CeOx/Al2O3 thin films on stainless steel substrate - Dynamical X-ray photoelectron spectroscopy investigations

Cataloged from PDF version of article.The CeOx/Al2O3 thin films on stainless steel with different ceria loading were subjected to a. c. ( square wave) pulses at various frequencies in the range 10(-3) to 100 kHz while recording X-ray photoelectron spectra. The resulting binding energy differences were derived from the frequency dependence of the corresponding Al2p, Ce3d and O1s peaks. At low ceria loadings the main constituent on the surface is CeAlO3 phase, while for high ceria loading the film is constructed from CeO2 and CeAlO3 phases spread over the Al2O3. Accordingly, it was observed that the ceria loading determines the conductivities of the investigated thin oxide films. (C) 2013 Elsevier B.V. All rights reserved

Measurement of crack opening stresses and crack closure stress profiles from heat generation in vibrating cracks

A method is described to measure crack opening stresses and closure stress profiles of a surface-breaking crack. Vibration is used to generate frictional heat by rubbing crack face asperities. Heat is generated at regions of contacting crack asperities under low, but nonzero, closure stress. Increasing force is applied to incrementally open the crack and measure the locations of crack heating as a function of applied load. Surface crack closure stresses are approximated from the heating locations as the load is varied and the crack opening stress is measured from the load required to fully open the crack and terminate heat generatio

CeOx/Al2O3 thin films on stainless steel substrate - Dynamical X-ray photoelectron spectroscopy investigations

The CeOx/Al2O3 thin films on stainless steel with different ceria loading were subjected to a.c. (square wave) pulses at various frequencies in the range 10- 3 to 100 kHz while recording X-ray photoelectron spectra. The resulting binding energy differences were derived from the frequency dependence of the corresponding Al2p, Ce3d and O1s peaks. At low ceria loadings the main constituent on the surface is CeAlO 3 phase, while for high ceria loading the film is constructed from CeO2 and CeAlO3 phases spread over the Al 2O3. Accordingly, it was observed that the ceria loading determines the conductivities of the investigated thin oxide films. © 2013 Elsevier B.V. All Rights Reserved

Intensity distribution for waves in disordered media: deviations from Rayleigh statistics

We study the intensity distribution function, P(I), for monochromatic waves propagating in quasi one-dimensional disordered medium, assuming that a point source and a point detector are embedded in the bulk of the medium. We find deviations from the Rayleigh statistics at moderately large I and a logarithmically-normal asymptotic behavior of P(I). When the radiation source and the detector are located close to the opposite edges of the sample (on a distance much less then the sample length), an intermediate regime with a stretched-exponential behavior of P(I) emerges.Comment: 4 pages Revtex, 3 figures included as eps file

Steps towards the hyperfine splitting measurement of the muonic hydrogen ground state: pulsed muon beam and detection system characterization

The high precision measurement of the hyperfine splitting of the muonic-hydrogen atom ground state with pulsed and intense muon beam requires careful technological choices both in the construction of a gas target and of the detectors. In June 2014, the pressurized gas target of the FAMU experiment was exposed to the low energy pulsed muon beam at the RIKEN RAL muon facility. The objectives of the test were the characterization of the target, the hodoscope and the X-ray detectors. The apparatus consisted of a beam hodoscope and X-rays detectors made with high purity Germanium and Lanthanum Bromide crystals. In this paper the experimental setup is described and the results of the detector characterization are presented.Comment: 22 pages, 14 figures, published and open access on JINS

Double strand breaks in DNA resulting from double-electron-emission events

A mechanism of double strand breaking (DSB) in DNA due to the action of two electrons is considered. These are the electrons produced in the vicinity of DNA molecules due to ionization of water molecules with a consecutive emission of two electrons, making such a mechanism possible. This effect qualitatively solves a puzzle of large yields of DSBs following irradiation of DNA molecules. The transport of secondary electrons, including the additional electrons, is studied in relation to the assessment of radiation damage due to incident ions. This work is a stage in the inclusion of Auger mechanism and like effects into the multiscale approach to ion-beam cancer therapy.Comment: 4 pages, 3 figure

Current Applications of Computational Chemistry in JACS

Article discussing molecules, mechanisms, and materials and current applications of computational chemistry in the Journal of the American Chemical Society (JACS)

Party system closure and openness: conceptualization, operationalization and validation

The degree of closure of the governmental arena is a central aspect of the stabilization of party systems, and yet little systematic effort has been devoted to its operationalization. The article proposes a new index, examines its reliability and validity, and reports the ranking of 60 party systems. By redefining the units of measurement we suggest new indicators that are uniform and transparent in their logic of construction, can be applied both to specific government-changes and to time periods, and are sensitive to the degree of change. The article finds a hierarchy among the components of party system closure, dominated by coalition formula. While new and established democracies can both produced closed patterns, the analysis of inter-war European party systems shows that closed systems are less prone to authoritarian takeover. The article demonstrates the power of inertia: the completely closed configurations stand out as the most durable ones