazoles (with R = H, 2-methyl, 4-methyl, 2-methoxy, 4-methoxy, 2-fluoro, 4-fluoro, 2-bromo and 4-bromo) at different temperatures have been measured by the transpiration method for the first time. The standard enthalpies of vaporization of these compounds were derived from the temperature dependencies of the vapor pressures. An internal consistency of the standard vaporization enthalpies has been proven by comparison with vaporization enthalpies of parent species, as well as by a group contribution method. A system of group-additivity values is suggested for a quick assessment of vaporization enthalpies of different 1-(R-phenyl)-1H-imidazoles. Gas-phase standard molar enthalpies of formation of 1-(R-phenyl)-1H-imidazoles have been calculated using the high-level quantum-chemical method G3MP2. The combination of experimentally determined standard vaporization enthalpies with the G3MP2 results allows for the prediction of the liquid-phase standard enthalpies of formation for the studied compounds

m@ANGEL: autonomic management platform for seamless cognitive connectivity to the mobile internet

B3G wireless access infrastructures can be realized through the concept of cognitive networks. In a B3G context, a network operator will rely on various alternate wireless access technologies, for realizing the appropriate business goals, such as capacity and QoS levels. Cognitive wireless access networks dynamically change their configuration, and in this respect the radio access technologies and spectrum used at the physical and MAC layers, in order to adapt to environment conditions. A cognitive infrastructure consists of reconfigurable elements and intelligent management functionality. This article focuses on the management part. We present a platform, called m@ANGEL, which adheres to autonomic computing principles, and aims at the provision of seamless cognitive connectivity to the mobile Internet. Our work starts from a business level view of cognitive wireless access networks. Technical requirements for m@ANGEL are identified, and the architecture of the platform is described. Moreover, the article describes the functionality and engineering challenges of the m@ANGEL components, which provide the means for monitoring, discovery, context acquisition, description of profiles/ goals/agreements, resource and service brokerage, configuration negotiation, selection, and implementation. Finally, concluding remarks are drawn, and issues for the next phases of our work are identified.X1126sciescopu

Thermochemical Properties of Tunable Aryl Alkyl Ionic Liquids (TAAILs) based on Phenyl-1H-imidazoles

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, WeinheimVaporization enthalpies of five different imidazolium based Tunable Aryl Alkyl Ionic Liquids (TAAILs) with a common bis(trifluoromethylsulfonyl)imide ([NTf2]) anion were measured using a Quartz Crystalline Microbalance (QCM) and by Thermogravimetric Analysis (TGA). The counter anion and the alkyl chain of these imidazolium-based ionic liquids with one N-aryl and one N-alkyl substituent were kept constant to study the influence of the ortho- and para-substituted aryl moieties on the vaporization enthalpies of these ionic liquids. For comparison, enthalpies of vaporization measured at elevated temperatures were adjusted to the reference temperature 298 K. Structure-property relations between TAAILs and similarly shaped corresponding 1-(R-phenyl)-imidazoles were analyzed. An incremental approach to predict vaporization enthalpies of ionic liquids by group contributions was suggested. The procedure is based on vaporization enthalpy of a starting IL and group contributions well established from molecular compounds