Dynamic origin of the morphotropic phase boundary - Soft modes and phase instability in 0.68Pb(Mg1/3Nb2/3O3)-0.32PbTiO3

We report neutron inelastic scattering on single crystal 0.68Pb(Mg1/3Nb2/3O3)-0.32PbTiO3 (PMN-0.32PT), a relaxor ferroelectric material that lies within the compositional range of the morphotropic phase boundary (MPB). Data were obtained between 100 K and 600 K under zero and non-zero electric field applied along the cubic [001] direction. The lowest energy, zone-center, transverse optic phonon is strongly damped and softens slowly at high temperature; however the square of the soft mode energy begins to increase linearly with temperature as in a conventional ferroelectric, which we term the soft mode "recovery," upon cooling into the tetragonal phase at TC. Our data show that the soft mode in PMN-0.32PT behaves almost identically to that in pure PMN, exhibiting the same temperature dependence and recovery temperature even though PMN exhibits no well-defined structural transition (no TC). The temperature dependence of the soft mode in PMN-0.32PT is also similar to that in PMN-0.60PT; however in PMN-0.60PT the recovery temperature equals TC. These results suggest that the temperature dependence and the energy scale of the soft mode dynamics in PMN-xPT are independent of concentration on the Ti-poor side of the MPB, but scale with TC for Ti-rich compositions. Thus the MPB may be defined in lattice dynamical terms as the concentration where TC first matches the recovery temperature of the soft mode. High-resolution x-ray studies show that the cubic-to-ferroelectric phase boundary shifts to higher temperatures by an abnormal amount within the MPB region in the presence of an electric field. This suggests that an unusual instability exists within the apparently cubic phase at the MPB.Comment: 13 pages, 6 figure

Manure Application Timing Drives Energy Absorption for Snowmelt on an Agricultural Soil

Reducing agricultural runoff year-round is important, in particular during snowmelt events on landscapes that receive wintertime applications of manure. To help inform manure guidelines, process-level data are needed that link management scenarios with the complexity of snowmelt, hence runoff. Albedo and radiative energy fluxes are strong drivers of thaw, but applying these mechanistic measurements across multiple, plot-scale management treatments over time presents a logistical challenge. The objective of this study was to first develop a practical field approach to estimate winter albedo in plot-scale field research with multiple management scenarios. The second objective was to quantify the radiative drivers of snowmelt by measuring fluxes after wintertime liquid manure application. Six management treatments were tested in south-central Wisconsin during the winters of 2015–2016 and 2016–2017 with a complete factorial design: three manure application timings (early December, late January, and unmanured) and two tillage treatments (conventional tillage versus no-tillage). A multiple linear regression model was developed to estimate albedo with digital imagery and readily-obtained site characteristics. Manure timing had a significant effect on radiative energy fluxes and tillage was secondary. January applications of liquid manure produced an immediate and lasting decrease in albedo, which resulted in greater net radiation absorbed by snowpack and subsequent energy available for snowmelt. Later applications of liquid manure accelerated snowmelt, which increased runoff losses and posed a challenge for nutrient retention from the liquid manure during thaw

Linking Nutrient Transport to Soil Physical Processes During Freeze/Thaw Events to Promote Wintertime Manure Management, Nutrient Use Efficiency, and Surface Water Quality.

The application of dairy manure to the landscape during winter is a longstanding practice for farms in the Midwestern United States and other temperate regions. Practical motivations behind winter spreading include affordability, availability of time, and the reduced risk of compaction from farm equipment on frozen soils. Wintertime manure applications, however, coincide with environmental conditions that are prone to runoff and accelerate nutrient losses from agricultural fields. Understanding the nutrient dynamics in response to winter-applied manure is especially important to Wisconsin, a leading state in dairy production, where up to 75% of annual runoff volumes occur on frozen and thawing soils. The high potential for winter runoff, hence nutrient transport, has prompted revisions to winter manure regulations, yet little conclusive data exist to guide these changing standards

Temperature and Manure Placement in a Snowpack Affect Nutrient Release from Dairy Manure During Snowmelt

Agricultural nutrient management is an issue due to N and P losses from fields and water quality degradation. Better information is needed on the risk of nutrient loss in runoff from dairy manure applied in winter. We investigated the effect of temperature on nutrient release from liquid and semisolid manure to water, and of manure quantity and placement within a snowpack on nutrient release to melting snow. Temperature did not affect manure P and NH4–N release during water extraction. Manure P release, but not NH4–N release, was significantly influenced by the water/manure solids extraction ratio. During snowmelt, manure P release was not significantly affected by manure placement in the snowpack, and the rate of P release decreased as application rate increased. Water extraction data can reliably estimate P release from manure during snowmelt; however, snowmelt water interaction with manure of greater solids content and subsequent P release appears incomplete compared with liquid manures. Manure NH4–N released during snowmelt was statistically the same regardless of application rate. For the semisolid manure, NH4–N released during snowmelt increased with the depth of snow covering it, most likely due to reduced NH3 volatilization. For the liquid manure, there was no effect of manure placement within the snowpack on NH4–N released during snowmelt. Water extraction data can also reliably estimate manure NH4–N release during snowmelt as long as NH3 volatilization is accounted for with liquid manures for all placements in a snowpack and semisolid manures applied on top of snow

Quantifying the Impact of Seasonal and Short-term Manure Application Decisions on Phosphorus Loss in Surface Runoff

Agricultural phosphorus (P) management is a research and policy issue due to P loss from fields and water quality degradation. Better information is needed on the risk of P loss from dairy manure applied in winter or when runoff is imminent. We used the SurPhos computer model and 108 site–years of weather and runoff data to assess the impact of these two practices on dissolved P loss. Model results showed that winter manure application can increase P loss by 2.5 to 3.6 times compared with non-winter applications, with the amount increasing as the average runoff from a field increases. Increased P loss is true for manure applied any time from late November through early March, with a maximum P loss from application in late January and early February. Shifting manure application to fields with less runoff can reduce P loss by 3.4 to 7.5 times. Delaying manure application when runoff is imminent can reduce P loss any time of the year, and sometimes quite significantly, but the number of times that application delays will reduce P loss is limited to only 3 to 9% of possible spreading days, and average P loss may be reduced by only 15% for winter-applied manure and 6% for non-winter-applied manure. Overall, long-term strategies of shifting manure applications to low runoff seasons and fields can potentially reduce dissolved P loss in runoff much more compared with near-term, tactical application decisions of avoiding manure application when runoff is imminent

Kidney and Pancreas Transplantation in the United States, 1998–2007: Access for Patients with Diabetes and End-Stage Renal Disease

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/73092/1/j.1600-6143.2009.02566.x.pd

Dynamics of Measured and Simulated Dissolved Phosphorus in Runoff from Winter-Applied Dairy Manure

Agricultural P loss from fields is an issue due to water quality degradation. Better information is needed on the P loss in runoff from dairy manure applied in winter and the ability to reliably simulate P loss by computer models. We monitored P in runoff during two winters from chisel-tilled and no-till field plots that had liquid dairy manure applied in December or January. Runoff total P was dominated by nondissolved forms when soils were bare and unfrozen. Runoff from snow-covered, frozen soils had much less sediment and sediment-related P, and much more dissolved P. Transport of manure solids was greatest when manure was applied on top of snow and runoff shortly after application was caused by snowmelt. Dissolved P concentrations in runoff were greater when manure was applied on top of snow because manure liquid remained in the snowpack and allowed more P to be available for loss. Dissolved runoff P also increased as the amount of rain or snowmelt that became runoff (runoff ratio) increased. The SurPhos manure P runoff model reliably simulated these processes to provide realistic predictions of dissolved P in runoff from surface manure. Overall, for liquid dairy manure applied in winter, dissolved P concentrations in runoff can be decreased if manure is applied onto bare, unfrozen soil, or if runoff ratio can be reduced, perhaps through greater soil surface roughness from fall tillage. Both management approaches will allow more manure P to infiltrate into soil and less move in runoff. SurPhos is a tool that can reliably evaluate P loss for different management and policy scenarios for winter manure application

Influence of the algal microbiome on biofouling during industrial cultivation of Nannochloropsis sp. in closed photobioreactors

Industrial cultivation of microalgae is becoming increasingly important, yet the process is still hampered by many factors, including contamination and biofouling of the algal reactors. We characterized a subset of microorganisms occurring in the broth and different biofilm stages of industrial scale photobioreactors applied for the cultivation of Nannochloropsis sp. A total of 69 bacterial strains were isolated, belonging to at least 24 different species. In addition, a green microalga was isolated and identified as Chlamydomonas hedleyi. The effect of C. hedleyi and 24 of the bacterial isolates on the productivity of Nannochloropsis was evaluated through growth and biofilm assays. C. hedleyi was shown to reduce growth and induce biofilm formation in Nannochloropsis. These effects were however indirect as they could be attributed to the bacteria associated to C. hedleyi and not C. hedleyi itself. Although most bacterial strains reported no effect, several were able to induce biofilm formation

Fall Tillage Reduced Nutrient Loads from Liquid Manure Application During the Freezing Season

Reducing agricultural runoff is important year round, particularly on landscapes that receive wintertime applications of manure. No-tillage systems are typically associated with reduced runoff loads during the growing season, but surface roughness from fall tillage may aid infiltration on frozen soils by providing surface depressional storage. The timing of winter manure applications may also affect runoff, depending on snow and soil frost conditions. Therefore, the objective of this study was to evaluate runoff and nutrient loads during the freezing season from combinations of tillage and manure application timings. Six management treatments were tested in south-central Wisconsin during the winters of 2015–2016 and 2016–2017 with a complete factorial design: two tillage treatments (fall chisel plow vs. no-tillage) and three manure application timings (early December, late January, and unmanured). Nutrient loads from winter manure application were lower on chisel-plowed versus untilled soils during both monitoring years. Loads were also lower from manure applied to soils with less frost development. Wintertime manure applications pose a risk of surface nutrient losses, but fall tillage and timing applications to thawed soils can help reduce loads