Layering Transitions and Solvation Forces in an Asymmetrically Confined Fluid

We consider a simple fluid confined between two parallel walls (substrates), separated by a distance L. The walls exert competing surface fields so that one wall is attractive and may be completely wet by liquid (it is solvophilic) while the other is solvophobic. Such asymmetric confinement is sometimes termed a `Janus Interface'. The second wall is: (i) purely repulsive and therefore completely dry (contact angle 180 degrees) or (ii) weakly attractive and partially dry (the contact angle is typically in the range 160-170 degrees). At low temperatures, but above the bulk triple point, we find using classical density functional theory (DFT) that the fluid is highly structured in the liquid part of the density profile. In case (i) a sequence of layering transitions occurs: as L is increased at fixed chemical potential (mu) close to bulk gas--liquid coexistence, new layers of liquid-like density develop discontinuously. In contrast to confinement between identical walls, the solvation force is repulsive for all wall separations and jumps discontinuously at each layering transition and the excess grand potential exhibits many metastable minima as a function of the adsorption. For a fixed temperature T=0.56Tc, where Tc is the bulk critical temperature, we determine the transition lines in the L, mu plane. In case (ii) we do not find layering transitions and the solvation force oscillates about zero. We discuss how our mean-field DFT results might be altered by including effects of fluctuations and comment on how the phenomenology we have revealed might be relevant for experimental and simulation studies of water confined between hydrophilic and hydrophobic substrates, emphasizing it is important to distinguish between cases (i) and (ii).Comment: 16 pages, 13 figure

Adobe Flash as a medium for online experimentation: a test of reaction time measurement capabilities

Adobe Flash can be used to run complex psychological experiments over the Web. We examined the reliability of using Flash to measure reaction times (RTs) using a simple binary-choice task implemented both in Flash and in a Linux-based system known to record RTs with millisecond accuracy. Twenty-four participants were tested in the laboratory using both implementations; they also completed the Flash version on computers of their own choice outside the lab. RTs from the trials run on Flash outside the lab were approximately 20 msec slower than those from trials run on Flash in the lab, which in turn were approximately 10 msec slower than RTs from the trials run on the Linux-based system (baseline condition). RT SDs were similar in all conditions, suggesting that although Flash may overestimate RTs slightly, it does not appear to add significant noise to the data recorded

Gamma ray angular correlations following inelastic scattering of 42-MeV alpha particles from magnesium 24

Angular correlation between inelastically scattered alpha particles and gamma rays emitted in subsequent nuclear decay of magnesium 2

EDIN design study alternate space shuttle booster replacement concepts. Volume 2: Design simulation results

Historical weight estimating relationships were developed for the liquid rocket booster (LRB) using Saturn technology, and modified as required to support the EDIN05 study. Mission performance was computed using February 1975 shuttle configuration groundrules to allow reasonable comparison of the existing shuttle with the EDIN05 designs. The launch trajectory was constrained to pass through both the RTLS/AOA and main engine cut-off points. Performance analysis was based on a point design trajectory model which optimized initial tilt rate and exo-atmospheric pitch profile. A gravity turn was employed during the boost phase in place of the shuttle angle-of-attack profile. Engine throttling add/or shutdown was used to constrain dynamic pressure and/or longitudinal acceleration where necessary

Water-depth measurement by wave refraction and multispectral techniques

Shallow ocean depth measurements by aerial photographs of wave refraction and wavelength changes and by multispectral scanning of wave reflectio

Paediatric HIV - Looking beyond CD4 counts

Paediatric HIV remains a significant health and social challenge in sub-Saharan Africa despite many countries gaining improved access to antiretroviral treatment. Paediatric HIV affects multiple body systems and has the potential to cause wide ranging impairments as well as activity and participation limitations. The aim of this paper is to highlight some of the impairments that remain, despite the children having access to better medical care, in order to establish a possible role for physiotherapists. Nine studies conducted through the department of physiotherapy at the University of the Witwatersrand, South Africa are presented. The results of these studies demonstrate the neurodevelopmental, musculoskeletal, respiratory and quality of life challenges which children infected with HIV as well as their caregivers continue to face. The need for long term, multidisciplinary follow up of children infected with HIV is emphasized

Global properties of dilatonic Gauss-Bonnet black holes

We study the phase space of the spherically symmetric solutions of Einstein Gauss-Bonnet system nonminimally coupled to a scalar field and show that in four dimensions the only regular black hole solutions are asymptotically flatComment: 12 pages, plain TeX; v.2: phase space is described in more detai

International Student Perceptions of Libraries: Experiences from the Middle East and North Africa

The purpose of this study was to better understand the types of experiences which have contributed to Arab international students’ perceptions and uses of information and libraries. In-depth, semi-structured interviews were conducted to understand how students from the MENA region perceive and use libraries and information as international students in the U.S. During interviews, participants were asked about their past and present experiences with seeking information and using libraries in both their home countries as well as during their time as students in the United States

Geology

Papers from private industry reporting applications of remote sensing to oil and gas exploration were presented. Digitally processed LANDSAT images were successfully employed in several geologic interpretations. A growing interest in digital image processing among the geologic user community was shown. The papers covered a wide geographic range and a wide technical and application range. Topics included: (1) oil and gas exploration, by use of radar and multisensor studies as well as by use of LANDSAT imagery or LANDSAT digital data, (2) mineral exploration, by mapping from LANDSAT and Skylab imagery and by LANDSAT digital processing, (3) geothermal energy studies with Skylab imagery, (4) environmental and engineering geology, by use of radar or LANDSAT and Skylab imagery, (5) regional mapping and interpretation, and digital and spectral methods

Nanoparticle biofabrication using English ivy (\u3cem\u3eHedera helix\u3c/em\u3e)

Background English ivy (Hedera helix) is well known for its adhesive properties and climbing ability. Essential to its ability to adhere to vertical surfaces is the secretion of a nanocomposite adhesive containing spherical nanoparticles, 60–85 nm in diameter, produced exclusively by root hairs present on adventitious roots. These organic nanoparticles have shown promise in biomedical and cosmetic applications, and represent a safer alternative to metal oxide nanoparticles currently available. Results It was discovered that the maximum adventitious root production was achieved by a 4 h application of 1 mg/ml indole-3 butyric acid (IBA) to juvenile English ivy shoot segments cultured in custom vessels. After incubation of the shoots under continuous light at 83 μmol/m2 s at 20°C for 2 weeks, the adventitious roots were harvested from the culture system and it was possible to isolate 90 mg of dry weight nanoparticles per 12 g of roots. The nanoparticle morphology was characterized by atomic force microscopy, and found to be similar to previous studies. Conclusions An enhanced system for the production of English ivy adventitious roots and their nanoparticles by modifying GA7 Magenta boxes and identifying the optimal concentration of IBA for adventitious root growth was developed. This system is the first such platform for growing and harvesting organic nanoparticles from plants, and represents an important step in the development of plant-based nanomanufacturing. It is a significant improvement on the exploitation of plant systems for the formation of metallic nanoparticles, and represents a pathway for the generation of bulk ivy nanoparticles for translation into biomedical applications